There is provided a technique of forming an insulating film containing silicon oxide. A coating solution containing polysilazane is applied onto a wafer W, the solvent of the coating solution is volatilized, and the coating film is irradiated with ultraviolet rays in nitrogen atmosphere before performing a curing process. Dangling bonds are generated in silicon which is a pre-hydrolyzed site in polysilazane. Therefore, the energy for hydrolysis is reduced, and unhydrolyzed sites are reduced even when the temperature of the curing process is 350° C. Since efficient dehydration condensation occurs, the crosslinking rate is improved, and a dense (good-quality) insulation film is formed. By forming a protective film on the surface of the coating film to which ultraviolet rays irradiated, the reaction of dangling bonds prior to the curing process is suppressed.

A coating method includes a first step for spraying, onto an inner area of an opening part of a cylindrical body having a bottom and arranged horizontally, a first coating material of synthetic resin containing non-volatile components while rotating the cylindrical body around a central axis thereof. After the first step, a second step is performed for spraying, onto an inner area of a barrel part of the cylindrical body, a second coating material of synthetic resin containing a lower proportion of non-volatile components than that of the first coating material while continuing to rotate the cylindrical body. After the second step is performed and before the volatile components of the second coating material vaporizes, a third step is performed in which the rotation of the cylindrical body is stopped, the cylindrical body is placed vertically, and the volatile components of the second coating material are vaporized.

A coating method includes a first step for spraying, onto an inner area of an opening part of a cylindrical body having a bottom and arranged horizontally, a first coating material of synthetic resin containing non-volatile components while rotating the cylindrical body around a central axis thereof. After the first step, a second step is performed for spraying, onto an inner area of a barrel part of the cylindrical body, a second coating material of synthetic resin containing a lower proportion of non-volatile components than that of the first coating material while continuing to rotate the cylindrical body. After the second step is performed and before the volatile components of the second coating material vaporizes, a third step is performed in which the rotation of the cylindrical body is stopped, the cylindrical body is placed vertically, and the volatile components of the second coating material are vaporized.

Described herein is an improved method for applying silane-based coatings to solid surfaces, in particular metal surfaces. Also described herein are a silane-containing composition, a solid surface, in particular a metal surface, including a silane-based coating, and a method of using the silane-based coating in the transportation industry or in electrically conductive assembling.

Glass or glass ceramic substrates are provided that have a decorative coating. Methods for coating a glass or glass ceramic substrate with a decorative coating are also provided. In the method, a first, textured layer is applied which is filled with a further layer, so that a layer material of graded composition is formed.

Glass or glass ceramic substrates are provided that have a decorative coating. Methods for coating a glass or glass ceramic substrate with a decorative coating are also provided. In the method, a first, textured layer is applied which is filled with a further layer, so that a layer material of graded composition is formed.

A method for modifying a polymeric surface is disclosed. The polymeric surface is activated utilizing atmospheric pressure plasma. An atom transfer radical polymerization initiator is then coupled to the activated surface. A monomer is then polymerized on the activated surface utilizing an activators regenerated by electron transfer (ARGET) atom transfer radical polymerization (ATRP) process. The method enables brush-modification of the polymeric surface, even if the polymeric surface is substantially chemically inert. By way of example, the method enables a chemically inert, substantially hydrophobic polymer surface to be functionalized with substantially hydrophilic polymer brushes. The methods of the present disclosure have general applicability to a myriad of implementations where tunable surface chemistry is advantageous, such as filtration membranes, marine surfaces, and medical devices seeking a biocompatible coating.

Provided is a coating material composition that enables an efficient repair operation of a coating film after coating, a (meth)acrylic copolymer that is suitable for obtaining the coating material composition, and a coated article and a method for forming a multilayer coating film using the coating material composition. The (meth)acrylic copolymer includes: a constituent unit derived from a macromonomer (a); and a constituent unit derived from a vinyl monomer (b), a hydroxyl value of the (meth)acrylic copolymer is equal to or greater than 120 mgKOH/g and equal to or less than 260 mgKOH/g, and the content of a constituent unit that has a primary hydroxyl group of the (meth)acrylic copolymer is equal to or less than 30 parts by mass with respect to 100 parts by mass of the constituent unit derived from the macromonomer (a) and the constituent unit derived from the vinyl monomer (b).

Provided is a coating material composition that enables an efficient repair operation of a coating film after coating, a (meth)acrylic copolymer that is suitable for obtaining the coating material composition, and a coated article and a method for forming a multilayer coating film using the coating material composition. The (meth)acrylic copolymer includes: a constituent unit derived from a macromonomer (a); and a constituent unit derived from a vinyl monomer (b), a hydroxyl value of the (meth)acrylic copolymer is equal to or greater than 120 mgKOH/g and equal to or less than 260 mgKOH/g, and the content of a constituent unit that has a primary hydroxyl group of the (meth)acrylic copolymer is equal to or less than 30 parts by mass with respect to 100 parts by mass of the constituent unit derived from the macromonomer (a) and the constituent unit derived from the vinyl monomer (b).

A process for coating a product by ion exchange including: a) providing a product that contains a surface segregating species (SSS) having a low surface energy component and an ionic component wherein the SSS has segregated to an outer surface of the product to form an activated surface; and b) treating the activated surface of the product with a liquid containing a surface modifying agent comprising one or more polyionic species, wherein the polyionic species is attracted to and deposits on the activated surface through a process of ion exchange.