Disclosed are methods, apparatuses and systems for the remediation of contaminated soils, groundwater, water, and/or waste using a combination of reagents. The disclosed methods may be used to treat various recalcitrant halogenated substances, such as perfluoroalkyls and polyfluoroalkyls. Particular combinations of reagents that may be used in the disclosed methods include but are not limited to: (1) persulfate, oxygen and ozone; (2) persulfate, salt, oxygen and ozone; (3) persulfate, phosphate, and/or oxygen; (4) persulfate, phosphate, oxygen and ozone; (5) persulfate, phosphate, salt and oxygen (6) persulfate, phosphate, salt, oxygen and ozone; (7) oxygen and salt; and (8) air and salt. The disclosed methods may enhance destruction of organic contaminants in the liquid phase and may also control the rate of aerosol or foam formation relative to the rate of chemical oxidation and/or reduction/transfer.

Disclosed are methods, apparatuses and systems for the remediation of contaminated soils, groundwater, water, and/or waste using a combination of reagents. The disclosed methods may be used to treat various recalcitrant halogenated substances, such as perfluoroalkyls and polyfluoroalkyls. Particular combinations of reagents that may be used in the disclosed methods include but are not limited to: (1) persulfate, oxygen and ozone; (2) persulfate, salt, oxygen and ozone; (3) persulfate, phosphate, and/or oxygen; (4) persulfate, phosphate, oxygen and ozone; (5) persulfate, phosphate, salt and oxygen (6) persulfate, phosphate, salt, oxygen and ozone; (7) oxygen and salt; and (8) air and salt. The disclosed methods may enhance destruction of organic contaminants in the liquid phase and may also control the rate of aerosol or foam formation relative to the rate of chemical oxidation and/or reduction/transfer.

The present invention provides a remediation method for degradation of cadmium in soil. The specific steps are as follows: step 1, determining the content of cadmium in the soil; step 2, crushing and sieving soil from a soil surface, and weighing; step 3, wetting the soil, and removing part of cadmium in the soil to obtain semi-remediated soil; step 4, mixing the semi-remediated soil with a remediation agent, and allowing to stand to obtain improved soil; and step 5, planting Bidens pilosa in the improved soil, and when a growing season is finished, uprooting, and ashing to obtain finished soil. The present invention utilizes anode and cathodes and a remediation agent to treat the cadmium contaminated soil, and plants Bidens pilosa in the soil to achieve a joint effect of electrodynamic remediation, chemical remediation, microbial remediation and phytoremediation to remediate the cadmium contaminated soil.

A reactor (16) for the remediation of polyfluoroalkyl- and/or microplastic-contaminated feedstocks includes an elongated, horizontally oriented, axially rotatable drum (34) having a shell (72) within a housing (32), with a feedstock input assembly (38) adjacent one end of the drum (34) and a feedstock output assembly (40) adjacent the opposite end thereof. A burner (94) within the housing (32) generates hot combustion gases which surround the drum (34) in order to conductively heat feedstock passing through the drum (34). The invention substantially completely remediates the feedstocks through volatilization of the contaminants.

Porous media containing undesired substances, e.g., perfluoroalkylated substances, are treated by mixing the porous media with a solid fuel comprising organic material. The mixture is heated to 200 C. to 400 C. to initiate smoldering combustion and an oxidizer gas is forced through the heated mixture such that the smoldering combustion is self-sustaining until the mixture reaches a PFAS destructive temperature and the perfluoroalkylated substances are thermally destroyed. A system is provided for conducting the treatment. The system includes a source of wax, wood chips, sawdust, tire scraps, waste rubber compounds, coal, granular activated carbon, solid fat, and combinations thereof as solid fuel. A mixer is provided for mixing the porous media with the solid fuel. An ignition system including static heating elements and a gas blower are provided for forcing heated oxidizer gas through the mixture such that self-sustaining smoldering combustion of the mixture is initiated and sustained.

Porous media containing undesired substances, e.g., perfluoroalkylated substances, are treated by mixing the porous media with a solid fuel comprising organic material. The mixture is heated to 200 C. to 400 C. to initiate smoldering combustion and an oxidizer gas is forced through the heated mixture such that the smoldering combustion is self-sustaining until the mixture reaches a PFAS destructive temperature and the perfluoroalkylated substances are thermally destroyed. A system is provided for conducting the treatment. The system includes a source of wax, wood chips, sawdust, tire scraps, waste rubber compounds, coal, granular activated carbon, solid fat, and combinations thereof as solid fuel. A mixer is provided for mixing the porous media with the solid fuel. An ignition system including static heating elements and a gas blower are provided for forcing heated oxidizer gas through the mixture such that self-sustaining smoldering combustion of the mixture is initiated and sustained.

A combination subsurface heating system that incorporates electrical resistance heating and thermal conduction heating with systems disposed within a single borehole. The combination heating system includes an electrically conductive outermost well casing and a heating element that is electrically isolated from the casing but disposed within it or in an adjacent casing but within the same borehole. Each of the two heating components is powered by a separate power source.

Methods are provided for the removal of sulfur and other ARD/AMD-generating materials through the smoldering combustion of an organic material. The methods comprise admixing an ARD/AMD-generating porous matrix material with an organic material to produce a mixture, exposing the mixture to an oxidant, and initiating a self-sustaining smoldering combustion of the mixture. Additional embodiments aggregate the organic material or ARD/AMD-generating porous matrix material or mixture thereof in an impoundment such as a reaction vessel, depression or matrix pile. Further embodiments utilize at least one heater to initiate combustion and at least one air supply port to supply oxidant to initiate and maintain combustion.

Methods are provided for the removal of sulfur and other ARD/AMD-generating materials through the smoldering combustion of an organic material. The methods comprise admixing an ARD/AMD-generating porous matrix material with an organic material to produce a mixture, exposing the mixture to an oxidant, and initiating a self-sustaining smoldering combustion of the mixture. Additional embodiments aggregate the organic material or ARD/AMD-generating porous matrix material or mixture thereof in an impoundment such as a reaction vessel, depression or matrix pile. Further embodiments utilize at least one heater to initiate combustion and at least one air supply port to supply oxidant to initiate and maintain combustion.

Methods and systems for treating an oil/water vapor stream containing solids fines. Routing a feed composition of oil/water vapors containing fine solids to a condensing unit, combining the feed composition with a cooled OWS emulsion, forming a warmed OWS emulsion. The warmed OWS emulsion is routed to a surge vessel containing a volume of surge OWS emulsion, where after a first portion of the surge OWS emulsion is routed to a heat exchanger, forming the cooled OWS emulsion, and a second portion of the surge OWS emulsion is routed to an OWS separation unit. The OWS separation unit may be one or more disc stack centrifuges, in some cases preceded by one or more decanting centrifuges. In certain embodiments the oil/water vapor stream containing solids fines is generated from a thermal desorption unit, such as a turbulent vacuum thermal desorption unit. Systems may be integrated with thermal desorption units and drilling rigs.