A method of making and using a new family of crystalline microporous metalloalumino(gallo)phosphosilicate molecular sieves is disclosed. These molecular sieves have been synthesized and are designated high charge density (HCD) MeAPSOs. These metalloalumino(gallo)phosphosilicates are represented by the empirical formula of:
R.sup.p+.sub.rA.sup.+.sub.mM.sup.2+.sub.wE.sub.xPSi.sub.yO.sub.z
where A is an alkali metal such as potassium, R is at least one quaternary ammonium cation such as ethyltrimethylammonium, M is a divalent metal such as Zn and E is a trivalent framework element such as aluminum or gallium. This family of metalloalumino(gallo)phosphosilicate materials is stabilized by combinations of alkali and quaternary ammonium cations, enabling unique, high charge density compositions. The HCD MeAPSO family of materials have catalytic properties for carrying out various hydrocarbon conversion processes and separation properties for separating at least one component.

A method of making and using a new family of crystalline microporous metalloalumino(gallo)phosphosilicate molecular sieves is disclosed. These molecular sieves have been synthesized and are designated high charge density (HCD) MeAPSOs. These metalloalumino(gallo)phosphosilicates are represented by the empirical formula of:
R.sup.p+.sub.rA.sup.+.sub.mM.sup.2+.sub.wE.sub.xPSi.sub.yO.sub.z
where A is an alkali metal such as potassium, R is at least one quaternary ammonium cation such as ethyltrimethylammonium, M is a divalent metal such as Zn and E is a trivalent framework element such as aluminum or gallium. This family of metalloalumino(gallo)phosphosilicate materials is stabilized by combinations of alkali and quaternary ammonium cations, enabling unique, high charge density compositions. The HCD MeAPSO family of materials have catalytic properties for carrying out various hydrocarbon conversion processes and separation properties for separating at least one component.

A method is provided for synthesizing molecular sieves of ITE framework type using one or more of 1-ethyl-1,3,5-trimethylpiperidinium cations and 1-ethyl-1-methyldecahydroquinolinium cations a structure directing agent.

A method is provided for synthesizing molecular sieves of ITE framework type using one or more of 1-ethyl-1,3,5-trimethylpiperidinium cations and 1-ethyl-1-methyldecahydroquinolinium cations a structure directing agent.

The present invention is directed to a method of preparing a molecular sieve of SWY framework type, denominated STA-30. STA-30 is synthesized using 1,4-diazabicyclo[2.2.2]octane, 1-azabicyclo[2.2.2]octane derivates and combinations thereof as structure directing agents. The resulting molecular sieve is useful as catalysts, particularly when used in combination with exchanged transition metal(s) for the Selective Catalytic Reduction (SCR) of NO.

The present invention is directed to a method of preparing a molecular sieve of SWY framework type, denominated STA-30. STA-30 is synthesized using 1,4-diazabicyclo[2.2.2]octane, 1-azabicyclo[2.2.2]octane derivates and combinations thereof as structure directing agents. The resulting molecular sieve is useful as catalysts, particularly when used in combination with exchanged transition metal(s) for the Selective Catalytic Reduction (SCR) of NO.

A catalyst and process for the production of methyl acetate by contacting dimethyl ether and carbon monoxide in the presence of a catalyst which is a zeolite of micropore volume of 0.01 ml/g or less.

A catalyst and process for the production of methyl acetate by contacting dimethyl ether and carbon monoxide in the presence of a catalyst which is a zeolite of micropore volume of 0.01 ml/g or less.

A lower olefin by using a zeolite catalyst, a composite catalyst capable of further extending the lifetime of catalytic activity, a method for producing the composite catalyst, a method for producing a lower olefin by using the composite catalyst, and a method for regenerating a composite catalyst in the method for producing a lower olefin are provided. The composite catalyst is a catalyst for producing a lower olefin from a hydrocarbon feedstock. This composite catalyst is constituted of a zeolite being a crystalline aluminosilicate containing gallium and iron or iron and further having a framework with 8- to 12-membered ring, and of silicon dioxide. By using the composite catalyst, a lower olefin can be continuously produced over a long period of time.

A lower olefin by using a zeolite catalyst, a composite catalyst capable of further extending the lifetime of catalytic activity, a method for producing the composite catalyst, a method for producing a lower olefin by using the composite catalyst, and a method for regenerating a composite catalyst in the method for producing a lower olefin are provided. The composite catalyst is a catalyst for producing a lower olefin from a hydrocarbon feedstock. This composite catalyst is constituted of a zeolite being a crystalline aluminosilicate containing gallium and iron or iron and further having a framework with 8- to 12-membered ring, and of silicon dioxide. By using the composite catalyst, a lower olefin can be continuously produced over a long period of time.