B01J2208/02

Fuel reforming system
09835117 · 2017-12-05 · ·

Provided is a fuel reforming system that can convert gasoline into alcohol in a vehicle. Provided is a fuel reforming system (1) equipped with a reformer (15) having a reforming catalyst (152) that uses air to reform gasoline to produce alcohol, a mixer (14) which mixes gasoline and air and supplies the mixture to the reformer (15), and a condenser (16) which separates the gas produced in the reformer (15) into a gas phase and a condensed phase of which reformed fuel is the primary constituent; wherein the fuel reforming system (1) is characterized in that the reforming catalyst (152) is configured including a main catalyst for extracting hydrogen atoms from the hydrocarbons in the gasoline to produce alkyl radicals, and a catalytic promoter for reducing alkyl hydroperoxides produced from the alkyl radicals to produce alcohol.

System and method for on stream catalyst replacement

A system of reforming reactors comprises a plurality of reactors coupled by flow lines, a feed header coupled to the plurality of reactors by a plurality of feed lines, an effluent header coupled to the plurality of reactors by a plurality of effluent lines, and a plurality of valves disposed in the flow lines, the feed lines, and the effluent lines. Each reactor comprises a reforming catalyst, and the plurality of valves is configured to dynamically connect the plurality of reactors to create a first serial flow path and reconnect the plurality of reactors to create a second serial flow path through the plurality of reactors. A first reactor of the plurality of reactors is adjacent to a second reactor of the plurality of reactors in the first serial flow path, and the first reactor is not adjacent to the second reactor in the second serial flow path.

Process and device for reducing environmental contaminates in heavy marine fuel oil

A process and device for reducing the environmental contaminants in a ISO 8217 compliant Feedstock Heavy Marine Fuel Oil, the process involving: mixing a quantity of the Feedstock Heavy Marine Fuel Oil with a quantity of Activating Gas mixture to give a feedstock mixture; contacting the feedstock mixture with one or more catalysts to form a Process Mixture from the feedstock mixture; separating the Product Heavy Marine Fuel Oil liquid components of the Process Mixture from the gaseous components and by-product hydrocarbon components of the Process Mixture and, discharging the Product Heavy Marine Fuel Oil. The Product Heavy Marine Fuel Oil is compliant with ISO 821 7 for residual marine fuel oils and has a sulfur level has a maximum sulfur content (ISO 14596 or ISO 8754) between the range of 0.05% wt. to 0.5% wt. The Product Heavy Marine Fuel Oil can be used as or as a blending stock for an ISO 8217 compliant, IMO MARPOL Annex VI (revised) compliant low sulfur or ultralow sulfur heavy marine fuel oil.

Catalytically heated fuel processor with replaceable structured supports bearing catalyst for fuel cell

A highly compact heat integrated fuel processor, which can be used for the production of hydrogen from a fuel source, suitable to feed a fuel cell, is described. The fuel processor assembly comprises a catalytic reforming zone (29) and a catalytic combustion zone (28), separated by a wall (27). Catalyst able to induce the reforming reactions is placed in the reforming zone and catalyst able to induce the combustion reaction is placed in the combustion zone, both in the form of coating on a suitable structured substrate, in the form of a metal monolith. Fe—Cr—Al—Y steel foils, in corrugated form so as to enhance the available area for reaction, can be used as suitable substrates. The reforming and the combustion zones can be either in rectangular shape, forming a stack with alternating combustion/reforming zones or in cylindrical shape forming annular sections with alternating combustion/reforming zones, in close contact to each other. The close placement of the combustion and reforming catalyst facilitate efficient heat transfer through the wall which separates the reforming and combustion chambers.

FUEL CELL SYSTEM WITH COMBINED PASSIVE AND ACTIVE SORBENT BEDS

A fuel cell system including a hydrocarbon fuel stream including a sulfur compound; a passive sorbent bed including a selective sulfur sorbent configured to remove the sulfur compound from the hydrocarbon fuel stream; a SCSO reactor, and an active sorbent bed comprising a sulfur oxide sorbent, wherein the active sorbet bed is configured to receive an effluent stream from the SCSO reactor and remove at least a portion of the sulfur oxides via the sulfur oxide sorbent. During start-up of the fuel cell system, the hydrocarbon fuel stream may be directed along a first flow pathway through the passive sorbent bed to remove the sulfur compound from the fuel stream during a first time period and then directed along a second flow pathway during a second time period that does not pass through the passive sorbent bed, e.g., once the SCSO reactor/active sorbent bed have reached operating temperature.

Flex-Fuel Hydrogen Reformer for IC Engines and Gas Turbines
20170292446 · 2017-10-12 ·

An on-board Flex-Fuel H.sub.2 reforming apparatus provides devices and the methods of operating these devices to produce H.sub.2 and CO from hydrocarbons and bio-fuels. One or more parallel autothermal reformers are used to convert the fuels into H.sub.2 over the Pt group metal catalysts without external heat and power. The produced reformate is then cooled and the dry gas is compressed and stored in vessels at a pressure between 1 to 100 atmospheres. For this system, the pressure of the storage vessels and the flow control curves are used directly to control the amount of the reformers' reformate output.

To improve thermal efficiency of a mobile vehicle or a distributed power generator, portion of the reformate from the storage vessels is used to mix with the primary fuels and air as part of a lean burn fuel mixture for the engine/gas turbine. Also, this on-board Flex-Fuel H.sub.2 reforming apparatus can provide H.sub.2 to regenerate the NO.sub.x and diesel particulate traps for diesel engines, and/or it can provide H.sub.2 for a mobile or a portable fuel cell power generator.

Fuel reformer and fuel cell

A fuel reformer 20 producing a reformed gas by catalysis by using a fuel gas includes a combustion chamber 24, a combustion nozzle 30, an exhausting pipe 15, a gas distribution gap 25, an outer reforming portion 43, a fuel gas introduction pipe 10, and a reformed gas outlet pipe 11. The combustion nozzle 30 is located in the combustion chamber 24. A columnar protruding portion 40 is provided in the combustion chamber 24.

Reactor and reaction method

A method of forming a hydrocarbon product, the method comprising a first step of enriching a carrier liquid with carbon monoxide and hydrogen and a subsequent step of bringing the enriched carrier liquid into contact with a catalyst in a first reaction zone of a reactor, wherein the catalyst catalyzes reaction of the carbon monoxide and hydrogen to form the hydrocarbon product.

Multi-stage process and device for treatment heavy marine fuel oil and resultant composition including ultrasound promoted desulfurization

A multi-stage process for reducing the environmental contaminants in an ISO8217 compliant Feedstock Heavy Marine Fuel Oil involving a core desulfurizing process and a ultrasound treatment process as either a pre-treating step or post-treating step to the core process. The Product Heavy Marine Fuel Oil complies with ISO 8217 for residual marine fuel oils and has a sulfur level has a maximum sulfur content (ISO 14596 or ISO 8754) between the range of 0.05 mass % to 1.0 mass. A process plant for conducting the process is also disclosed.

Heavy marine fuel oil composition

A process for reducing the environmental contaminants in a ISO 8217 compliant Feedstock Heavy Marine Fuel Oil (Feedstock), the process involving: mixing a quantity of the Feedstock with a quantity of Activating Gas mixture to give a feedstock mixture; contacting the feedstock mixture with one or more catalysts to form a Process Mixture from the feedstock mixture; separating the Product Heavy Marine Fuel Oil liquid (Product) components of the Process Mixture from the gaseous components and by-product hydrocarbons of the Process Mixture and, discharging the Product. The Product is compliant with ISO standards for residual marine fuel oils and has a maximum sulfur content between the range of 0.05% wt. to 0.50% wt. The Product can be used as or as a blending stock for compliant, low sulfur or ultralow sulfur heavy marine fuel oil. A device for conducting the process is also disclosed.