The invention provides a method for synthesizing a mesoporous zeolite ETS-10 containing a metal without a templating agent. The method according to the invention comprises the steps of: mixing a silicon source with a NaOH solution to obtain a mixed solution so that the content of Na.sub.2O in the mixed solution is 10.0% to 20.0% by weight; adding a KOH or KF solution so that the content of K.sub.2O is 10.0% to 25.0% by weight and stirring it well; adding a titanium source solution and stirring it well; adding a precursor compound containing metal Ni and/or Co and stirring it well; and subjecting it to a crystallization reaction to obtain the mesoporous zeolite ETS-10. The mesoporous zeolite ETS-10 obtained by the invention has a specific surface area of 320 to 420 m.sup.2/g, a mesoporous volume of 0.11 to 0.21 cm.sup.3/g, and thus can be used as a catalyst and a support thereof in synthesis industry for macromolecular fine chemicals.

The invention provides a method for synthesizing a mesoporous zeolite ETS-10 containing a metal without a templating agent. The method according to the invention comprises the steps of: mixing a silicon source with a NaOH solution to obtain a mixed solution so that the content of Na.sub.2O in the mixed solution is 10.0% to 20.0% by weight; adding a KOH or KF solution so that the content of K.sub.2O is 10.0% to 25.0% by weight and stirring it well; adding a titanium source solution and stirring it well; adding a precursor compound containing metal Ni and/or Co and stirring it well; and subjecting it to a crystallization reaction to obtain the mesoporous zeolite ETS-10. The mesoporous zeolite ETS-10 obtained by the invention has a specific surface area of 320 to 420 m.sup.2/g, a mesoporous volume of 0.11 to 0.21 cm.sup.3/g, and thus can be used as a catalyst and a support thereof in synthesis industry for macromolecular fine chemicals.

The invention relates to a molecular sieve SCM-15, a preparation process and use thereof. The molecular sieve comprises a schematic chemical composition of a formula of SiO.sub.2.GeO.sub.2, wherein the molar ratio of silicon and germanium satisfies SiO.sub.2/GeO.sub.21. The molecular sieve has unique XRD diffraction data and can be used as an adsorbent or a catalyst.

The invention relates to a molecular sieve SCM-15, a preparation process and use thereof. The molecular sieve comprises a schematic chemical composition of a formula of SiO.sub.2.GeO.sub.2, wherein the molar ratio of silicon and germanium satisfies SiO.sub.2/GeO.sub.21. The molecular sieve has unique XRD diffraction data and can be used as an adsorbent or a catalyst.

The invention relates to a molecular sieve SCM-14, a preparation process and use thereof. The molecular sieve has a schematic chemical composition of a formula of SiO.sub.2.1/nGeO.sub.2 or a formula of kF.mQ.SiO.sub.2.1/nGeO.sub.2.pH.sub.2O, wherein the molar ratio of silicon to germanium, n, satisfies n30, and other values and symbols are defined in the specification. The molecular sieve has unique XRD diffraction data and can be used as an adsorbent or a catalyst.

The invention relates to a molecular sieve SCM-14, a preparation process and use thereof. The molecular sieve has a schematic chemical composition of a formula of SiO.sub.2.1/nGeO.sub.2 or a formula of kF.mQ.SiO.sub.2.1/nGeO.sub.2.pH.sub.2O, wherein the molar ratio of silicon to germanium, n, satisfies n30, and other values and symbols are defined in the specification. The molecular sieve has unique XRD diffraction data and can be used as an adsorbent or a catalyst.

In a process for the epoxidation of an olefin with hydrogen peroxide in the presence of a solvent, where a mixture comprising olefin, an aqueous hydrogen peroxide solution and a solvent is continuously passed through a fixed bed of an epoxidation catalyst comprising a titanium zeolite, addition of a chelating agent to the aqueous hydrogen peroxide solution before mixing it with solvent reduces or prevents formation of deposits on the catalyst and blocking of orifices of a liquid distributor.

In a process for the epoxidation of an olefin with hydrogen peroxide in the presence of a solvent, where a mixture comprising olefin, an aqueous hydrogen peroxide solution and a solvent is continuously passed through a fixed bed of an epoxidation catalyst comprising a titanium zeolite, addition of a chelating agent to the aqueous hydrogen peroxide solution before mixing it with solvent reduces or prevents formation of deposits on the catalyst and blocking of orifices of a liquid distributor.

Methods of simultaneously converting butanes and methanol to olefins over Ti-containing zeolite catalysts are described. The exothermicity of the alcohols to olefins reaction is matched by endothermicity of dehydrogenation reaction of butane(s) to light olefins resulting in a thermo-neutral process. The Ti-containing zeolites provide excellent selectivity to light olefins as well as exceptionally high hydrothermal stability. The coupled reaction may advantageously be conducted in a staged reactor with methanol/DME conversion zones alternating with zones for butane(s) dehydrogenation. The resulting light olefins can then be reacted with iso-butane to produce high-octane alkylate. The net result is a highly efficient and low cost method for converting methanol and butanes to alkylate.

Methods of simultaneously converting butanes and methanol to olefins over Ti-containing zeolite catalysts are described. The exothermicity of the alcohols to olefins reaction is matched by endothermicity of dehydrogenation reaction of butane(s) to light olefins resulting in a thermo-neutral process. The Ti-containing zeolites provide excellent selectivity to light olefins as well as exceptionally high hydrothermal stability. The coupled reaction may advantageously be conducted in a staged reactor with methanol/DME conversion zones alternating with zones for butane(s) dehydrogenation. The resulting light olefins can then be reacted with iso-butane to produce high-octane alkylate. The net result is a highly efficient and low cost method for converting methanol and butanes to alkylate.