B01J27/02

Thermally Stable Monolith Catalysts for Methane Reforming and Preparing Method of the Same

The present invention relates to a monolith catalyst for carbon-dioxide/methane reforming and a method of manufacturing the same, and more particularly to a novel monolith catalyst for a reforming reaction having improved thermal durability, configured such that a sintering inhibiting layer is formed by coating the surface of a monolith support with at least one element selected from the group consisting of Group 2, 3, 6, 13, 15 and 16 elements among elements in Period 3 or higher and an active catalyst layer is formed on the sintering inhibiting layer, thereby preventing carbon deposition and catalyst deactivation due to deterioration even upon reaction at high temperatures.

CATALYST FOR HYDROLYSIS OF CARBONYL SULFIDE AND METHOD OF PRODUCING SAME

A catalyst for COS hydrolysis includes titanium dioxide and a barium compound supported on the titanium dioxide. The catalyst, when expressing Ba and S in the catalyst in terms of BaO and SO.sub.3, respectively, has a molar ratio of SO.sub.3 to BaO of at least 1. The catalyst converts COS and H.sub.2O in a raw material gas to CO.sub.2 and H.sub.2S.

CATALYST FOR HYDROLYSIS OF CARBONYL SULFIDE AND METHOD OF PRODUCING SAME

A catalyst for COS hydrolysis includes titanium dioxide and a barium compound supported on the titanium dioxide. The catalyst, when expressing Ba and S in the catalyst in terms of BaO and SO.sub.3, respectively, has a molar ratio of SO.sub.3 to BaO of at least 1. The catalyst converts COS and H.sub.2O in a raw material gas to CO.sub.2 and H.sub.2S.

Agglomerated ODH catalyst

Oxidative dehydrogenation catalysts for converting lower paraffins to alkenes such as ethane to ethylene when prepared as an agglomeration, for example extruded with supports comprising slurries of Nb.sub.2O.sub.5.

Method for producing fluorenylidene diallylphenols, and fluorenylidene diallylphenols
10906855 · 2021-02-02 · ·

Provided are: a method for producing fluorenylidene diallylphenols represented by formula (1), the method including a reaction step for reacting fluorenones represented by formula (2) and allylphenols represented by formula (3) in the presence of an acid catalyst, excluding compounds having mercapto groups, the amount of acid catalyst being 0.001-20 mol per mol of compound represented by formula (2); and fluorenylidene diallylphenols represented by formula (4). ##STR00001##

Method for producing fluorenylidene diallylphenols, and fluorenylidene diallylphenols
10906855 · 2021-02-02 · ·

Provided are: a method for producing fluorenylidene diallylphenols represented by formula (1), the method including a reaction step for reacting fluorenones represented by formula (2) and allylphenols represented by formula (3) in the presence of an acid catalyst, excluding compounds having mercapto groups, the amount of acid catalyst being 0.001-20 mol per mol of compound represented by formula (2); and fluorenylidene diallylphenols represented by formula (4). ##STR00001##

Solid acid catalyst for preparing D-galactose and preparation method thereof

Disclosed is a solid acid catalyst for preparing D-galactose and a preparation method thereof. The method includes: S1. synthesis of a skeleton carrier: S11. preparation of a sodium aluminate solution and an organic template solution; S12. mixing the sodium aluminate solution with the organic template solution, and thoroughly shaking a resulting mixture to obtain a mixed solution; S13. adding a zirconium source to the mixed solution obtained in S12, and thoroughly mixing; S14. subjecting a reaction system obtained in S13 to a hydrothermal reaction to obtain a mixed crystal ZrO.sub.2/Al.sub.2O.sub.3; and S15. rapidly heating the mixed crystal ZrO.sub.2/Al.sub.2O.sub.3 obtained in S14 until the organic template is completely ashed, and washing a resulting product with absolute ethanol to obtain a white solid ZrO.sub.2/Al.sub.2O.sub.3; and S2. soaking the skeleton carrier obtained in S1 in concentrated sulfuric acid such that sulfonyl is loaded on the skeleton carrier to obtain the target solid acid.

Solid acid catalyst for preparing D-galactose and preparation method thereof

Disclosed is a solid acid catalyst for preparing D-galactose and a preparation method thereof. The method includes: S1. synthesis of a skeleton carrier: S11. preparation of a sodium aluminate solution and an organic template solution; S12. mixing the sodium aluminate solution with the organic template solution, and thoroughly shaking a resulting mixture to obtain a mixed solution; S13. adding a zirconium source to the mixed solution obtained in S12, and thoroughly mixing; S14. subjecting a reaction system obtained in S13 to a hydrothermal reaction to obtain a mixed crystal ZrO.sub.2/Al.sub.2O.sub.3; and S15. rapidly heating the mixed crystal ZrO.sub.2/Al.sub.2O.sub.3 obtained in S14 until the organic template is completely ashed, and washing a resulting product with absolute ethanol to obtain a white solid ZrO.sub.2/Al.sub.2O.sub.3; and S2. soaking the skeleton carrier obtained in S1 in concentrated sulfuric acid such that sulfonyl is loaded on the skeleton carrier to obtain the target solid acid.

Solid catalyst for manufacturing fatty acid methyl or ethyl ester and method for manufacturing fatty acid methyl or ethyl ester using the same
10888842 · 2021-01-12 · ·

The present invention relates to a method for manufacturing a catalyst for synthesizing a fatty acid methyl or ethyl ester and a method for manufacturing a fatty acid methyl or ethyl ester using the catalyst. It provides a method for manufacturing a solid catalyst by mixing the oxides of manganese as active catalytic material and the soda lime glass as carrier wherein the content of the oxides of manganese is in the range of 0.1 w % to 70 w %, molding the mixture to spherical or cylindrical shape and sintering the molded catalyst. It also provides a method for manufacturing fatty acid methyl or ethyl ester with high purity by reacting fatty acid or a mixture of oil and fatty acid with methanol or ethanol by placing the solid catalyst in the reactor.

Solid catalyst for manufacturing fatty acid methyl or ethyl ester and method for manufacturing fatty acid methyl or ethyl ester using the same
10888842 · 2021-01-12 · ·

The present invention relates to a method for manufacturing a catalyst for synthesizing a fatty acid methyl or ethyl ester and a method for manufacturing a fatty acid methyl or ethyl ester using the catalyst. It provides a method for manufacturing a solid catalyst by mixing the oxides of manganese as active catalytic material and the soda lime glass as carrier wherein the content of the oxides of manganese is in the range of 0.1 w % to 70 w %, molding the mixture to spherical or cylindrical shape and sintering the molded catalyst. It also provides a method for manufacturing fatty acid methyl or ethyl ester with high purity by reacting fatty acid or a mixture of oil and fatty acid with methanol or ethanol by placing the solid catalyst in the reactor.