Patent classifications
B01J35/60
Platinum/palladium zeolite catalyst
The invention relates to a method for producing a bimetallic catalyst containing palladium and platinum on a zeolitic carrier material, to a bimetallic catalyst that can be obtained by means of the method, and to the use of the catalyst in oxidation catalysis.
Egg-shell type hybrid structure of highly dispersed nanoparticle-metal oxide support, preparation method thereof, and use thereof
The present invention relates to an egg-shell type hybrid structure of highly dispersed nanoparticles-metal oxide support, a preparation method thereof, and a use thereof. Specifically, the present invention relates to an egg-shell type hybrid structure of highly dispersed nanoparticles-metal oxide support, providing an excellent platform in a size of nanometers or micrometers which can support nanoparticles selectively in the porous shell portion by employing a metal oxide support with an average diameter of nanometers or micrometers including a core of nonporous metal oxide and a shell of porous metal oxides, a preparation method thereof, and a use thereof.
Catalyst for purification of exhaust gas, method for producing the same, and method for purification of exhaust gas using the same
A catalyst for purification of exhaust gas, wherein a substrate and a catalyst coat layer which is formed on a surface of the substrate and which comprises catalyst particles, wherein the catalyst coat layer has an average thickness in a range of 25 to 160 m, and a void fraction in a range of 50 to 80% by volume as measured by a weight-in-water method, 0.5 to 50% by volume of all voids in the catalyst coat layer consist of high-aspect ratio pores which have equivalent circle diameters in a range of 2 to 50 m in a cross-sectional image of a cross-section of the catalyst coat layer which the cross-section is perpendicular to a flow direction of exhaust gas in the substrate, and which have aspect ratios of 5 or higher, and the high-aspect ratio pores have an average aspect ratio in a range of 10 to 50.
Bound catalyst for selective conversion of oxygenates to aromatics
A catalyst composition includes a zeolite, a binder, and a Group 12 transition metal selected from the group consisting of Zn, Cd, or a combination thereof, the zeolite having a silicon to aluminum ratio of at least about 10, the catalyst composition comprising about 50 wt % or less of the binder based on a total weight of the catalyst composition, the catalyst composition having a micropore surface area of at least about 340 m.sup.2/g, a molar ratio of Group 12 transition metal to aluminum of about 0.1 to about 1.3, and at least one of (a) a mesoporosity of greater than about 20 m.sup.2/g; (b) a diffusivity for 2,2-dimethylbutane of greater than about 110.sup.2 sec.sup.1 when measured at a temperature of about 120 C. and a 2,2-dimethylbutane pressure of about 60 torr (about 8 kPa).
NICKEL DIATOMACEOUS EARTH CATALYST AND METHOD FOR PRODUCING THE SAME
A nickel diatomaceous earth catalyst having a weight loss rate measured by hydrogen-TG at 400 to 600? C. of 0.05 to 2.0%.
Alumina bound catalyst for selective conversion of oxygenates to aromatics
A catalyst composition comprising a zeolite, an alumina binder, and a Group 12 transition metal selected from Zn and/or Cd, the zeolite having a Si/Al ratio of at least about 10 and a micropore surface area of at least about 340 m.sup.2/g, the catalyst composition comprising about 50 wt % or less of the binder, based on a total weight of the catalyst composition, and having a micropore surface area of at least about 290 m.sup.2/g, a molar ratio of Group 12 transition metal to aluminum of about 0.1 to about 1.3, and at least one of: a mesoporosity of about 20 m.sup.2/g to about 120 m.sup.2/g; a diffusivity for 2,2-dimethylbutane of greater than about 110.sup.2 sec.sup.1 when measured at a temperature of about 120 C. and a 2,2-dimethylbutane pressure of about 60 torr (8 kPa); and a combined micropore surface area and mesoporosity of at least about 380 m.sup.2/g.
Support carbon material and catalyst for solid polymer type fuel cell use
A support carbon material able to support a catalyst metal in a highly dispersed state and resistant to the flooding phenomenon and with little voltage drop even at the time of large current power generation under high humidity conditions and a catalyst using the same, specifically, a support carbon material for solid polymer type fuel cell use comprised of a porous carbon material which has a pore volume and a pore area found by the BJH analysis method from a nitrogen adsorption isotherm in an adsorption process of a radius 2 nm to 50 nm pore volume V.sub.A of 1 ml/g to 5 ml/g and a radius 2 nm to 50 nm pore area S.sub.2-50 of 300 m.sup.2/g to 1500 m.sup.2/g and a ratio (V.sub.5-25/V.sub.A) of radius 5 nm to 25 nm pore volume V.sub.5-25 (ml/g) to said pore volume V.sub.A (ml/g) of 0.4 to 0.7 and a ratio (V.sub.2-5/V.sub.A) of radius 2 nm to 5 nm pore volume V.sub.2-5 (ml/g) to the same of 0.2 to 0.5 and a catalyst using the same.
Porous body, honeycomb filter, method for producing porous body, and method for producing honeycomb filter
A porous body constituting a porous partition wall 44 of a honeycomb filter 30 has a porosity P of 20% to 60%, a permeability k of 1 m.sup.2 or more and satisfies k0.2823 P10.404. The porous body is obtained by a method for producing, for example, includes (a) a step of acquiring porous body data representing a temporary porous body having porosity higher than target porosity, (b) a step of deriving information about a flow rate for each space voxel during passage of a fluid through inside of the porous body, (c) a step of preferentially replacing the voxel having a low flow rate among the space voxels with the object voxel, and adjusting the porosity of the porous body data to the target porosity, and (d) a step of forming a porous body based on the porous body data after replacement.
Catalyst carrier, method for producing catalyst carrier, and use of catalyst carrier
A catalyst carrier, an electrode catalyst, an electrode including the catalyst, a membrane electrode assembly including the electrode, a fuel cell including the membrane electrode assembly, and a method for producing the catalyst carrier. The catalyst carrier includes a carbon material having a chain structure including a chain of carbon particles. The catalyst carrier contains a titanium compound-carbon composite particle in which carbon encloses a titanium compound particle. The molar ratios of a carbon element, a nitrogen element, and an oxygen element to a titanium element taken as 1 in the catalyst carrier are more than 0 and 50 or less, more than 0 and 2 or less, and more than 0 and 3 or less, respectively.
Hydrocarbon conversion processes using metal carbide nanomaterial catalysts
A catalyst that includes heterogeneous metal carbide nanomaterials and a novel preparation method to synthesize the metal carbide nanomaterials under relatively mild conditions to form an encapsulated transition metal and/or transition metal carbide nanoclusters in a support and/or binder. The catalyst may include confined platinum carbide nanoclusters. The preparation may include the treatment of encapsulated platinum nanoclusters with ethane at elevated temperatures. The catalysts may be used for catalytic hydrocarbon conversions, which include but are not limited to, ethane aromatization, and for selective hydrogenation, with negligible green oil production.