Patent classifications
B01J29/005
FCC catalyst additive and binder
Provided is a process for manufacturing a Fluid Catalytic Cracking catalyst additive composition with a novel binder. The steps involve mixing an alumina source with water to make a slurry; adding to the alumina slurry an amount of P2O5 source; the slurry is then stirred and reacted under controlled temperature and time conditions to form an aluminum phosphate binder; adding to the aluminum phosphate binder a zeolite, an amount of silica binder and an amount of clay; and spray-drying the slurry to form catalyst additive particles. The catalyst additive composition comprises a about 35 wt % to about 65 wt % zeolite; about 0 wt % to about 10 wt % silica; about 15 wt % to about 50 wt % clay and an aluminum phosphate binder comprising about 2.5 wt % to 5 wt % amorphous or pseudo-boehmite alumina and about 7 wt % to 15 wt % phosphoric acid.
SCR-Active Material
The present invention relates to an SCR-active material, comprising a small-pore zeolite, aluminum oxide and copper, characterized in that it contains 5 to 25 wt-% of aluminum oxide in relation to the entire material and that the copper is present on the aluminum oxide in a first concentration and on the small-pore zeolite in a second concentration.
Catalyst Compositions and Their Use in Aromatic Alkylation Processes
Catalyst compositions comprising a zeolite and a mesoporous support or binder are disclosed. The mesoporous support or binder comprises a mesoporous metal oxide having a particle diameter of greater than or equal to 20 m at 50% of the cumulative pore size distribution (d50). Also disclosed are processes for producing a mono-alkylated aromatic compound (e.g., ethylbenzene or cumene) which exhibit improved yield of the mono-alkylated aromatic compound using alkylation catalysts comprising one or more of these catalyst compositions.
FCC CATALYST WITH ENHANCED MESOPOROSITY, ITS PREPARATION AND USE
Process for the preparation of a catalyst and a catalyst comprising enhanced mesoporosity is provided herein. Thus, in one embodiment, provided is a particulate FCC catalyst comprising 2 to 50 wt % of one or more ultra stabilized high Si02/A1203 ratio large pore faujasite zeolite or a rare earth containing USY, 0 to 50 wt % of one or more rare-earth exchanged large pore faujasite zeolite, 0 to 30 wt % of small to medium pore size zeolites, 5 to 45 wt % quasi-crystalline boehmite 0 to 35 wt % microcrystalline boehmite, 0 to 25 wt % of a first silica, 2 to 30 wt % of a second silica, 0.1 to 10 wt % one or more rare earth components showiomg enhanced mesoporosity in the range of 6-40 nm, the numbering of the silica corresponding to their orders of introduction in the preparation process.
ZSM-5 additive activity enhancement by improved zeolite and phosphorus interaction
A catalytic additive comprising an intermediate pore zeolite, such as ZSM-5 is treated so as to improve propylene yields when the additive is included in a FCC catalytic inventory by first treating the zeolite with a phosphorus compound to incorporate the phosphorus in the zeolite, and mixing the P-treated zeolite with a matrix component comprising kaolin and another phosphorus-containing compound.
SCR-active material
The present invention relates to an SCR-active material, comprising a small-pore zeolite, aluminum oxide and copper, characterized in that it contains 5 to 25 wt-% of aluminum oxide in relation to the entire material and that the copper is present on the aluminum oxide in a first concentration and on the small-pore zeolite in a second concentration.
NANOTHERAPEUTIC AND A METHOD OF OXIDATIVE DEHYDROGENATION BUILT ON HIERACHICAL SILICA COMPOSITES
A nanotherapeutic supported by a hierarchical silica composite with dual imaging capability (e.g. fluorescence and magnetic resonance imaging), a method of preparing the nanotherapeutic, and a method of treating cancer. Also disclosed is a method of oxidatively dehydrogenating ethane using a catalytic system supported by a hierarchical silica composite.
SAPO-34/ZSM-5@ kaolin microsphere composite catalytic material and its preparation and use
The present invention relates to a composite catalytic material of SAPO-34/ZSM-5@kaolin microspheres and its preparation and use, the method comprises the steps of: 1) processing kaolin into kaolin microspheres, and baking them to obtain activated kaolin microspheres; 2) mixing the activated kaolin microspheres obtained in step 1), water, a phosphorus source, and a template agent to prepare a gel; 3) mixing the gel obtained in step 2) and a ZSM-5 molecular sieve, and carrying out aging, crystallization, and separation to obtain a composite material of SAPO-34/ZSM-5@kaolin; 4) subjecting the composite material obtained in step 3) to ammonium exchange treatment and baking, to obtain the composite catalytic material of SAPO-34/ZSM-5@kaolin microspheres. The present invention not only greatly shortens the preparation route for the catalyst and reduces the cost of catalyst preparation, but also allows adjustment of the fractions of SAPO-34 and ZSM-5 molecular sieves in the composite material by adjustment of the synthesis conditions.
Catalyst for catalytic cracking of hydrocarbon oil and method for catalytic cracking of hydrocarbon oil
A catalyst for catalytic cracking of a hydrocarbon oil can produce a gasoline fraction having a high octane number in high yield while suppressing an increase in yield of a heavy distillate, and produce LPG having a high propylene content in high yield. The catalyst includes a specific amount of a granulated catalyst A that includes a zeolite having a sodalite cage structure, silicon derived from a silica sol, phosphorus and aluminum derived from mono aluminum phosphate, a clay mineral, and a rare-earth metal, and a specific amount of a granulated catalyst B that includes a pentasil-type zeolite, the ratio of the mass of phosphorus and aluminum derived from mono aluminum phosphate included in the granulated catalyst A to the mass of the pentasil-type zeolite included in the granulated catalyst B being 0.015 to 3000.
ZEOLITE MONOLITH COMPOSITIONS AND METHODS FOR THE CATALYTIC CRACKING OF ALKANES
Porous zeolite monolith compositions for the catalytic cracking of alkanes. The compositions may be prepared layer by layer using a 3D printer such that the compositions comprise a plurality of micropores and a plurality of mesopores and may be characterized by macro-meso-microporosity.