The present invention relates to a continuous roll-to-roll process for improving the water tolerance of bio-based polymers, in particular cellulose nanofibrils (CNF) films. Furthermore, the invention provides a method, which combines surface modification/functionalization for improving water stability and wet strength, UV/Ozone treatment, corona treatment or plasma activation for purifying and activating the surface and thus increasing the reaction efficiency, and further hydrophobization of the surface of CNF film.

The present invention relates to a continuous roll-to-roll process for improving the water tolerance of bio-based polymers, in particular cellulose nanofibrils (CNF) films. Furthermore, the invention provides a method, which combines surface modification/functionalization for improving water stability and wet strength, UV/Ozone treatment, corona treatment or plasma activation for purifying and activating the surface and thus increasing the reaction efficiency, and further hydrophobization of the surface of CNF film.

A hardcoat film including a support and a hardcoat layer, in which the support contains a resin as a main component, a film thickness of the hardcoat layer exceeds 20 μm, the hardcoat layer contains a structure derived from a compound which has one alicyclic epoxy group and one ethylenically unsaturated double bond group and has a molecular weight equal to or less than 300, and a structure derived from a compound which has 3 or more ethylenically unsaturated double bond groups, a radical polymerization initiator and a cationic polymerization initiator.

The present invention relates to a polyimide precursor comprising a repeating unit represented by the following chemical formula (1): ##STR00001##
wherein A is a tetravalent group having at least one aliphatic six membered ring and no aromatic ring in the chemical structure, and B is a divalent group having at least one amide bond and an aromatic ring in the chemical structure; or A is an aliphatic tetravalent group and B is a divalent group having at least one chemical structure represented by the following chemical formula (2) in the chemical structure: ##STR00002##
and X.sub.1 and X.sub.2 are each independently hydrogen, a C.sub.1-6 alkyl group or a C.sub.3-9 alkylsilyl group.

The present invention relates to a polyimide precursor comprising a repeating unit represented by the following chemical formula (1): ##STR00001##
wherein A is a tetravalent group having at least one aliphatic six membered ring and no aromatic ring in the chemical structure, and B is a divalent group having at least one amide bond and an aromatic ring in the chemical structure; or A is an aliphatic tetravalent group and B is a divalent group having at least one chemical structure represented by the following chemical formula (2) in the chemical structure: ##STR00002##
and X.sub.1 and X.sub.2 are each independently hydrogen, a C.sub.1-6 alkyl group or a C.sub.3-9 alkylsilyl group.

Disclosed herein are molecularly coated surfaces, methods of coating surfaces, and methods of using coatings on surfaces. In some embodiments, the coated surfaces are useful in applications to avoid blemishes on gemstones, confer antimicrobial activity on a surface, confer a therapeutic property to a surface, detect an analyte, change the color of a surface, and or to change the physical and/or chemical properties of a surface.

A method for creating a dielectric thin-film coating for devices having a fusible element is disclosed. The method comprises mixing insoluble and soluble polymers in solid form and exposing the mixture to heat to create a melt mixture. The melt mixture is then dissolved in a solvent to create a slurry which can then be deposited on the device as a thin-film coating to create an interior insulation layer or an external surface.

The hydrophobic and corrosion resistive film of cross-linked poly(hexafluoroisopropyl methacrylate) was prepared by photopolymerization. The starting materials were a monomer of 1,1,1,3,3,3-hexafluoroisopropyl methacrylate, a photoinitiator of hydroxycyclohexyl phenyl ketone, and a cross-linker of poly(ethyleneglycol diacrylate). Photopolymerization was used to start polymerization and to cure the polymer film on an aluminum surface. Drop-casting was used to deposit the fluoropolymer onto an aluminum substrate (AA 3003). The fluoropolymer film has high corrosion protection when measured by potentiodynamic polarization and open circuit potential techniques in an aqueous solution of 3.5% NaCl. Fourier-transform infrared spectroscopy was used to monitor the polymerization process. The dynamic contact angle technique was used to measure the hydrophobicity for the fluorinated polymer coating. Thermal stability of the fluorinated polymer was measured using thermogravimetric analysis. Treatment with strong acid followed by contact angle measurements before and after the treatment confirmed the chemical resistance for the coated aluminum.

The present disclosure relates to a method for coating a coiled sucker rod, the method comprising: (a) transferring the coiled sucker rod from a first reel to a thermal spray metal gun system with a conveyance system; and (b) applying a thermal spray metal coating on the coiled sucker rod with a thermal spray metal gun system to form a thermal spray metal coated coiled sucker rod.

Methods of curtain coating substrates are disclosed. In some embodiments, the methods include applying two or more liquid layers simultaneously to a substrate, wherein the multiple layers include a bottom liquid layer comprising a shear thinning liquid, and another liquid layer comprising a viscoelastic liquid. In some embodiments, the disclosed methods include formulating a bottom layer liquid comprising a shear thinning liquid, formulating another layer liquid comprising a viscoelastic liquid, pumping the bottom layer liquid and the other layer liquid through coating dies simultaneously and onto a moving substrate such that the bottom layer liquid impinges on the substrate thereby forming a bottom layer, and the other layer liquid forms another liquid layer above the bottom liquid layer. The inclusion of a bottom liquid layer comprising a shear thinning liquid and other layer comprising a viscoelastic liquid provides for enlargement of the curtain coating window.