Hydrocracking catalysts and hydrocracking processes for the selective production of lube base stocks are disclosed. The hydrocracking catalyst contains a low acidity, highly dealuminated USY zeolite having a zeolite acid site density of from 1 to 100 micromole/g, a catalyst support, and one or more metals. The hydrocracking catalysts can maximize lube base stock yield while providing for effective impurity removal and VI enhancement at lower hydrocracking conversions.

The present disclosure features a method of making an engine aftertreatment catalyst, where the engine aftertreatment catalyst includes a metal oxide, a metal zeolite, and/or vanadium oxide when the metal oxide is different from vanadium oxide, each of which can be independently surface-modified with a surface modifier. The method includes providing a solution including an organic solvent and an organometallic compound; mixing the solution with a metal oxide, a metal zeolite, and/or a vanadium oxide to provide a mixture; drying the mixture; and calcining the mixture to provide a surface-modified metal oxide catalyst, a surface-modified metal zeolite catalyst, and/or a surface-modified vanadium oxide catalyst. The organometallic compound can be, for example, a metal alkoxide, a metal carboxylate, a metal acetylacetonate, and/or a metal organic acid ester.

The present invention provides a modified composite molecular sieve, and a preparation method and an application of the modified composite molecular sieve. The modified composite molecular sieve comprises SiO.sub.2 and a composite molecular sieve that comprises molecular sieve MCM-22 and zeolite A selected from at least one of ZSM-22, ZSM-23 and ZSM-48, wherein, the molecular sieve MCM-22 covers around the zeolite A. The present invention further provides a catalyst and an application of the catalyst. The catalyst comprises a carrier and a noble metal loaded on the carrier, wherein, the carrier comprises a modified composite molecular sieve that is the modified composite molecular sieve provided in the present invention or the modified composite molecular sieve obtained with the method provided in the present invention. The catalyst that utilizes the composite molecular sieve as a carrier not only can decrease the solidifying point of waxy raw oil, but also can improve the yield of liquid product, is especially applicable to the isomerization dewaxing process of lube distillate, and has an advantage of remarkably improving the viscosity index of lube base oil.

The present disclosure provides a hydrocracking catalyst, a method for preparing the same and a use of the same, and a method for hydrocracking catalytic diesel oil. The catalyst comprises a support, an active metal component, and carbon, wherein, based on the total weight of the catalyst, the content of the support is 60 to 90 wt %, the content of the active metal component calculated in metal oxides is 15 to 40 wt %, and the content of carbon calculated in C element is 1 to 5 wt %; measured with an infrared acidimetric estimation method, the acid properties of the hydrocracking catalyst are: the total infrared acid amount is 0.4 to 0.8 mmol/g, wherein, the infrared acid amount of strong acid with desorption temperature greater than 350 C. is 0.08 mmol/g or lower, and the ratio of the total infrared acid amount to the infrared acid amount of strong acid with desorption temperature greater than 350 C. is 5 to 50.

An optical member related to the present application includes a metal substrate or inorganic carbon substrate having a rough surface on at least a part, and the metal substrate or inorganic carbon substrate does not melt at a growth temperature of a carbon nanostructure, an inorganic material layer containing inorganic fine particles comprised from a metal oxide and the inorganic material layer being formed on the rough surface of the metal substrate or the inorganic carbon substrate; a catalyst metal fine particle layer supported on the inorganic material layer; and a carbon nanostructure formed on the catalyst metal fine particle layer. The material of the metal substrate may be a metal selected from a group comprising of Ti, Zr, Hf, V, Nb, Ta, Cr, Mo, W, Pd, Pt, Cu, Au and Ag or an alloy of these as a main component, an isotropic graphite or glassy carbon.

Provided are a titanium dioxide-coated upconverting nanoparticle (UCNP) and a photocatalyst complex containing a gold nanorod (GNR) combined with the titanium dioxide-coated UCNP.

An exhaust gas purifying catalyst has enhanced NOx purification performance in a lean atmosphere, and a production method for producing an exhaust gas purifying catalyst includes sputtering a target material containing Ta and Rh to form composite fine metal particles respectively containing Ta and Rh.

The present invention provides a photocatalyst coated body which can realize a sufficient photocatalytic activity and adhesiveness with a substrate, without significantly impairing an appearance of a substrate, especially an exterior building material. The photocatalyst coated body has a structure including a substrate, an intermediate layer formed on the substrate, and a photocatalyst layer formed on the intermediate layer. The intermediate layer includes inorganic oxide particles having an average particle diameter of nanosize. The photocatalyst layer includes photocatalyst particles having an average particle diameter of more than 0 m to less than 10 m and inorganic oxide particles having an average particle diameter of nanosize. A sum of a film thickness of the intermediate layer and a film thickness of the photocatalyst layer is 0.3 m or more to 1.5 m or less.

Catalysts useful for the selective hydrogenation of carbonyl groups, including for the reduction of aldehydes to alcohols, are described. The catalysts incorporate palladium and rhenium on an alumina support. Methods of making the catalysts, and methods of using the catalysts for the selective hydrogenation of furanyl 2-carbaldehydes to 2-furanmethanols, are also presented.

A TiO.sub.2-based catalyst precursor material in powder form includes TiO.sub.2 particles with the formula TiO.sub.(2-x)(OH).sub.2x (x=0-1). The particles are coated with one or more auxiliary shaping agents and after coating and drying have a specific surface area of at least 150 m.sup.2/g. The material has a content of 1) 50-99.5% by weight of the titanium-oxygen compound with the general formula TiO.sub.(2-x)(OH).sub.2x, wherein x=0 to 1, or mixtures thereof, wherein the crystalline phases of the titanium-oxygen compound are in the anatase form, and 2) 0.5-50% by weight of an auxiliary shaping agent or mixtures thereof, which evaporates, sublimates and/or decomposes upon heating to temperatures below the transformation temperature from anatase to rutile, wherein the % by weight are relative to the total weight of the dried catalyst precursor material.