The present application discloses a molecular sieve-based catalyst modification apparatus. The apparatus comprises a feed unit 1, a modification unit 2 and a cooling unit 3 connected in sequence; the feed unit comprises a catalyst feed unit 11 and a modifier feed unit 12, a catalyst and a modifier are introduced into the modification unit 2 respectively by the catalyst feed unit and the modifier feed unit and are discharged from the modification unit after sufficient reaction in modification unit, and then enter the cooling unit 3 for cooling. The present application further discloses a use method for the molecular sieve-based catalyst modification apparatus. The use method comprises: introducing a catalyst and a modifier into the modification unit 2 respectively through the feed unit 1; wherein the catalyst is modified by the modifier in the modification unit 2, and then discharged to the cooling unit 3 to cool until the temperature is lower than 50° C., and then the cooled modified catalyst is transferred to any storage device.

The present invention provides a one-pot process of synthesis of phenyl naphthalene compounds that are employed as heat transfer agents. More particularly, the present invention provides a process of preparation of 1-phenylnaphthalene and 2-methyl-1-phenylnaphthalene using refinery spent catalyst. These molecules are known for application as synthetic heat transfer fluids that deliver outstanding performance and thermal stability at continuously high operating temperatures. The reaction is carried out in aqueous medium using a spent catalyst which is a palladium based charcoal catalyst as obtained from various refinery processes. Further, the present invention provides a heat resistant formulation using the synthesized polyhydrocarbons, wherein the formulation is optimized with a free radical scavenger.

Provided are: an exhaust gas purifying composition that contains a phosphorus-containing BEA-type zeolite and has further improved heat resistance; and a production method therefor.

The exhaust gas purifying composition contains a phosphorus-containing BEA-type zeolite, wherein the phosphorus-containing BEA-type zeolite has a pore volume ratio (V2/V1) of a micropore volume V2 having a pore diameter in a range of 2 nm or less, as measured by a SF method, to a mesopore volume V1 having a pore diameter in a range of 2 nm or more and 100 nm or less, as measured by a BJH method, of 2.0 or more.

The invention discloses a bifunctional additive for increasing low-carbon olefins and reducing slurry in cracking product, wherein the dry-basis components of said additive is as follows: 40˜55 wt % of phosphorus-containing MFI zeolite, 0˜10 wt % of large pore type Y and Beta zeolites, 3˜20 wt % of inorganic binder, 8˜22 wt % of inorganic matrix composed of alumina and amorphous silica-alumina and 15˜40 wt % of clay. The bifunctional additive is mainly used to facilitate production rate of cracked LPG and increase concentration of propylene in LPG and octane number of produced the gasoline, and at the same time reduce the yield of slurry in the cracking products. The invention also discloses its preparation method and application of said additive.

An oligomerization catalyst, oligomer products, methods for making and using same. The catalyst can include a supported nickel phosphate compound. The catalyst is stable at oligomerization temperatures of 500° C. or higher and particularly useful for making oligomer products containing C4 to C26 olefins having a boiling point in the range of 170° C. to 360° C.

The present invention provides a one-pot process of synthesis of phenyl naphthalene compounds that are employed as heat transfer agents. More particularly, the present invention provides a process of preparation of 1-phenylnaphthalene and 2-methyl-1-phenylnaphthalene using refinery spent catalyst. These molecules are known for application as synthetic heat transfer fluids that deliver outstanding performance and thermal stability at continuously high operating temperatures. The reaction is carried out in aqueous medium using a spent catalyst which is a palladium based charcoal catalyst as obtained from various refinery processes. Further, the present invention provides a heat resistant formulation using the synthesized polyhydrocarbons, wherein the formulation is optimized with a free radical scavenger.

The oxidative coupling of methane (OCM) and the oxidative dehydrogenation (ODH) of ethane and higher hydrocarbons is described using SO.sub.3 and sulfate, sulfite, bisulfite and metabifulfite salts as oxygen transfer agents in the presence of one or more elements selected from Groups 3 to 14 of the periodic table, optionally further in the presence of alkali or alkaline salts and/or sulfur-containing compounds.

The oxidative coupling of methane (OCM) and the oxidative dehydrogenation (ODH) of ethane and higher hydrocarbons is described using SO.sub.3 and sulfate, sulfite, bisulfite and metabifulfite salts as oxygen transfer agents in the presence of one or more elements selected from Groups 3 to 14 of the periodic table, optionally further in the presence of alkali or alkaline salts and/or sulfur-containing compounds.

The invention includes an additive for maximizing production of olefins. The additive comprises a ZSM-5 molecular sieve, at least one inorganic oxide, and phosphorus oxide. The ZSM-5 molecular sieve has iron in the framework, and the additive comprises at least 0.5 weight percent iron, as measured as iron oxide, in the molecular sieve framework. The additive is useful for maximizing production of olefins in a FCC process.

The present discloses an aromatization catalyst, preparation process and application thereof and a low-carbon olefin aromatization process. The aromatization catalyst comprises a microporous material, a binder and a modifier; the microporous material is a zeolite molecular sieve, the binder is alumina, the modifier is phosphorus, and the molar ratio of the aluminum element in the binder to the phosphorus element is more than or equal to 1 and less than 5; the ratio of the acidity of the strongly acidic sites to the acidity of the weakly acidic sites of the olefin aromatization catalyst is less than 1.