Patent classifications
B01J35/60
A Short Channel Ordered Mesoporous Carbon Loaded Indium Cobalt Sulfide and Indium Nickel Sulfide Ternary Composite Photocatalyst, the Preparation Method Thereof and the Use Thereof
A short channel ordered mesoporous carbon loaded indium cobalt sulfide and indium nickel sulfide ternary composite photocatalyst, and a preparation method and application thereof. The short channel ordered mesoporous carbon loaded indium cobalt sulfide and indium nickel sulfide ternary composite photocatalyst is prepared by mixing pretreated short channel mesoporous carbon with cobalt salt, nickel salt, indium salt and reducing agent with a hydrothermal reaction. The short channel ordered mesoporous carbon is obtained by calcining a short channel ordered mesoporous silica and a carbon source under the protection of nitrogen, wherein the short channel ordered mesoporous silica is prepared by carrying out reactions of sol-gel-hydrothermal-calcination sequentially using a mixture of a surfactant, a hydrochloric acid solution, ammonium fluoride and tetraethyl orthosilicate. The photocatalyst has strong adsorption and visible light catalytic activity on VOCs, and can effectively adsorb and decompose the enriched VOCs in situ on the surface of the catalyst.
Olefin metathesis method using a catalyst containing aluminum and molybdenum
The invention relates to a process for the metathesis of olefins implemented with a catalyst comprising a mesoporous matrix and at least the elements molybdenum and aluminum, said elements being incorporated into said matrix by means of at least one precursor comprising molybdenum and aluminum.
Exhaust gas purification catalyst
The present invention is directed to address the following problem: in an exhaust gas purification catalyst comprising a dual catalyst of a combination of a startup catalyst and an underfloor catalyst, reduction in the gas diffusivity of the underfloor catalyst results in reduction in the use efficiency of a catalytic active site, resulting in reduction in purification performance. The present invention relates to an exhaust gas purification catalyst comprising a dual catalyst of a combination of a startup catalyst and an underfloor catalyst having a catalyst coating where a large number of voids are included, wherein high-aspect-ratio pores having an aspect ratio of 5 or more account for a certain rate or more of the whole volume of the voids, to thereby enhance the purification performance of the catalyst.
Ethoxylation catalyst and manufacturing method therefor
Disclosed is an ethoxylation catalyst having a BET specific surface area of 40 to 150 m.sup.2/g and including calcium sulfate particles including at least one kind of compound selected from the group consisting of calcium sulfate 0.5 hydrate and type III anhydrous calcium sulfate.
Electrode catalyst for fuel cell, electrode catalyst layer for fuel cell, method for producing the same, and membrane electrode assembly and fuel cell using the catalyst layer
The present invention relates to an electrode catalyst for fuel cell containing a catalyst carrier having carbon as a main component and a catalytic metal carried on the catalyst carrier, wherein the electrode catalyst for fuel cell has a ratio R (D/G intensity ratio) of a peak intensity of D band (D intensity) measured in the vicinity of 1620 cm.sup.1 to a peak intensity of G band (G intensity) measured in the vicinity of 1580 cm.sup.1 by Raman spectroscopy of more than 0.6 and 0.8 or less, and satisfies at least one of the (a) to (d). According to the present invention, an electrode catalyst for fuel cell excellent in gas transportability is provided.
Honeycomb structure
A honeycomb structure includes a pillar-shaped honeycomb structure body including porous partition walls defining and forming a plurality of cells which extend from an inflow end face to an outflow end face, and a porous outer wall surrounding the partition walls, a porous supporting bulge disposed to extend out from a circumference of the outer wall so that at least a part of the outer wall is exposed, and plugging portions arranged in open ends of the cells, and the supporting bulge has support portions and a side wall portion, and the partition walls and the outer wall of the honeycomb structure body and the support portions and the side wall portion of the supporting bulge are all formed monolithically by formation of a ceramic raw material.
Nickel-based mesoporous catalyst and use thereof in hydrogenation
A supported catalyst having a calcined, predominantly aluminum, oxide support and an active phase of 5 to 65% by weight nickel with respect to the total mass of the catalyst, said active phase having no group VIB metal, the nickel particles having a diameter less than or equal to 20 nm, said catalyst having a mesopore median diameter greater than or equal to 14 nm, a mesopore volume measured by mercury porosimetry greater than or equal to 0.45 mL/g, a total pore volume measured by mercury porosimetry greater than or equal to 0.45 mL/g, a macropore volume less than 5% of the total pore volume, said catalyst being in the form of grains having an average diameter comprised between 0.5 and 10 mm. The invention also relates to the process for the preparation of said catalyst and the use thereof in a hydrogenation process.
Gd-containing, anti-coking solid acid catalysts and preparation method and use thereof
The present invention relates to an anti-coking catalyst having a physical property of reducing coke formation, which comprises a solid acid catalyst containing gadolinium (Gd) on the surface, a preparation method thereof, and a use thereof. The preparation method includes a first step of determining the amount of gadolinium (Gd) or a Gd-providing precursor to be used relative to the total weight of the solid acid catalyst, which reducing the coking of a specific solid acid catalyst below a specific level under a specific reaction condition; and a second step of preparing a Gd-containing solid acid catalyst using the amount determined in the first step. The catalyst according to the present invention is a catalyst in which an appropriate weight ratio of gadolinium is supported on the surface of a pure solid acid substance or solid acid substance on which a specific metal is supported. Therefore, the production of coke on the catalyst surface is inhibited while maintaining the activity of the solid acid catalyst in a hydrocarbon conversion reaction, and as a result, the catalyst of the present invention exhibits an effect of improving its lifespan.
ZEOLITE ADSORBENT IN THE FORM OF LOW-TORTUOSITY AGGLOMERATES
Provided is a zeolite-based adsorbent in the form of agglomerates, where the adsorbent having a tortuosity factor, calculated from the pore distribution determined by mercury intrusion porosimetry, of greater than 1 and less than 3. The adsorbent also has a porosity as determined by mercury intrusion porosimetry of between 25% and 35%. The adsorbent is useful in the field of separations in particular in a process for separating para-xylene from aromatic hydrocarbon isomer fractions containing 8 carbon atoms.
CATALYST STRUCTURE AND METHOD OF UPGRADING HYDROCARBONS IN THE PRESENCE OF THE CATALYST STRUCTURE
A catalyst structure includes a porous support structure, where the support structure includes an aluminosilicate material and any two or more metals loaded in the porous support structure selected from Ga, Ag, Mo, Zn, Co and Ce. The catalyst structure is used in a hydrocarbon upgrading process that is conducted in the presence of methane, nitrogen or hydrogen.