B01J29/90

Regeneration method for benzene alkylation solid acid catalyst

A regeneration method for a benzene alkylation solid acid catalyst, comprising: purging the solid acid catalyst in a reactor with a gas; continuously injecting n-hexane at a feed port of the reactor and heating the n-hexane to wash the solid acid catalyst, and discharging the n-hexane entraining benzene alkylation reaction residues from a discharge port of the reactor; and stopping injecting n-hexane, cleaning off a liquid in the reactor by purging with the gas, and cooling the reactor. In the regeneration method of the present disclosure, the regeneration liquid used is n-hexane, which can increase the solubility of the residues in channels and enhance the regeneration effect. Meanwhile, permanent damage to the channel structure of the catalyst caused by carbon burning regeneration can be avoided, thereby prolonging the lifetime of the catalyst.

METHOD FOR PRODUCING LIGHT AROMATIC
20220389336 · 2022-12-08 ·

A method for producing light aromatics, includes the steps of: i) contacting a feedstock comprising heavy aromatic(s) with a catalyst in a fluidized reactor for aromatics lightening reaction in the presence of hydrogen to obtain a product rich in C6-C8 light aromatic(s) and a spent catalyst, wherein the heavy aromatic is one or more selected from C9+ aromatics; ii) separating the resulted product rich in C6-C8 light aromatic(s) to obtain hydrogen, a non-aromatic component, C6-C8 light aromatic(s) and a C9+ aromatic component; and iii) recycling at least a part of the C9+ aromatic component to the fluidized reactor. The method has strong adaptability to feedstocks and high flexibility in operation and allows a long-period stable operation. The method can produce high-value light aromatics from heavy aromatics that are difficult to be treated and utilized.

METHOD FOR PRODUCING LIGHT AROMATIC
20220389336 · 2022-12-08 ·

A method for producing light aromatics, includes the steps of: i) contacting a feedstock comprising heavy aromatic(s) with a catalyst in a fluidized reactor for aromatics lightening reaction in the presence of hydrogen to obtain a product rich in C6-C8 light aromatic(s) and a spent catalyst, wherein the heavy aromatic is one or more selected from C9+ aromatics; ii) separating the resulted product rich in C6-C8 light aromatic(s) to obtain hydrogen, a non-aromatic component, C6-C8 light aromatic(s) and a C9+ aromatic component; and iii) recycling at least a part of the C9+ aromatic component to the fluidized reactor. The method has strong adaptability to feedstocks and high flexibility in operation and allows a long-period stable operation. The method can produce high-value light aromatics from heavy aromatics that are difficult to be treated and utilized.

Method for partially regenerating methanol to olefin catalyst and methanol to olefin process

The present application discloses a method for partially regenerating a methanol to olefin catalyst, comprising: placing a deactivated methanol to olefin catalyst in a regenerator to carry out a partial regeneration reaction to obtain a regenerated catalyst; at least a portion of the regenerated catalyst has a coke amount of more than 1%. The present application discloses a methanol to olefin process, the methanol to olefin reaction is carried out in a fluidized bed with the use of a methanol to olefin catalyst, wherein at least a portion of the regenerated catalyst has a coke amount of more than 1%.

Method for partially regenerating methanol to olefin catalyst and methanol to olefin process

The present application discloses a method for partially regenerating a methanol to olefin catalyst, comprising: placing a deactivated methanol to olefin catalyst in a regenerator to carry out a partial regeneration reaction to obtain a regenerated catalyst; at least a portion of the regenerated catalyst has a coke amount of more than 1%. The present application discloses a methanol to olefin process, the methanol to olefin reaction is carried out in a fluidized bed with the use of a methanol to olefin catalyst, wherein at least a portion of the regenerated catalyst has a coke amount of more than 1%.

Two step process for chemically recycling plastic waste

A two-step process that includes a pyrolytic first step carried out in a mechanically or gravitationally impelled reactor and a catalytic fluid bed second step that upgrades the resulting vapor, for the conversion of waste plastics, polymers, and other waste materials to useful chemical and fuel products such as paraffins, olefins, and aromatics such as BTX is described.

Two step process for chemically recycling plastic waste

A two-step process that includes a pyrolytic first step carried out in a mechanically or gravitationally impelled reactor and a catalytic fluid bed second step that upgrades the resulting vapor, for the conversion of waste plastics, polymers, and other waste materials to useful chemical and fuel products such as paraffins, olefins, and aromatics such as BTX is described.

Catalytic pyrolysis of polystyrene into aromatic rich liquid product using spherical catalyst

The present invention provides a process of catalytic depolymerization of polystyrene involving a spherical catalyst, an apparatus for carrying out the depolymerization, recovering the aromatic rich liquid product and recycling the catalyst without any decrease in the catalytic performance. Further, the present invention provides that the aromatic rich liquid product includes styrene, xylene, benzene, ethyl benzene, with styrene content greater than 65%. Additionally, the catalyst involved in the depolymerization process is a spherical catalyst that is easily recovered from coke/char formed during the process and is recycled and reused without any decrease in the catalytic performance.

Catalytic pyrolysis of polystyrene into aromatic rich liquid product using spherical catalyst

The present invention provides a process of catalytic depolymerization of polystyrene involving a spherical catalyst, an apparatus for carrying out the depolymerization, recovering the aromatic rich liquid product and recycling the catalyst without any decrease in the catalytic performance. Further, the present invention provides that the aromatic rich liquid product includes styrene, xylene, benzene, ethyl benzene, with styrene content greater than 65%. Additionally, the catalyst involved in the depolymerization process is a spherical catalyst that is easily recovered from coke/char formed during the process and is recycled and reused without any decrease in the catalytic performance.

COKE CONTROL REACTOR, DEVICE FOR PREPARING LOW-CARBON OLEFINS FROM OXYGEN-CONTAINING COMPOUND, AND USE THEREOF

A coke control reactor, a device for preparing low-carbon olefins from an oxygen-containing compound, and a use thereof are provided. The coke control reactor includes a riser reactor and a bed reactor; the bed reactor includes a bed reactor shell, and the bed reactor shell encloses a reaction zone I, a transition zone, and a gas-solid separation zone I from bottom to top; a bed reactor distributor is arranged in the reaction zone I; a coke controlled catalyst delivery pipe is arranged outside the reaction zone I; an upper section of the riser reactor penetrates through a bottom of the bed reactor and is axially inserted in the bed reactor; and an outlet end of the riser reactor is located in the transition zone. The coke control reactor can control the conversion and generation of coke species in a catalyst.