B01J35/50

Composite catalyst, method for producing composite catalyst, method for producing lower olefin and method for regenerating composite catalyst

A lower olefin by using a zeolite catalyst, a composite catalyst capable of further extending the lifetime of catalytic activity, a method for producing the composite catalyst, a method for producing a lower olefin by using the composite catalyst, and a method for regenerating a composite catalyst in the method for producing a lower olefin are provided. The composite catalyst is a catalyst for producing a lower olefin from a hydrocarbon feedstock. This composite catalyst is constituted of a zeolite being a crystalline aluminosilicate containing gallium and iron or iron and further having a framework with 8- to 12-membered ring, and of silicon dioxide. By using the composite catalyst, a lower olefin can be continuously produced over a long period of time.

OXIDATIVE DEHYDROGENATION CATALYSTS

Provided in this disclosure are oxidative dehydrogenation catalysts that include a mixed metal oxide having the empirical formula:


Mo.sub.1.0V.sub.0.12-0.49Te.sub.0.05-0.17Nb.sub.0.10-0.20O.sub.d

wherein d is a number to satisfy the valence of the oxide. The oxidative dehydrogenation catalyst is characterized by having XRD diffraction peaks (2 degrees) at 220.2, 270.2, 28.00.2, and 28.30.1. The disclosure also provides methods of making the catalysts that include wet ball milling.

METHODS FOR PREPARATION AND USE OF LIQUID SYNTHESIS CATALYSTS
20200038846 · 2020-02-06 ·

Described herein are catalysts relating to liquid synthesis, methods of their preparation, and methods of their use. In an embodiment according to the present disclosure, a method of producing a catalyst for liquid synthesis comprises: providing a silica oxide support; pretreating the silica oxide support to remove air and moisture; impregnating the pretreated silica oxide support with cobalt from a cobalt source using a cobalt impregnation method; and calcinating the impregnated silica oxide support in an oven with a temperature ramping profile, wherein the calcinating comprises feeding air into the oven.

Catalyst for isobutylene production and method for producing isobutylene

Provided are: a catalyst for dehydration, with which isobutylene is able to be produced with high conversion and high selectivity through a dehydration reaction of isobutanol; and a method for producing isobutylene. This catalyst has a BET specific surface area within the range of from 210 m.sup.2/g to 350 m.sup.2/g (inclusive) as calculated from N.sub.2 adsorption/desorption isotherms. It is preferable that this catalyst is formed of at least one substance selected from among alumina, silica alumina, zeolite, and solid phosphoric acid. It is more preferable that this catalyst contains alumina, and it is especially preferable that this catalyst is formed of alumina. In this method for producing isobutylene, the isobutanol concentration in the starting material gas is preferably 20% by volume or more, more preferably 40% by volume or more, and especially preferably 60% by volume or more. In addition, the temperature of a catalyst layer is preferably from 230 C. to 370 C. (inclusive), and more preferably from 240 C. to 360 C. (inclusive).

Heavy Aromatics Conversion Processes and Catalyst Compositions Used Therein

Disclosed are processes for conversion of a feedstock comprising C.sub.8+ aromatic hydrocarbons to lighter aromatic products in which the feedstock and optionally hydrogen are contacted in the presence of the catalyst composition under conversion conditions effective to dealkylate and transalkylate said C.sub.8+ aromatic hydrocarbons to produce said lighter aromatic products comprising benzene, toluene and xylene. The catalyst composition comprises a zeolite, a first metal, and a second metal, and is treated with a source of sulfur and/or a source of steam.

Heavy Aromatics Conversion Processes and Catalyst Compositions Used Therein

Disclosed are processes for conversion of a feedstock comprising C.sub.8+ aromatic hydrocarbons to lighter aromatic products in which the feedstock and optionally hydrogen are contacted in the presence of a first and a second catalyst composition under conversion conditions effective to produce said lighter aromatic products comprising benzene, toluene and xylene. In the process, the C.sub.8+ aromatic hydrocarbons are dealkylated to form C.sub.6-C.sub.7 aromatic hydrocarbon and the C.sub.2+ olefins formed are saturated. The remaining C.sub.8+ aromatic hydrocarbons are transalkylated with the C.sub.6-C.sub.7 aromatic hydrocarbon. The first and second catalyst compositions each comprise a zeolite, a first metal, and optionally a second metal, and are treated with a source of sulfur and/or a source of steam.

NOVEL PGM NANOPARTICLES TWC CATALYSTS FOR GASOLINE EXHAUST GAS APPLICATIONS
20200030775 · 2020-01-30 ·

A three-way catalyst article, and its use in an exhaust system for internal combustion engines, is disclosed. The catalyst article for treating exhaust gas comprising: a substrate; and a first catalytic region on the substrate; wherein the first catalytic region comprises a first platinum group metal (PGM) component, wherein the first PGM component comprises PGM nanoparticles, wherein the PGM nanoparticles have an average particle size of about 1 to about 20 nm with a standard deviation (SD) no more than 1 nm.

CATALYTIC FORMS AND FORMULATIONS

Catalytic forms and formulations are provided. The catalytic forms and formulations are useful in a variety of catalytic reactions, for example, the oxidative coupling of methane. Related methods for use and manufacture of the same are also disclosed.

DECOMPOSITION OF CONDENSATION POLYMERS

Particles of a transition metal are used as a catalyst for depolymerisation of condensation polymers in alcohol. In the method of catalysed depolymerisation of a condensation polymer in a solid form into monomers and/or oligomers, transition metal particles; are mixed with the condensation polymer in alcohol to obtain a reaction mixture. This reaction mixture is processed to disperse the condensation polymer into the alcohol and decompose it, wherein the transition metal particles act as a catalyst and the alcohol is a reagent. The catalyst is particularly supplied as a catalyst composition of transition metal particles in an alcoholic liquid. The transition metal particles are typically non-porous and may have an oxide surface.

Plasmonic Nanoparticle Catalysts and Methods for Producing Long-Chain Hydrocarbon Molecules

A plasmonic nanoparticle catalyst for producing hydrocarbon molecules by light irradiation, which comprises at least one plasmonic provider and at least one catalytic property provider, wherein the plasmonic provider and the catalytic property provider are in contact with each other or have distance less than 200 nm, and molecular composition of the hydrocarbon molecules produced by light irradiation is temperature-dependent. And a method for producing hydrocarbon molecules by light irradiation utilizing the plasmonic nanoparticle catalyst.