Patent classifications
B01J38/48
Process for Oligomerization with Stage-customized Exchange of the Oligomerization Catalyst
A method includes at least two-stage process for the oligomerization of short-chain olefins in the presence of a catalyst, wherein the regeneration of the catalyst is stage-customized.
Aromatization processes using both fresh and regenerated catalysts, and related multi-reactor systems
Multi-reactor systems with aromatization reactor vessels containing a catalyst with low surface area and pore volume, followed in series by aromatization reactor vessels containing a catalyst with high surface area and pore volume, are disclosed. Related reforming methods using the different aromatization catalysts also are described.
Aromatization processes using both fresh and regenerated catalysts, and related multi-reactor systems
Multi-reactor systems with aromatization reactor vessels containing a catalyst with low surface area and pore volume, followed in series by aromatization reactor vessels containing a catalyst with high surface area and pore volume, are disclosed. Related reforming methods using the different aromatization catalysts also are described.
Coated articles having high kNOx/kSOx ratios for selective catalytic reduction
Articles comprising a catalyst film comprising VOx, MoO.sub.3 or WO.sub.3, and TiO.sub.2 deposited on a substrate are disclosed. The articles are useful for selective catalytic reduction (SCR) of NOx in exhaust gases. Methods for producing such articles deposit a catalyst film on the substrate to form a coated substrate, which is then calcined. When used in an SCR process, the coated articles have enhanced activity for NOx conversion, reduced activity for SOx conversion, or both. Light-weight, coated articles having high catalyst loads can be fabricated at the same or reduced dimensions when compared with laminated articles, and increased kNOx/kSOx ratios are available even from coated articles having relatively thin catalyst films. The articles should have particular value for power plant operations, where coal and high-sulfur fuels are commonly used and controlling sulfur trioxide generation is critical.
Method for storage and release of hydrogen
The invention provides a process for the production of hydrogen, comprising catalytically decomposing a concentrated aqueous solution of potassium formate in a reaction vessel to form bicarbonate slurry and hydrogen, discharging the hydrogen from said reaction vessel, and treating a mixture comprising the bicarbonate slurry and the catalyst with an oxidizer, thereby regenerating the catalyst. Pd/C catalysts useful in the process are also described.
Method for storage and release of hydrogen
The invention provides a process for the production of hydrogen, comprising catalytically decomposing a concentrated aqueous solution of potassium formate in a reaction vessel to form bicarbonate slurry and hydrogen, discharging the hydrogen from said reaction vessel, and treating a mixture comprising the bicarbonate slurry and the catalyst with an oxidizer, thereby regenerating the catalyst. Pd/C catalysts useful in the process are also described.
Method for recovering catalyst
A method for recovering a catalyst, wherein a solution containing a reaction mixture obtained by performing a hydrogenation reaction in a presence of a catalyst containing a platinum group metal is brought into contact with a fiber membrane having a group containing an amino group or a thiol group on a surface, thereby recovering the platinum group metal included in the solution is provided.
Method for recovering catalyst
A method for recovering a catalyst, wherein a solution containing a reaction mixture obtained by performing a hydrogenation reaction in a presence of a catalyst containing a platinum group metal is brought into contact with a fiber membrane having a group containing an amino group or a thiol group on a surface, thereby recovering the platinum group metal included in the solution is provided.
Methods of regenerating aromatization catalysts with a decoking step between chlorine and fluorine addition
Methods for regenerating a spent catalyst are disclosed. Such methods may employ a step of chlorinating the spent catalyst in the gas phase, followed by decoking the chlorinated spent catalyst, and then fluorinating the de-coked catalyst in a fluorine-containing solution of a fluorine-containing compound.
Methods of regenerating aromatization catalysts with a decoking step between chlorine and fluorine addition
Methods for regenerating a spent catalyst are disclosed. Such methods may employ a step of chlorinating the spent catalyst in the gas phase, followed by decoking the chlorinated spent catalyst, and then fluorinating the de-coked catalyst in a fluorine-containing solution of a fluorine-containing compound.