Patent classifications
B01J37/30
Preparation method of mesoporous Fe—Cu-SSZ-13 molecular sieve
A method of preparing a mesoporous Fe—Cu—SSZ-13 molecular sieve includes activating an aluminum source, a silicon source, an iron source and a copper source respectively; mixing the activated minerals with sodium hydroxide, water and a seed crystal at 25-90° C., while controlling feeding amounts of respective raw materials so that molar ratios of respective materials in a synthesis system are as follows: SiO.sub.2/Al.sub.2O.sub.3=10-100, SiO.sub.2/Fe.sub.2O.sub.3=30-3000, SiO.sub.2/CuO=1-100, Na.sub.2O/SiO.sub.2=0.1-0.5, H.sub.2O/SiO.sub.2=10-50, template/SiO.sub.2=0.01-0.5; adding an acid source to adjust pH of the system for first aging; and adding the acid source again to adjust the pH of the system for second aging to obtain aged gel; pouring an aged mixture into a kettle; cooling a crystallized product and filtering to remove a liquor; washing a filter cake; drying to obtain a solid; performing ion exchange; and filtering, washing and drying the solid to obtain powder; and placing the powder in a muffle furnace.
Preparation method of mesoporous Fe—Cu-SSZ-13 molecular sieve
A method of preparing a mesoporous Fe—Cu—SSZ-13 molecular sieve includes activating an aluminum source, a silicon source, an iron source and a copper source respectively; mixing the activated minerals with sodium hydroxide, water and a seed crystal at 25-90° C., while controlling feeding amounts of respective raw materials so that molar ratios of respective materials in a synthesis system are as follows: SiO.sub.2/Al.sub.2O.sub.3=10-100, SiO.sub.2/Fe.sub.2O.sub.3=30-3000, SiO.sub.2/CuO=1-100, Na.sub.2O/SiO.sub.2=0.1-0.5, H.sub.2O/SiO.sub.2=10-50, template/SiO.sub.2=0.01-0.5; adding an acid source to adjust pH of the system for first aging; and adding the acid source again to adjust the pH of the system for second aging to obtain aged gel; pouring an aged mixture into a kettle; cooling a crystallized product and filtering to remove a liquor; washing a filter cake; drying to obtain a solid; performing ion exchange; and filtering, washing and drying the solid to obtain powder; and placing the powder in a muffle furnace.
BOTTOMS UPGRADING AND LOW COKE FLUID CATALYTIC CRACKING CATALYST
A microspherical fluid catalytic cracking (FCC) catalyst includes Y zeolite and a gamma-alumina.
BOTTOMS UPGRADING AND LOW COKE FLUID CATALYTIC CRACKING CATALYST
A microspherical fluid catalytic cracking (FCC) catalyst includes Y zeolite and a gamma-alumina.
CATALYST FOR ALKYLENE OXIDE ADDITION REACTION AND APPLICATION THEREOF
The present invention provides a catalyst for an addition reaction of alkylene oxide, the catalyst comprises a nanocomposite ion-exchange resin having a structural formula of P-Im.sup.+-M.sup.−, wherein P is a nanocomposite resin matrix, Im.sup.+ is a cation derived from 5-6 membered heterocycle containing at least one nitrogen atom such as imidazolium cation, pyrazolium cation, pyrrolidinium cation, piperidinium cation, piperazinium cation, pyrimidinium cation, pyrazinium cation, pyridazinium cation, triazinium cation, and M.sup.− is an anion. The catalyst of the present invention can be used in the addition reaction of alkylene oxide and carbon dioxide. The catalyst has high wear resistance, high swelling resistance, and high activity. The products after the reaction are easy to separate, and the catalyst can be used continuously many times.
CATALYST FOR ALKYLENE OXIDE ADDITION REACTION AND APPLICATION THEREOF
The present invention provides a catalyst for an addition reaction of alkylene oxide, the catalyst comprises a nanocomposite ion-exchange resin having a structural formula of P-Im.sup.+-M.sup.−, wherein P is a nanocomposite resin matrix, Im.sup.+ is a cation derived from 5-6 membered heterocycle containing at least one nitrogen atom such as imidazolium cation, pyrazolium cation, pyrrolidinium cation, piperidinium cation, piperazinium cation, pyrimidinium cation, pyrazinium cation, pyridazinium cation, triazinium cation, and M.sup.− is an anion. The catalyst of the present invention can be used in the addition reaction of alkylene oxide and carbon dioxide. The catalyst has high wear resistance, high swelling resistance, and high activity. The products after the reaction are easy to separate, and the catalyst can be used continuously many times.
CATALYST FOR SYNTHESIZING DIMETHYLETHER OR METHYLACETATE FROM SYNTHETIC GAS, METHOD FOR PREPARING THE SAME, AND METHOD FOR PREPARING DIMETHYLETHER OR METHYLACETATE USING THE SAME
The present disclosure provides a method of preparing a catalyst for synthesizing dimethyl ether or methylacetate from synthetic gas that includes preparing a nanosheet ferrierite zeolite (FER), and co-precipitating the nanosheet ferrierite zeolite and a precursor of a Cu—Zn—Al-based oxide (CZA) to obtain a hybrid CZA/FER catalyst.
CATALYST FOR SYNTHESIZING DIMETHYLETHER OR METHYLACETATE FROM SYNTHETIC GAS, METHOD FOR PREPARING THE SAME, AND METHOD FOR PREPARING DIMETHYLETHER OR METHYLACETATE USING THE SAME
The present disclosure provides a method of preparing a catalyst for synthesizing dimethyl ether or methylacetate from synthetic gas that includes preparing a nanosheet ferrierite zeolite (FER), and co-precipitating the nanosheet ferrierite zeolite and a precursor of a Cu—Zn—Al-based oxide (CZA) to obtain a hybrid CZA/FER catalyst.
ZEOLITE WITH CU AND PD CO-EXCHANGED IN A COMPOSITE
The present disclosure provides catalyst compositions and catalytic articles capable of storing and/or reducing nitrogen oxide (NO.sub.x) emissions in engine exhaust, catalyst articles coated with such compositions, and processes for preparing such catalyst compositions and articles. The catalyst compositions include copper and palladium co-exchanged zeolites. Further provided is a process for preparing such co-exchanged zeolites, an exhaust gas treatment system including the catalytic articles disclosed herein, and methods for reducing NO in an exhaust gas stream using such catalytic articles and systems.
ZEOLITE WITH CU AND PD CO-EXCHANGED IN A COMPOSITE
The present disclosure provides catalyst compositions and catalytic articles capable of storing and/or reducing nitrogen oxide (NO.sub.x) emissions in engine exhaust, catalyst articles coated with such compositions, and processes for preparing such catalyst compositions and articles. The catalyst compositions include copper and palladium co-exchanged zeolites. Further provided is a process for preparing such co-exchanged zeolites, an exhaust gas treatment system including the catalytic articles disclosed herein, and methods for reducing NO in an exhaust gas stream using such catalytic articles and systems.