B01J35/70

Process for the production of a carbon supported catalyst

A process for the production of a carbon supported catalyst, which comprises the following steps: (a) precipitation of at least one metal oxide onto a surface of a carbon-comprising support by preparing an initial mixture, comprising the carbon-comprising support, at least one metal oxide precursor and an organic solvent, and spray-drying of the initial mixture to obtain an intermediate product, (b) loading of noble-metal-comprising particles onto the surface of the intermediate product in a liquid medium by deposition, precipitation and/or reduction of a noble-metal-comprising precursor with a reducing agent, (c) heat treatment of the catalyst precursor resulting from step (b) at a temperature higher than 400 C.

Method for deposition of noble metal nanoparticles on catalysts to promote same, and the compositions so produced

A method for promoting the supported catalysts using noble metal nanoparticles. Different noble metal precursors are preferentially deposited onto the supported metal catalysts through Chemical vapor deposition (CVD), and compositions so produced. Further, the promoted catalyst is used for CO and CO.sub.2 hydrogenation reactions, increasing the reaction conversion, C.sub.5+ compounds selectivity and chain growth probability. The active phase of catalyst can be either cobalt oxide, nickel oxide or their reduced format (Co.sup.0 or Ni.sup.0), and the noble metal is preferably Ruthenium.

Core-shell oxide material, method for producing the same, and catalyst and method for purification of exhaust gas using the core-shell oxide material

A core-shell oxide material comprises: a core which comprises a ceria-zirconia based solid solution powder having at least one ordered phase of a pyrochlore phase and a phase; and a shell which comprises an alumina based oxide disposed on at least a portion of a surface of the core.

Binderless molecular sieve catalyst and a preparation method thereof

The present invention relate to a binderless molecular sieve catalyst and a process for preparing the same, which are mainly useful for solving the problems of the current catalysts, such as lower activity, less pore volume and worse diffusivity. The present invention relates to a novel binderless molecular sieve catalyst, comprising, based on the weight of the catalyst, 90-100 wt. % of a molecular sieve, 0-10 wt. % of a binder, and 0-10 wt. % of an anti-wear agent, wherein said catalyst has a pore volume of 0.1-0.5 ml/g, an average pore diameter of 50-100 nm, and a porosity of 20-40%; the anti-wear agent is selected from the rod or needle-like inorganic materials having a length/diameter ratio of 2-20. Said catalyst has the advantages of higher activity, greater pore volume, larger average pore diameter and porosity, and better diffusivity, and well solves said problems and can be used for the industrial preparation of binderless molecular sieve catalysts.

Catalytic cracking catalyst, process for producing the same, and method of catalytic cracking of hydrocarbon oil

A catalytic cracking catalyst is provided which has high cracking activity and with which the production of FCC gasoline having a high octane number can efficiently proceed without lowering a gasoline yield. Also provided are a process for producing the catalyst and a method of the catalytic cracking of a hydrocarbon oil with the catalyst. The catalyst for catalytic cracking of a hydrocarbon oil comprises a crystalline aluminosilicate, a binder, and a clay mineral in a certain proportion, wherein the content of sodium and potassium therein is 0.5% by mass or lower in terms of oxide (Na.sub.2O and K.sub.2O) amount, the content of at least one rare earth metal therein is 3.0% by mass or lower in terms of oxide (RE.sub.2O.sub.3, wherein RE is a rare earth element) amount, the [RE.sub.2O.sub.3+Na.sub.2O+K.sub.2O]/[crystalline aluminosilicate] ratio by mass is 0.1 or lower, and the catalyst has a xenon adsorption amount, as measured at an adsorption temperature of 25 C. and a partial xenon pressure of 650 torr, of 2.2010.sup.20 molecules or more per g of the catalyst. Also provided are a process for producing the catalyst and a method of catalytic cracking of a hydrocarbon oil with the catalyst.

Process for the production of alkenols and use thereof for the production of 1,3-butadiene

Process for the production of alkenols comprising the dehydration of at least one diol in the presence of at least one catalyst based on cerium oxide, wherein said catalyst based on cerium oxide is obtained by precipitation, in the presence of at least one base, of at least one compound containing cerium. Preferably, said diol may be a butanediol, more preferably 1,3-butanediol, still more preferably bio-1,3-butanediol derived from biosynthetic processes. Said alkenols may advantageously be used for the production of 1,3-butadiene, in particular of bio-1,3-butadiene.

Multifunctional cerium-based nanomaterials and methods for producing the same

Embodiments relate to a cerium-containing nano-coating composition, the composition including an amorphous matrix including one or more of cerium oxide, cerium hydroxide, and cerium phosphate; and crystalline regions including one or more of crystalline cerium oxide, crystalline cerium hydroxide, and crystalline cerium phosphate. The diameter of each crystalline region is less than about 50 nanometers.

Enhanced catalytic activity at the stoichiometric condition of zero-PGM catalysts for TWC applications

The present disclosure relates to zero-PGM (ZPGM) catalysts including variations of Nickel-doped Copper-Manganese spinel for improved catalyst performance at the stoichiometric condition for use within three-way catalyst (TWC) applications. The ZPGM catalyst material compositions within the aforementioned ZPGM catalysts are expressed with general formulas of Cu.sub.1-XNi.sub.XMn.sub.2O.sub.4 (A-site substitution) and Cu.sub.1Mn.sub.2-XNi.sub.XO.sub.4 (B-site substitution). The ZPGM catalysts are subjected to a TWC isothermal steady-state sweep test to assess the catalytic performance (e.g., NO conversion). Test results indicate the ZPGM catalysts exhibit higher NO conversions, at stoichiometric condition and lean conditions, when Ni substituted the B-site cation of the CuMn spinel as compared to Ni substituted the A-site cation of the CuMn spinel. Additionally, NO conversions of the ZPGM catalysts are significantly affected, at the stoichiometric condition, by the molar ratio of the Ni dopant within the A or B-site cation of the CuMn spinel.

FUNCTIONAL NANOSCALE METAL OXIDES FOR STABLE METAL SINGLE ATOM AND CLUSTER CATALYSTS
20240416325 · 2024-12-19 ·

A nanocomposite catalyst includes a support, a multiplicity of nanoscale metal oxide clusters coupled to the support, and one or more metal atoms coupled to each of the nanoscale metal oxide clusters. Fabricating a nanocomposite catalyst includes forming nanoscale metal oxide clusters including a first metal on a support, and depositing one or more metal atoms including a second metal on the nanoscale metal oxide clusters. The nanocomposite catalyst is suitable for catalyzing reactions such as CO oxidation, water-gas-shift, reforming of CO.sub.2 and methanol, and oxidation of natural gas.

A METHOD FOR PRODUCING RENEWABLE GAS, RENEWABLE NAPHTHA, AND RENEWABLE JET FUEL

The present invention relates to a method for producing renewable gas D, renewable naphtha E, and renewable jet fuel F or components thereto from a renewable feedstock A, in particular to methods comprising separate hydrodeoxygenation (20) and hydroisomerization steps (40) wherein the hydroisomerization is performed in the presence of a metal impregnated ZSM-23 catalyst.