Patent classifications
B01J37/0081
Methods for preparing diol
Provided is a method for preparing a diol. In the method, a saccharide and hydrogen as raw materials are contacted with a catalyst in water to prepare the diol. The employed catalyst is a composite catalyst comprised of a main catalyst and a cocatalyst, wherein the main catalyst is a water-insoluble acid-resistant alloy; and the cocatalyst is a soluble tungstate and/or soluble tungsten compound. The method uses an acid-resistant, inexpensive and stable alloy needless of a support as a main catalyst, and can guarantee a high yield of the diol in the case where the production cost is relatively low.
ALUMINUM BASED METALLIC GLASS POWDER FOR EFFICIENT DEGRADATION OF AZO DYE AND OTHER TOXIC ORGANIC CHEMICALS
The present invention provides amorphous bi-functional catalytic aluminum metallic glass particles having an aluminum metallic glass core and 2 or more transition metals disposed on the surface of the aluminum metallic glass core to form amorphous bi-functional aluminum metallic glass particles with catalytic activity.
Aluminum based metallic glass powder for efficient degradation of AZO dye and other toxic organic chemicals
The present invention provides amorphous bi-functional catalytic aluminum metallic glass particles having an aluminum metallic glass core and 2 or more transition metals disposed on the surface of the aluminum metallic glass core to form amorphous bi-functional aluminum metallic glass particles with catalytic activity.
A CATALYTICALLY ACTIVE PRODUCT AND A METHOD OF PRODUCING SUCH A CATALYTICALLY ACTIVE PRODUCT
A method of producing a catalytically active product (10) is disclosed. The method comprises providing a substrate (11) and depositing a first material (12) and particles (13) of a second material on the substrate, wherein the particles (13) of the second material have a higher melting point than the first material (12). Then, the substrate (11) with the first material (12) and said particles (13) is heated to a temperature where the first material (12) is melted and the particles (13) of the second material are not melted, wherein the first material (12) and the particles (13) are adhered to the substrate (11), wherein particles (13) are partly embedded in the first material (12) and form a rough surface. A ceramic material is deposited on the rough surface formed by the particles (13) to form a ceramic layer (14) thereon, wherein a catalytically active material (16) id added to the ceramic layer (14). Disclosed is also a catalytically active product.
Methane steam reforming, using nickel/alumina nanocomposite catalyst or nickel/silica-alumina hybrid nanocomposite catalyst
The present invention relates to a method of methane steam reforming using a nickel/alumina nanocomposite catalyst. More specifically, the present invention relates to a method of carrying out methane steam reforming using a nickel/alumina nanocomposite catalyst wherein nickel metal nanoparticles are uniformly loaded in a high amount on a support via a melt infiltration method with an excellent methane conversion even under a relatively severe reaction condition of a high gas hourly space velocity or low steam supply, and to a catalyst for this method. In addition, the present invention prepares a nickel/silica-alumina hybrid nanocatalyst by mixing the catalyst prepared by the melt infiltration method as the first catalyst and the nickel silica yolk-shell catalyst as the second catalyst, and applies it to the steam reforming of methane to provide a still more excellent catalytic activity even under the higher temperature of 700 C. or more with the excellent methane conversion.
Method for the Preparation of a Vanadium Based Catalyst
Method for the preparation of a catalyst comprising vanadium pentoxide supported on a metal oxide catalyst carrier comprising the steps of a) providing particles of crystalline vanadium pentoxide and particles of a metal oxide catalyst carrier; b) solid state mixing the particles and dispersing the vanadium pentoxide particles on surface of the metal oxide carrier particles; and c) anchoring the dispersed vanadium pentoxide particles on surface of the metal oxide carrier particles by calcination at a temperature above 500? C., characterized in that sintering of the vanadium pentoxide particles is suppressed by addition of an anti-sintering metal oxide component, such as tungsten trioxide, during the anchoring in step c).
CATALYST COMPOSITION
A catalyst composition comprising an intermetallic compound is disclosed. The intermetallic compound comprises a transition metal selected from Fe, Ce, Y, Nb and combinations thereof; and a noble metal selected from Pt, Pd, Rh and combinations thereof. The invention further relates to a washcoat comprising the catalyst composition, and a catalyst article comprising the catalyst composition, a method of treating exhaust gas with the catalyst article, a method for manufacturing the catalyst article and systems comprising the catalyst article.
SUPPORTED NOBLE METAL CATALYST, PREPARATION METHOD THEREFOR AND USE THEREOF
A method for preparing a supported noble metal catalyst, comprising: i) melting a noble metal sponge, a peroxide, and a support and/or a support precursor together; ii) dispersing the molten mixture in water; and iii) adjusting the pH to 4 to 10, thereby obtaining a supported noble metal catalyst. The method uses a noble metal sponge rather than an intermediate noble metal precursor, such as a noble metal nitrate salt, a noble metal halide salt, a halogenated noble metal acid, or a salt of the halogenated noble metal acid, for example, H.sub.3IrCl.sub.6, H.sub.2IrCl.sub.6, or IrCl.sub.3. The method does not produce any intermediate product, and does not use any chlorine-containing material, thereby avoiding contamination of the final catalyst by chlorine. The catalyst produced by the present invention has high activity, high surface area, and the RDE OER overpotential is less than 230 mV (at 10 mA cm.sup.2).
MOLTEN IRON CATALYST FOR PRODUCING HIGH-CARBON ALPHA-OLEFINS FROM SYNTHESIS GAS AND PREPARATION METHOD AND APPLICATION THEREOF
The present application relates to the technical field of chemical production, and particularly relates to a molten iron catalyst for high-temperature Fischer-Tropsch synthesis, a preparation method of the molten iron catalyst and an application of the molten iron catalyst in preparation of high-carbon ?-olefin from synthesis gas. The molten iron catalyst comprises iron oxides and a cocatalyst, and mass contents of components are: potassium oxide per 0.1-1 g/100gFe; strontium oxide 0.1-1 g/100gFe; manganese oxide 1-20 g/100gFe, and rare earth metal oxides 1-10 g/100gFe; the rest is iron oxides. The molar ratio of ferric iron to double ferrous iron in the iron oxides, namely Fe.sup.3+/2Fe.sup.2+, is 0.4-1.5. The application aims to provide a molten iron catalyst with high strength, high activity, and high selectivity of higher ?-olefin.
Process for preparing 3 aminomethyl-3,5,5-trimethylcyclohexylamine
Process for preparing isophoronediamine, characterized in that A) isophoronenitrile is subjected directly in one stage to aminating hydrogenation to give isophoronediamine in the presence of ammonia, hydrogen, a hydrogenation catalyst and possibly further additions, and in the presence or absence of organic solvents; or B) isophoronenitrile is first converted fully or partly in at least two or more than two stages to isophoronenitrile imine, and this isophoronenitrile imine is subjected to aminating hydrogenation to give isophoronediamine as a pure substance or in a mixture with other components and/or isophoronenitrile, in the presence of at least ammonia, hydrogen and a catalyst.