Porous media containing undesired substances, e.g., perfluoroalkylated substances, are treated by mixing the porous media with a solid fuel comprising organic material. The mixture is heated to 200 C. to 400 C. to initiate smoldering combustion and an oxidizer gas is forced through the heated mixture such that the smoldering combustion is self-sustaining until the mixture reaches a PFAS destructive temperature and the perfluoroalkylated substances are thermally destroyed. A system is provided for conducting the treatment. The system includes a source of wax, wood chips, sawdust, tire scraps, waste rubber compounds, coal, granular activated carbon, solid fat, and combinations thereof as solid fuel. A mixer is provided for mixing the porous media with the solid fuel. An ignition system including static heating elements and a gas blower are provided for forcing heated oxidizer gas through the mixture such that self-sustaining smoldering combustion of the mixture is initiated and sustained.

An in-situ thermal desorption system, an in-situ thermal desorption-oxidation remediation system and a remediation method are provided, wherein the in-situ thermal desorption system comprises a heating device and an extraction device, wherein the heating device is used for transporting heated air to the contaminated soil to desorb the organic pollutants, and wherein the extraction device is used for sucking the desorbed organic pollutants. The in-situ thermal desorption-oxidation remediation system adds a thermal catalytic oxidation device based on the in-situ thermal desorption system, wherein the organic pollutants extracted by the extraction device are catalytically degraded in the thermal catalytic oxidation device, and a device for recycling and reprocessing an exhaust gas is further added. The present disclosure also provides an in-situ thermal desorption-oxidation remediation method. The heating method of the present disclosure is novel, which reduces the cost of thermal desorption, strengthens the heating area, improves the heating efficiency, further enhances the thermal catalytic oxidation efficiency, and achieves the reuse and recycle of the exhaust gas. Thus, no secondary exhaust gas is produced.

An in-situ thermal desorption system, an in-situ thermal desorption-oxidation remediation system and a remediation method are provided, wherein the in-situ thermal desorption system comprises a heating device and an extraction device, wherein the heating device is used for transporting heated air to the contaminated soil to desorb the organic pollutants, and wherein the extraction device is used for sucking the desorbed organic pollutants. The in-situ thermal desorption-oxidation remediation system adds a thermal catalytic oxidation device based on the in-situ thermal desorption system, wherein the organic pollutants extracted by the extraction device are catalytically degraded in the thermal catalytic oxidation device, and a device for recycling and reprocessing an exhaust gas is further added. The present disclosure also provides an in-situ thermal desorption-oxidation remediation method. The heating method of the present disclosure is novel, which reduces the cost of thermal desorption, strengthens the heating area, improves the heating efficiency, further enhances the thermal catalytic oxidation efficiency, and achieves the reuse and recycle of the exhaust gas. Thus, no secondary exhaust gas is produced.

A method for remediating contaminated soil and groundwater includes selecting a treatment material and creating a smolderable mixture of a contaminant, the treatment material, and soil.

A rock sample includes multiple rock samples that are each obtained from the borehole. The rock samples have been exposed to contamination during a drilling operation to drill the borehole. The rock sample is split into a first sample portion and a second sample portion. The first sample portion is decontaminated with a solvent. The second sample portion is decontaminated by thermovaporization for an initial duration of time at an initial thermovaporization temperature below that of a cracking temperature of an organic matter carried within the rock sample. A difference between a first pyrolysis Tmax value of the first sample portion decontaminated by the solvent and a second pyrolysis Tmax value of the second sample portion decontaminated by the thermovaporization is determined to satisfy a decontamination level threshold. The remainder of rock samples are decontaminated by the thermovaporization in response to determining that the difference satisfies the decontamination level threshold.

A rock sample includes multiple rock samples that are each obtained from the borehole. The rock samples have been exposed to contamination during a drilling operation to drill the borehole. The rock sample is split into a first sample portion and a second sample portion. The first sample portion is decontaminated with a solvent. The second sample portion is decontaminated by thermovaporization for an initial duration of time at an initial thermovaporization temperature below that of a cracking temperature of an organic matter carried within the rock sample. A difference between a first pyrolysis Tmax value of the first sample portion decontaminated by the solvent and a second pyrolysis Tmax value of the second sample portion decontaminated by the thermovaporization is determined to satisfy a decontamination level threshold. The remainder of rock samples are decontaminated by the thermovaporization in response to determining that the difference satisfies the decontamination level threshold.

A method for repairing an organic polluted site includes the following steps: step 1, build a sunlight greenhouse; step 2, carry out pretreatment to the soil of the organic polluted site; step 3, perform a biological heap treatment on the pretreated soil; step 4, implement quality control on the biological heap for soil remediation. By constructing a sunlight greenhouse within the original site of organic pollution sites, placing a biological heap in the sunlight greenhouse for a biological heap treatment, using the heat accumulated in the sunlight greenhouse to promote the volatilization of volatile organic matters in the soil without causing secondary pollution, and meanwhile adding a microbial agent and a nutritional agent to the polluted soil to promote the degradation and conversion of adsorbed organic matters.

A method for repairing an organic polluted site includes the following steps: step 1, build a sunlight greenhouse; step 2, carry out pretreatment to the soil of the organic polluted site; step 3, perform a biological heap treatment on the pretreated soil; step 4, implement quality control on the biological heap for soil remediation. By constructing a sunlight greenhouse within the original site of organic pollution sites, placing a biological heap in the sunlight greenhouse for a biological heap treatment, using the heat accumulated in the sunlight greenhouse to promote the volatilization of volatile organic matters in the soil without causing secondary pollution, and meanwhile adding a microbial agent and a nutritional agent to the polluted soil to promote the degradation and conversion of adsorbed organic matters.

Implementations of a non-polluting biomass processor, and manufactured processor components are disclosed which at least partly address the local technical problems of a municipality, business, and/or organization, to generate non-polluting emissions, while generating at least one, often two or more, product outputs from biomass feedstocks input into the biomass processor. Examples of the operations of the biomass processor and various combinations of its manufactured processor components are disclosed. The product outputs may include carbon char and/or activated carbon, both of which may be used to increase water retention in climates with hot, dry summers and/or used to remediate water pollution in water reservoirs.

A method for remediating a contaminated porous matrix including selecting the type and quantity of organic fuel to create a smolderable mixture of the organic fuel and contaminated porous matrix, and controlling the rate of oxidant addition to manipulate the relative proportions of oxidative breakdown products, non-oxidative breakdown products, and non-destructive remediation processes. The method further involves collecting the volatilized contaminant, and any gaseous breakdown products of the contaminant.