The present disclosure is directed to large-pore germanosilicate compositions designated CIT-13/OH and CIT-14/IST, the two large-pore germanosilicate each having a three-dimensional framework with 10- and 14-membered ring channels and 8- and 12-membered ring channels, respectively. The disclosure also sets forth methods for converting the former to the latter under conditions consistent with an inverse sigma transformation. Uses of the large-pore germanosilicate compositions are also disclosed.

Provide is a functional structural body that can suppress aggregation of metal oxide nanoparticles and prevent functional loss of metal oxide nanoparticles, and thus exhibit a stable function over a long period of time. A functional structural body (1) includes: a skeletal body (10) of a porous structure composed of a zeolite-type compound; and at least one type of metal oxide nanoparticles (20) containing a perovskite-type oxide present in the skeletal body (10), the skeletal body (10) having channels (11) that connect with each other, and the metal oxide nanoparticles (20) being present at least in the channels (11) of the skeletal body (10).

Provide is a functional structural body that can suppress aggregation of metal oxide nanoparticles and prevent functional loss of metal oxide nanoparticles, and thus exhibit a stable function over a long period of time. A functional structural body (1) includes: a skeletal body (10) of a porous structure composed of a zeolite-type compound; and at least one type of metal oxide nanoparticles (20) containing a perovskite-type oxide present in the skeletal body (10), the skeletal body (10) having channels (11) that connect with each other, and the metal oxide nanoparticles (20) being present at least in the channels (11) of the skeletal body (10).

The present invention relates to a new chiral zeolite material of composition a SiO.sub.2:b GeO.sub.2:c X.sub.2O.sub.3:d YO.sub.2, with an ITV structure, prepared with a specific chiral organic structure-directing agent, (1S,2S)—N-ethyl-N-methyl-pseudoephedrine or its enantiomer, (1R,2R)—N-ethyl-N-methyl-pseudoephedrine, which means that the material is rich in one of the crystalline forms; a method whereby said material is obtained, and the use thereof in adsorption and catalysis processes.

The present invention relates to a new chiral zeolite material of composition a SiO.sub.2:b GeO.sub.2:c X.sub.2O.sub.3:d YO.sub.2, with an ITV structure, prepared with a specific chiral organic structure-directing agent, (1S,2S)—N-ethyl-N-methyl-pseudoephedrine or its enantiomer, (1R,2R)—N-ethyl-N-methyl-pseudoephedrine, which means that the material is rich in one of the crystalline forms; a method whereby said material is obtained, and the use thereof in adsorption and catalysis processes.

The present invention relates to a catalytic material for treating an exhaust gas produced by a natural gas engine, which catalytic material comprises a molecular sieve and a platinum group metal (PGM) supported on the molecular sieve, wherein the molecular sieve has a framework comprising silicon, oxygen, titanium and optionally germanium, and has a content of non-titanium heteroatom T-atoms of ≤ about 0.20 mol %, wherein the titanium is present in an amount of from 1 to 3 mol %. The present invention further relates to a catalyst article and to a compressed natural gas combustion and exhaust system.

The present invention relates to a catalytic material for treating an exhaust gas produced by a natural gas engine, which catalytic material comprises a molecular sieve and a platinum group metal (PGM) supported on the molecular sieve, wherein the molecular sieve has a framework comprising silicon, oxygen, titanium and optionally germanium, and has a content of non-titanium heteroatom T-atoms of ≤ about 0.20 mol %, wherein the titanium is present in an amount of from 1 to 3 mol %. The present invention further relates to a catalyst article and to a compressed natural gas combustion and exhaust system.

The present disclosure provides a method for preparing a molecular sieve catalyst. A water-in-oil micro-emulsion including a continuous phase containing an organic solvent and a dispersed phase containing an aqueous solution containing one or more metal salts and a water-soluble organic carbon source is prepared, hydrolyzed, and azeotropically distilled to form a mixture solution. The mixture solution is heated to carbonize the water-soluble organic carbon source to form nanoparticles each having a core-shell structure including a carbon-shelled metal-oxide. The nanoparticles containing the carbon-shelled metal-oxide are dispersed in a molecular sieve precursor solution. A nanoparticle-loaded molecular sieve is formed from the molecular sieve precursor solution containing the nanoparticles, and then calcined to remove carbon there-from to form a metal-oxide loaded molecular sieve.

The present disclosure provides a method for preparing a molecular sieve catalyst. A water-in-oil micro-emulsion including a continuous phase containing an organic solvent and a dispersed phase containing an aqueous solution containing one or more metal salts and a water-soluble organic carbon source is prepared, hydrolyzed, and azeotropically distilled to form a mixture solution. The mixture solution is heated to carbonize the water-soluble organic carbon source to form nanoparticles each having a core-shell structure including a carbon-shelled metal-oxide. The nanoparticles containing the carbon-shelled metal-oxide are dispersed in a molecular sieve precursor solution. A nanoparticle-loaded molecular sieve is formed from the molecular sieve precursor solution containing the nanoparticles, and then calcined to remove carbon there-from to form a metal-oxide loaded molecular sieve.

Described are compositions and catalytic articles comprising both a first molecular sieve promoted with copper and a second molecular sieve promoted with iron, the first and second molecular sieves having a d6r unit and the first molecular sieves having cubic shaped crystals with an average crystal size of about 0.5 to about 2 microns. The weight ratio of the copper-promoted molecular sieve to the iron-promoted molecular sieve can be about 1:1 to about 4:1. The catalytic articles are useful in methods and systems to catalyze the reduction of nitrogen oxides in the presence of a reductant.