B01J37/32

METHOD OF PREPARING FeMnCeOx BIOMATERIAL AND METHOD OF TREATING ANTIBIOTIC WASTEWATER

A method of preparing a FeMnCeO.sub.x biomaterial is provided, including the following steps. A Pseudomonas sp. strain KW-2 is obtained. A culture medium with a pH of 6.5-7.8 is prepared, which includes 0.1 g/L K.sub.2HPO.sub.4, 0.2 g/L MnSO.sub.4.Math.7H.sub.2O, 0.2 g/L NaNO.sub.3, 0.1 g/L CaCl.sub.2), 0.1 g/L NH.sub.4Cl, 0.1 g/L (NH.sub.4).sub.2CO.sub.3, 35 g/L NaCl and 150 mg/L ferric ammonium citrate. The culture medium is autoclaved, inoculated with the KW-2 strain, cultured for 1-3 days, added with a cerium nitrate solution, cultured for 3-7 days and centrifuged at 4,000-8,000 rpm for 10-20 min to collect a precipitate. The precipitate is rinsed 5-8 times with deionized water and 0.01 mol/L phosphate buffered saline (PBS) and freeze-dried at ?60? C. to obtain the FeMnCeO.sub.x biomaterial. A method for treating antibiotic wastewater using the FeMnCeO.sub.x biomaterial is also provided.

Catalytic extruded, solid honeycomb body

An extruded, solid honeycomb body comprises a copper-promoted, small pore, crystalline molecular sieve catalyst for converting oxides of nitrogen in the presence of a reducing agent, wherein the crystalline molecular sieve contains a maximum ring size of eight tetrahedral atoms, which extruded, solid honeycomb body comprising: 20-50% by weight matrix component comprising diatomaceous earth, wherein 2-20 weight % of the extruded, solid honeycomb body is diatomaceous earth; 80-50% by weight of the small pore, crystalline molecular sieve ion-exchanged with copper; and 0-10% by weight of inorganic fibres.

Catalytic effects of oxygen carrier based chemical-looping reforming of CH4 with CO2
10478807 · 2019-11-19 ·

The invention relates to CeO.sub.2 and La.sub.2O.sub.3 for catalyzing Fe.sub.2O.sub.3Al.sub.2O.sub.3 based chemical-looping reforming of CH.sub.4 with CO.sub.2 (CL-DRM). The reaction performance of all the composite oxygen carriers was evaluated in a fixed-bed reactor at atmospheric pressure condition. The influencing factors, including temperature and time-on-stream (TOS) were investigated. The characteristics of the oxygen carriers were checked with Brunauer-Emmett-Teller (BET) analysis and X-ray diffraction (XRD). The reducibility of the composite materials was elucidated with temperature-programmed reduction by CH.sub.4 (CH.sub.4-TPR). Preliminary experimental observations suggest that the simultaneous presence of CeO.sub.2 and La.sub.2O.sub.3 can not only enhance the reactivity of Fe.sub.2O.sub.3Al.sub.2O.sub.3 toward CH.sub.4 oxidation and its oxygen releasing rate for fast reaction kinetics, but also improve the reactivity of its reduced form toward CO.sub.2 splitting.

Catalytic effects of oxygen carrier based chemical-looping reforming of CH4 with CO2
10478807 · 2019-11-19 ·

The invention relates to CeO.sub.2 and La.sub.2O.sub.3 for catalyzing Fe.sub.2O.sub.3Al.sub.2O.sub.3 based chemical-looping reforming of CH.sub.4 with CO.sub.2 (CL-DRM). The reaction performance of all the composite oxygen carriers was evaluated in a fixed-bed reactor at atmospheric pressure condition. The influencing factors, including temperature and time-on-stream (TOS) were investigated. The characteristics of the oxygen carriers were checked with Brunauer-Emmett-Teller (BET) analysis and X-ray diffraction (XRD). The reducibility of the composite materials was elucidated with temperature-programmed reduction by CH.sub.4 (CH.sub.4-TPR). Preliminary experimental observations suggest that the simultaneous presence of CeO.sub.2 and La.sub.2O.sub.3 can not only enhance the reactivity of Fe.sub.2O.sub.3Al.sub.2O.sub.3 toward CH.sub.4 oxidation and its oxygen releasing rate for fast reaction kinetics, but also improve the reactivity of its reduced form toward CO.sub.2 splitting.

Honeycomb structure and production method for said honeycomb structure

The present invention relates to a honeycomb structured body including a honeycomb fired body in which multiple through-holes are arranged longitudinally in parallel with one another with a partition wall therebetween, wherein the honeycomb fired body is an extrudate containing ceria-zirconia composite oxide particles and alumina particles, and when the pore size of the partition wall of the honeycomb fired body is measured by mercury porosimetry, and the measurement results are shown as a pore size distribution curve with pore size (m) on the horizontal axis and log differential pore volume (ml) on the vertical axis, at least one peak is present in each of the pore size ranges of 0.01 to 0.1 m and 0.1 to 5 m.

Honeycomb structure and production method for said honeycomb structure

The present invention relates to a honeycomb structured body including a honeycomb fired body in which multiple through-holes are arranged longitudinally in parallel with one another with a partition wall therebetween, wherein the honeycomb fired body is an extrudate containing ceria-zirconia composite oxide particles and alumina particles, and when the pore size of the partition wall of the honeycomb fired body is measured by mercury porosimetry, and the measurement results are shown as a pore size distribution curve with pore size (m) on the horizontal axis and log differential pore volume (ml) on the vertical axis, at least one peak is present in each of the pore size ranges of 0.01 to 0.1 m and 0.1 to 5 m.

THREE-DIMENSIONAL COMPOSITE MATERIAL, PREPARATION METHOD THEREOF AND APPLICATION THEREOF IN REMOVAL OF WATER POLLUTANTS BY VISIBLE LIGHT CATALYTIC DEGRADING
20190329233 · 2019-10-31 ·

A method of preparing a three-dimensional composite material includes the following steps: preparing polystyrene by soap-free emulsion polymerizing, obtaining polystyrene opal by a vertical deposition method, synthesizing MoP IO (molybdenum phosphide inverse opal), and compounding with quantum points CdS, so as to obtain a novel inorganic composite material, namely cadmium sulfide quantum dot-compounded MoP IO. The preparation method has the advantages that the MoP IO is prepared first, and the MoP IO is of a three-dimensional cyclic pore structure and has the photonic band gap feature, so that the MoP IO has better catalysis effect in light catalysis in comparison with that of common porous material; the MoP IO is compounded with the cadmium sulfide quantum dots, so that the light absorbing ability is enhanced, and the composite material capable of absorbing the visible light is obtained.

THREE-DIMENSIONAL COMPOSITE MATERIAL, PREPARATION METHOD THEREOF AND APPLICATION THEREOF IN REMOVAL OF WATER POLLUTANTS BY VISIBLE LIGHT CATALYTIC DEGRADING
20190329233 · 2019-10-31 ·

A method of preparing a three-dimensional composite material includes the following steps: preparing polystyrene by soap-free emulsion polymerizing, obtaining polystyrene opal by a vertical deposition method, synthesizing MoP IO (molybdenum phosphide inverse opal), and compounding with quantum points CdS, so as to obtain a novel inorganic composite material, namely cadmium sulfide quantum dot-compounded MoP IO. The preparation method has the advantages that the MoP IO is prepared first, and the MoP IO is of a three-dimensional cyclic pore structure and has the photonic band gap feature, so that the MoP IO has better catalysis effect in light catalysis in comparison with that of common porous material; the MoP IO is compounded with the cadmium sulfide quantum dots, so that the light absorbing ability is enhanced, and the composite material capable of absorbing the visible light is obtained.

Use of Surfactants to Extract a Platinum Group Metal or Gold from Organic Compositions

The present invention is in the field of surfactants to extract a platinum group metal or gold, in particular palladium, from organic compositions. In particular, the invention concerns the use of surfactants to back-extract a platinum group metal or gold, in particular palladium, from organic compositions further comprising an extractant of said platinum group metal or gold, in particular palladium from an aqueous solution.

Process for producing a catalyst and catalyst article

A process for producing a ceramic catalyst involves the steps of: a) providing functional particles having a catalytically inactive pore former as a support surrounded by a layer of a catalytically active material, b) processing the functional particles with inorganic particles to form a catalytic composition, c) treating the catalytic composition thermally to form a ceramic catalyst, wherein the ceramic catalyst comprises at least porous catalytically inactive cells which are formed by the pore formers in the functional particles, which are embedded in a matrix comprising the inorganic particles, which form a porous structure and which are at least partly surrounded by an active interface layer comprising the catalytically active material of the layer of the functional particles. An SCR catalyst produced in by this method has an improved NO.sub.x conversion rate compared to a conventionally produced SCR catalyst.