According to one or more embodiments, cationic polymers may be produced which include one or more monomers containing cations. Such cationic polymers may be utilized as structure directing agents to for mesoporous zeolites. The mesoporous zeolites may include micropores as well as mesopores, and may have a surface area of greater than 350 m.sup.2/g and a pore volume of greater than 0.3 cm.sup.3/g. Also described are core/shell zeolites, where at least the shell portion includes a mesoporous zeolite material.

According to one or more embodiments, cationic polymers may be produced which include one or more monomers containing cations. Such cationic polymers may be utilized as structure directing agents to for mesoporous zeolites. The mesoporous zeolites may include micropores as well as mesopores, and may have a surface area of greater than 350 m.sup.2/g and a pore volume of greater than 0.3 cm.sup.3/g. Also described are core/shell zeolites, where at least the shell portion includes a mesoporous zeolite material.

A process comprising hydrothermally synthesizing a titanium-containing zeolitic material having framework type MWW in the presence of an MWW template compound, obtaining a mother liquor comprising water, a first portion of the MWW template compound and a titanium-containing zeolitic material having framework type MWW comprising a second portion of the MWW template compound, separating the first portion of the MWW template compound from the mother liquor and recycling the first portion of the MWW template compound into a hydrothermal synthesis of a titanium-containing zeolitic material having framework type MWW.

A process comprising hydrothermally synthesizing a titanium-containing zeolitic material having framework type MWW in the presence of an MWW template compound, obtaining a mother liquor comprising water, a first portion of the MWW template compound and a titanium-containing zeolitic material having framework type MWW comprising a second portion of the MWW template compound, separating the first portion of the MWW template compound from the mother liquor and recycling the first portion of the MWW template compound into a hydrothermal synthesis of a titanium-containing zeolitic material having framework type MWW.

The invention relates to a molecular sieve SCM-15, a preparation process and use thereof. The molecular sieve comprises a schematic chemical composition of a formula of “SiO.sub.2.GeO.sub.2”, wherein the molar ratio of silicon and germanium satisfies SiO.sub.2/GeO.sub.2≥1. The molecular sieve has unique XRD diffraction data and can be used as an adsorbent or a catalyst.

The invention relates to a molecular sieve SCM-15, a preparation process and use thereof. The molecular sieve comprises a schematic chemical composition of a formula of “SiO.sub.2.GeO.sub.2”, wherein the molar ratio of silicon and germanium satisfies SiO.sub.2/GeO.sub.2≥1. The molecular sieve has unique XRD diffraction data and can be used as an adsorbent or a catalyst.

The invention relates to methods for hydrocracking or hydrotreating hydrocarbon containing feedstocks. This is accomplished via the use of a catalyst which comprises a β zeolite of *BEA framework, where a portion of aluminum atoms in the *BEA framework have been substituted by from 0.1-5.0 wt % of each of Ti and Zr, calculated on an oxide basis.

A method for preparing titanium-containing molecular sieves include the following steps: irradiating a mixed solution containing a silicon source, a template and a titanium source by a light source containing ultraviolet light before crystallization, and then subjecting the mixed solution to crystallization and post-treatment to obtain the titanium-containing molecular sieve. In the method for preparing titanium-containing molecular sieve of the present invention, the mixed solution containing the silicon source, the template and the titanium source is treated with the ultraviolet light, and free radicals generated by the ultraviolet light can effectively dissociate titanium oligomers and accelerate the hydrolysis of the silicon source, and thus match the hydrolysis rate of a silicon-titanium precursor, thereby preventing a titanium monomer from self-polymerization to form non-framework titanium. Therefore, a titanium-containing molecular sieve that does not contain the non-framework titanium can be quickly prepared.

A method for preparing titanium-containing molecular sieves include the following steps: irradiating a mixed solution containing a silicon source, a template and a titanium source by a light source containing ultraviolet light before crystallization, and then subjecting the mixed solution to crystallization and post-treatment to obtain the titanium-containing molecular sieve. In the method for preparing titanium-containing molecular sieve of the present invention, the mixed solution containing the silicon source, the template and the titanium source is treated with the ultraviolet light, and free radicals generated by the ultraviolet light can effectively dissociate titanium oligomers and accelerate the hydrolysis of the silicon source, and thus match the hydrolysis rate of a silicon-titanium precursor, thereby preventing a titanium monomer from self-polymerization to form non-framework titanium. Therefore, a titanium-containing molecular sieve that does not contain the non-framework titanium can be quickly prepared.

A process for the preparation of small aromatic compounds from black liquor comprising: providing black liquor that derives from alkaline treatment of wood chips; subjecting the black liquor to a pyrolysis treatment to yield a pyrolysed black liquor gas and a solid mass comprising char and salts in a first reactor, wherein the salts substantially derive from the treatment of black liquor; contacting at least part of the pyrolysed black liquor gas with a catalyst in a second reactor, which is different from the first reactor to provide a conversion treatment to yield a conversion product; and recovering small aromatic compounds from the conversion product.