Patent classifications
B01J37/02
A METHOD OF PRODUCING A CERAMIC SUPPORT AND A CERAMIC SUPPORT
Herein is disclosed a method of producing a ceramic support suitable for a catalyst, the method comprising providing a porous ceramic structure, comprising a body portion with a monomodal macropore structure, wherein the macropores comprises a first mean pore size; washcoating the porous ceramic structure using a suspension comprising oxide and/or hydroxide nanoparticles and drying and calcinating the washcoated porous ceramic structure at a temperature below the melting point of the nanoparticles. In addition, the ceramic support and its structure is disclosed.
REFORMING CATALYST
A novel steam reforming catalyst comprising hibonite and potassium beta-alumina with improved resilience, improved activity, reduced potassium leaching and reduced coking problems. It also regards a method for producing the novel catalyst and uses of the novel catalyst in reforming reactors, in a plant for producing hydrogen gas, or in a plant for producing synthesis gas.
CATALYST AND CATALYST GROUP
A catalyst may suppress pressure loss and coaking and produce a target substance in high yield when a gas-phase catalytic oxidation reaction of a material substance is conducted using the catalyst to produce the target substance. A ring-shaped catalyst may have a straight body part and a hollow body part, which is used when a gas-phase catalytic oxidation reaction of a material substance is conducted to produce a target substance, wherein a length of the straight body part is shorter than a length of the hollow body part and at least at one end part, a region from an end part of the straight body part to an end part of the hollow body part is concavely curved.
EXHAUST GAS TREATMENT SYSTEM COMPRISING A MULTIFUNCTIONAL CATALYST
The present invention relates to an exhaust gas treatment system for treating exhaust gas from a lean burn combustion engine, wherein said exhaust gas comprises hydrocarbons and NOx, the exhaust gas treatment system comprising: (i) a means for injecting hydrocarbons into an exhaust gas stream; (ii) a diesel oxidation catalyst (DOC) comprising a substrate and a catalyst coating provided on the substrate, wherein the catalyst coating comprises one or more platinum group metals, wherein the one or more platinum group metals comprise platinum; (iii) a means for injecting a nitrogenous reducing agent into an exhaust gas stream; and (iv) a multifunctional catalyst (MFC) comprising an oxidation catalyst, and a selective catalytic reduction (SCR) catalyst for the selective catalytic reduction of NOx, wherein the MFC comprises a substrate and a catalyst coating provided on the substrate, wherein the catalyst coating comprises the oxidation catalyst and the SCR catalyst, wherein the oxidation catalyst comprises one or more platinum group metals, wherein the one or more platinum group metals comprise palladium and/or platinum, and wherein the SCR catalyst comprises a zeolitic material loaded with copper and/or iron; wherein the means for injecting hydrocarbons, the DOC, the means for injecting a nitrogenous reducing agent, and the MFC are located in sequential order in a conduit for exhaust gas, wherein the means for injecting hydrocarbons into an exhaust gas stream is located upstream of the DOC, wherein the DOC is located upstream of the MFC, and wherein the means for injecting a nitrogenous reducing agent into the exhaust gas stream is located between the DOC and the MFC. Furthermore, the present invention relates to a method for the treatment of exhaust gas using the exhaust gas treatment system according to the present invention, and to a method for the preparation of an exhaust gas treatment system according to the present invention.
DOPING GRADIENT-BASED PHOTOCATALYSIS
A photocatalytic device includes a substrate having a surface, and an array of conductive projections supported by the substrate and extending outward from the surface of the substrate. Each conductive projection of the array of conductive projections has a semiconductor composition. The semiconductor composition establishes a photochemical diode. The surface may be nonplanar such that subsets of the array of conductive projections are oriented at different angles.
ANIONIC PGM CARBOXYLATE ASSISTED PGM NANOPARTICLE SYNTHESIS FOR EXHAUST GAS TREATMENT APPLICATIONS
A method of manufacturing a catalyst article, the method comprising: providing an anionic complex comprising a PGM and a carboxylate ion; providing a support material; applying the anionic complex to the support material to form a loaded support material; disposing the loaded support material on a substrate; and heating the loaded support material to form nanoparticles of the PGM on the support material.
Supported zeolite films and methods for preparing
A method for producing a crystalline film comprising zeolite and/or zeolite-like crystals on a porous substrate is described. The method has the steps of: providing a porous support; modifying at least a surface of the top-layer of said porous support by treatment with a composition having one or more cationic polymer(s); rendering at least the outer surface of said porous support hydrophobic by treatment with a composition having one or more hydrophobic agent(s); subjecting said treated porous support to a composition having zeolite and/or zeolite-like crystals thereby depositing and attaching zeolite and/or zeolite-like crystals on said treated porous support, and growing a crystalline film of zeolite and/or zeolite-like crystals on said treated porous support and calcination. Crystalline films find use in a variety of fields such as in the production of membranes, catalysts etc.
PHOSPHORUS ELEMENT-CONTAINING ZEOLITE AND METHOD FOR PRODUCING PHOSPHORUS ELEMENT-CONTAINING ZEOLITE
A small-pore zeolite that is modified with phosphorus, is excellent in hydrothermal durability, and has an 8-membered oxygen ring structure. The 8-membered oxygen ring structure is CHA, AEI, and AFX. The small-pore zeolite incudes at least an aluminum element, a silica element, a phosphorus element, wherein the phosphorus element is defined by expression (1), and the small-pore zeolite has an 8-membered oxygen ring structure being of CHA, AEI, or AFX. The phosphorus element that modifies the zeolite is unevenly distributed and richly contained on the surface layer side of the zeolite. A method for producing a phosphorus element-containing zeolite.
METAL OXIDE-BASED SCR CATALYST COMPOSITION
The present disclosure provides SCR catalyst compositions capable of reducing nitrogen oxide (NO.sub.x) emissions in engine exhaust. The catalyst compositions include a reducible metal oxide support containing ceria, one or more transition metal oxides as a redox promotor; and an oxide of niobium, tungsten, silicon, molybdenum, or a combination thereof as an acidic promotor. The redox promotor and the acid promotor are both supported on the reducible metal oxide support. Further provided are SCR catalyst articles coated with such compositions, processes for preparing such catalyst compositions and articles, an exhaust gas treatment system including such catalyst articles, and methods for reducing NO.sub.x in an exhaust gas stream using such catalyst articles and systems.
SYSTEM AND METHOD FOR SOLAR-POWERED DESALINATION AND WATER PURIFICATION
A novel solar-powered desalination and water purification system is disclosed herein. The system includes a nanofiber-impregnated graphene aerogel, an untreated water source, a water collection surface, and a purified water storage container. A novel photocatalytic nanofiber-impregnated graphene aerogel for desalination and photodegradation of contaminants for use in the disclosed system is also disclosed herein. The nanofiber-impregnated graphene aerogel exhibits excellent hydrophilicity, thermal insulation, and photodegradation capability, and allows for efficient solar-powered evaporation of water. The introduction of photocatalytic nanofibers into the graphene aerogel allows effective interfacial evaporation and in situ photodegradation of contaminants. The rate of water evaporation is preferably greater than 1.3 gal/ft.sup.2 per day, and the contaminant removal is preferably greater than 90%. A method of desalinating and purifying water using the disclosed system is also disclosed herein.