A process for metallising a polymeric surface of an article, the process including applying to the polymeric surface a liquid carrier containing a suspension of metallic or metal-looking particles, wherein the polymeric surface and the liquid carrier are such that the wetting angle between the liquid carrier and the polymeric surface is of substantially 90 or above, and wherein the particles and the polymeric surface are such that the particles have a greater affinity to the polymeric surface than to one another or to the liquid, whereby particles suspended in the liquid migrate to the interface between the liquid and the polymeric surface to form a monolayer coating of particles on the polymeric surface.

Described herein are aqueous dispersions including multistage-prepared polymers of olefinically unsaturated compounds and to the preparation and use thereof, in particular in the field of automobile coating.

An inkjet ink for an impermeable base material includes water, a resin-coated pigment in which at least a part of the pigment is coated with a crosslinked resin, a solvent A which is an alkanediol compound having a boiling point of 180? C. to 200? C., and a solvent B which is at least one of a monoalcohol compound having a boiling point of 70? C. to 160? C. or a glycol monoether compound having a boiling point of 70? C. to 160? C. An image recording method includes applying of the inkjet ink for an impermeable base material to record an image.

A nanocomposite is provided including spherical pyrogenic silica nanoparticles dispersed in a curable resin or a curing agent. The nanocomposite contains less than 2% by weight solvent and less than 0.5% by weight dispersant based on the nanoparticle weight. A composite is also provided including from about 4 to 70 weight percent of spherical pyrogenic silica nanoparticles dispersed in a cured resin, and a filler embedded in the cured resin. Optionally, the composite further contains a curing agent. Further, a method of preparing a nanoparticle-containing curable resin system is provided including mixing from 10 to 70 weight percent of aggregated spherical pyrogenic silica nanoparticles with a curable resin to form a mixture. The mixture contains less than 2% by weight solvent and less than 0.5% by weight dispersant based on the nanoparticle weight. The method also includes milling the mixture in an immersion mill containing milling media to form a milled resin system including silica nanoparticles dispersed in the curable resin.

A method of applying a coating composition to a substrate utilizing a high transfer efficiency applicator include the steps of providing the high transfer efficiency applicator comprising an array of nozzles wherein each nozzle defines a nozzle orifice having a diameter of from 0.00002 m to 0.0004, providing the coating composition, and applying the coating composition to the substrate through the nozzle orifice without atomization such that at least 99.9% of the applied coating composition contacts the substrate to form a coating layer having a wet thickness of at least 5 microns, wherein the coating composition includes a carrier, a binder, and a radar reflective pigment or a LiDAR reflective pigment. The coating composition has an Ohnesorge number (Oh) of from about 0.01 to about 12.6, a Reynolds number (Re) of from about 0.02 to about 6,200, and a Deborah number (De) of from greater than 0 to about 1730.

A nanocomposite is provided including nonspherical silica nanoparticles dispersed in a curable resin or a curing agent, where the nanocomposite contains less than 2% by weight solvent. A composite is also provided including from about 4 to 70 weight percent of nonspherical silica nanoparticles dispersed in a cured resin, and a filler embedded in the cured resin. Further, a method of preparing a nanoparticle-containing curable resin system is provided including mixing from 10 to 70 weight percent of aggregated silica nanoparticles with a curable resin and optionally a dispersant, a catalyst, a diluent, a surface treatment agent, and/or a curing agent, to form a mixture. The mixture contains less than 2% by weight solvent. The method also includes milling the mixture in an immersion mill containing milling media to form a milled resin system including nonspherical silica nanoparticles dispersed in the curable resin.

A method of forming a layered coating film includes: coating a workpiece with an electrodeposition coating material to form an electrodeposition coating layer; applying a colored coating material including a white pigment over the electrodeposition coating layer to form two or more colored coating layers that are layered on the electrodeposition layer; and applying a clear coating material over the two or more colored coating layers. The colored coating material includes coating materials respectively applied to form a lower-side colored coating layer and an upper-side colored coating layer of the two or more colored coating layers. A concentration of the white pigment in the coating material applied to form the lower-side colored coating layer is equal to or higher than a concentration of the white pigment included in the coating material applied to form the upper-side colored coating layer.

To provide a production method for obtaining a coated article provided with a coating film having excellent weather resistance by using a powder coating material. A method for producing a coated article, which comprises applying a powder coating material comprising a fluororesin (A), a non-fluororesin (B) and a metallic pigment (C) to the surface of a substrate, and heating the substrate having the powder coating material applied, to a temperature of at least the glass transition temperature of the fluororesin (A) and the non-fluororesin (B), followed by cooling, to form a coating film on the substrate surface, and which is characterized in that the content of the metallic pigment (C) is from 0.7 to 23 mass % to the total amount of the powder coating material, the PCI value of the coating film is at least 6, and the flip-flop value is at least 1.2.

A process is described for metallising a polymeric surface of an article. The process comprises applying to the polymeric surface a liquid carrier containing a suspension of metallic or metal-looking particles. The polymeric surface and the liquid carrier are such that the wetting angle between the liquid carrier and the polymeric surface is of substantially 90 or above and the particles and the polymeric surface are such that the particles have a greater affinity to the polymeric surface than to one another or to the liquid, so that particles suspended in the liquid migrate to the interface between the liquid and the polymeric surface to form a monolayer coating of particles on the polymeric surface.

Provided are a light-blocking member, a black resin composition, and a black resin molded article having excellent durability and solvent resistance, and the like. In a light-blocking member (1) comprising a substrate (11) and a light-blocking membrane (21) provided on at least one surface of this substrate (11), the light-blocking membrane (21) containing an ultraviolet curable resin as a binder resin and containing a black pigment as a filler dispersed in this binder resin is employed. The light-blocking membrane (21) preferably further contains photo- and/or thermal polymerization initiators. In addition, the content of the filler in the light-blocking membrane (21) is preferably 10% by mass or more and 60% by mass or less in terms of solids based on all resin components contained in the light-blocking membrane (21).