A porous ceramic honeycomb body including a substrate of intersecting porous walls forming axial channels extending from a first end face to a second end face. An active portion of the walls include a zeolite catalyst disposed inside pores thereof and/or is comprised of an extruded zeolite and a three way catalyst (TWC) is disposed on wall surfaces of at least a portion of the active portion.

A family of highly charged crystalline microporous metallophosphate molecular sieves designated PST-19 has been synthesized. These high charge density metallophosphates are represented by the empirical formula of:
R.sup.p+.sub.rA.sup.+.sub.mM.sup.2+.sub.xE.sub.yPO.sub.z
where A is an alkali metal such as potassium, R is an organoammonium cation such as tetraethylammonium, M is a divalent metal such as zinc and E is a trivalent framework element such as aluminum or gallium. The PST-19 family of materials are among the first MeAPO-type molecular sieves to be stabilized by combinations of alkali and quaternary ammonium cations, enabling unique compositions. The PST-19 family of molecular sieves has the SBS topology and catalytic properties for carrying out various hydrocarbon conversion processes and separation properties for separating at least one component.

A family of highly charged crystalline microporous metallophosphate molecular sieves designated PST-16 has been synthesized. These metallophosphates are represented by the empirical formula of:
R.sup.p+.sub.rA.sub.m.sup.+M.sub.xE.sub.yPO.sub.z
where A is an alkali metal such as potassium, R is an organoammonium cation such as ethyltrimethylammonium, M is a divalent metal such as zinc and E is a trivalent framework element such as aluminum or gallium. The PST-16 family of molecular sieves are stabilized by combinations of alkali and organoammonium cations, enabling unique metalloalumino(gallo)phosphate compositions and exhibit the CGS topology. The PST-17 family of molecular sieves has catalytic properties for carrying out various hydrocarbon conversion processes and separation properties for separating at least one component.

The present invention relates to a process for preparing a phosphorus containing zeolite type catalysts based on crystalline aluminosilicates, the catalysts of this process and the use of this catalysts for the conversion of methanol to olefins.

The present invention relates to a process for preparing a phosphorus containing zeolite type catalysts based on crystalline aluminosilicates, the catalysts of this process and the use of this catalysts for the conversion of methanol to olefins.

Presented is a process for the preparation of zeolitic material through condensed gel crystallizations. The present disclosure describes methods for improved preparation of zeolites by preparing an aqueous precursor mixture; removing at least 5 wt % of the total water from the aqueous precursor solution to create a solution with greater solids content; crystallizing the solution of step (b) to create a zeolite product. The resulting zeolites can show improved mesoporosity without any post-treatment to create mesoporosity. This effect is particularly prominent in ZSM-5 zeolites, for example.

STA-18, a molecular sieve having a SFW structure and containing phosphorus in the framework, is described. STA-18AP (as prepared) can have a lower alkyl amine, such as trimethylamine, and one of 1,6-(1,4-diazabicyclo[2.2.2]octane)hexyl cations (from diDABCO-C6) or 1,7-(1,4-diazabicyclo[2.2.2]octane)heptyl cations (from diDABCO-C7) or 1,8-(1,4-diazabicyclo[2.2.2]octane)octyl cations (from diDABCO-C8) as SDAs. A lower alkyl ammonium hydroxide, such as tetrabutylammonium hydroxide, can be used as a pH modifier for making SAPO STA-18. A calcined product, STA-18C, formed from STA-18AP is also described. Methods of preparing STA-18AP, STA-18C and metal containing calcined counterparts of STA-18C are described along with methods of using STA-18C and metal containing calcined counterparts of STA-18C in a variety of processes, such as treating exhaust gases and converting methanol to olefins are described.

STA-18, a molecular sieve having a SFW structure and containing phosphorus in the framework, is described. STA-18AP (as prepared) can have a lower alkyl amine, such as trimethylamine, and one of 1,6-(1,4-diazabicyclo[2.2.2]octane)hexyl cations (from diDABCO-C6) or 1,7-(1,4-diazabicyclo[2.2.2]octane)heptyl cations (from diDABCO-C7) or 1,8-(1,4-diazabicyclo[2.2.2]octane)octyl cations (from diDABCO-C8) as SDAs. A lower alkyl ammonium hydroxide, such as tetrabutylammonium hydroxide, can be used as a pH modifier for making SAPO STA-18. A calcined product, STA-18C, formed from STA-18AP is also described. Methods of preparing STA-18AP, STA-18C and metal containing calcined counterparts of STA-18C are described along with methods of using STA-18C and metal containing calcined counterparts of STA-18C in a variety of processes, such as treating exhaust gases and converting methanol to olefins are described.

A porous ceramic honeycomb body including a substrate of intersecting porous walls forming axial channels extending from a first end face to a second end face. An active portion of the walls include a zeolite catalyst disposed inside pores thereof and/or is comprised of an extruded zeolite and a three way catalyst (TWC) is disposed on wall surfaces of at least a portion of the active portion.

A catalyst system and processes for combined aromatization and selective hydrogen combustion of oxygenated hydrocarbons are disclosed. The catalyst system contains at least one aromatization component and at least one selective hydrogen combustion component. The process is such that the yield of hydrogen is less than the yield of hydrogen when contacting the hydrocarbons with the aromatization component alone.