Patent classifications
B01J37/16
Ammonia membrane reactor comprising a composite membrane
The present specification discloses a membrane reactor comprising a reaction region; a permeate region; and a composite membrane disposed at a boundary of the reaction region and the permeate region, wherein the reaction region comprises a bed filled with a catalyst for dehydrogenation reaction, wherein the composite membrane comprises a support layer including a metal with a body-centered-cubic (BCC) crystal structure, and a catalyst layer including a palladium (Pd) or a palladium alloy formed onto the support layer, wherein ammonia (NH.sub.3) is supplied to the reaction region, the ammonia is converted into hydrogen (H.sub.2) by the dehydrogenation reaction in the presence of the catalyst for dehydrogenation reaction, and the hydrogen permeates the composite membrane and is emitted from the membrane reactor through the permeate region.
Chromium-based catalysts and processes for converting alkanes into higher and lower aliphatic hydrocarbons
Processes for cracking an alkane reactant to form a lower aliphatic hydrocarbon product and for converting an alkane reactant into a higher aliphatic hydrocarbon product are disclosed, and these processes include a step of contacting the alkane reactant with a supported chromium (II) catalyst. In addition to the formation of various aliphatic hydrocarbons, such as linear alkanes, branched alkanes, 1-alkenes, and internal alkenes, aromatic hydrocarbons and hydrogen also can be produced.
Chromium-based catalysts and processes for converting alkanes into higher and lower aliphatic hydrocarbons
Processes for cracking an alkane reactant to form a lower aliphatic hydrocarbon product and for converting an alkane reactant into a higher aliphatic hydrocarbon product are disclosed, and these processes include a step of contacting the alkane reactant with a supported chromium (II) catalyst. In addition to the formation of various aliphatic hydrocarbons, such as linear alkanes, branched alkanes, 1-alkenes, and internal alkenes, aromatic hydrocarbons and hydrogen also can be produced.
TRANSITION METAL ELECTROCHEMICAL CATALYST PREPARED USING ULTRAFAST COMBUSTION METHOD, AND SYNTHESIS METHOD THEREFOR
A method for preparing a transition metal electrochemical catalyst according to an embodiment of the present disclosure includes dissolving a nitrogen precursor and a transition metal precursor in a polyol-based solvent so as to prepare a solution in which transition metal ions and free anions are coordinated, and mixing same with a support so as to prepare a mixture, igniting the mixture so as to carbonize the polyol-based solvent, thereby forming transition metal nanoparticles encompassed by carbon, performing heat treatment in order to carbonize remaining organic matter contained in the mixture, and removing, through acid treatment, impurities and transition metal nanoparticles not encompassed by carbon, and then removing remaining acid through washing and additional heat treatment, thereby a nanocatalyst having a structure in which a single-atom transition metal-nitrogen bonding structure and/or transition metal nanoparticles encompassed by carbon exist is synthesized.
Process for Producing a Fischer-Tropsch Synthesis Catalyst
The present invention relates to a process for conveniently preparing a supported cobalt-containing Fischer-Tropsch synthesis catalyst having improved activity and selectivity for C.sub.5+hydrocarbons. In one aspect, the present invention provides a process for preparing a supported cobalt-containing Fischer-Tropsch synthesis catalyst, said process comprising the steps of: (a) impregnating a support material with: i) a cobalt-containing compound and ii) acetic acid, or a manganese salt of acetic acid, in a single impregnation step to form an impregnated support material; and (b) drying and calcining the impregnated support material; wherein the support material impregnated in step (a) has not previously been modified with a source of metal other than cobalt; and wherein when the cobalt-containing compound is cobalt hydroxide, a manganese salt of acetic acid is not used in step (a) of the process.
THREE-DIMENSIONAL POROUS CATALYST, CATALYST CARRIER OR ABSORBENT STRUCTURE OF STACKED STRANDS
A three-dimensional porous catalyst, catalyst carrier or absorbent structure of stacked strands of catalyst, catalyst carrier or absorbent material, composed of layers of spaced-apart parallel strands, wherein parallel strands within a layer are arranged in groups of two or more closely spaced-apart, equidistant strands separated by a small distance, wherein the groups of equidistant strands are separated from adjacent strands or adjacent groups of strands by a larger distance.
THREE-DIMENSIONAL POROUS CATALYST, CATALYST CARRIER OR ABSORBENT STRUCTURE OF STACKED STRANDS
A three-dimensional porous catalyst, catalyst carrier or absorbent structure of stacked strands of catalyst, catalyst carrier or absorbent material, composed of layers of spaced-apart parallel strands, wherein parallel strands within a layer are arranged in groups of two or more closely spaced-apart, equidistant strands separated by a small distance, wherein the groups of equidistant strands are separated from adjacent strands or adjacent groups of strands by a larger distance.
PRECIOUS METAL CATALYSTS FABRICATED USING REVERSE LOADING AND METAL SHUTTLING
A catalyst may include a base material, a precious metal, and a metal oxide. At least a portion of the precious metal may form catalytically active sites on a surface of the metal oxide. The catalytically active sites may be formed by depositing the precious metal on the base material to form a catalyst structure, performing a first calcination on the catalyst structure, depositing the metal oxide on the catalyst structure, wherein the precious metal is at least partially encapsulated by the metal oxide, performing a second calcination on the catalyst structure, and reducing the catalyst structure with a reductive material, where at least a portion of the precious metal diffuses to a surface of the metal oxide to form the catalytically active sites.
Dry reforming catalyst using metal oxide support, and method for preparing synthetic gas by using same
The present invention relates to a dry reforming catalyst in which an active material is impregnated on the surface of a metal oxide support and the active material is surrounded by a surfactant, a method of preparing the same, and a method of producing a synthetic gas using the catalyst. Since the surfactant on the surface of the active material prevents the active material from being sintered and the active material surface from being covered with carbon, the dry reforming catalyst exhibits high activity at high temperature for a long period of time without having to use a precious metal, and thus is useful for the production of a synthetic gas.
Dry reforming catalyst using metal oxide support, and method for preparing synthetic gas by using same
The present invention relates to a dry reforming catalyst in which an active material is impregnated on the surface of a metal oxide support and the active material is surrounded by a surfactant, a method of preparing the same, and a method of producing a synthetic gas using the catalyst. Since the surfactant on the surface of the active material prevents the active material from being sintered and the active material surface from being covered with carbon, the dry reforming catalyst exhibits high activity at high temperature for a long period of time without having to use a precious metal, and thus is useful for the production of a synthetic gas.