The present invention provides an outer layer material for a composite roll for rolling, in which the strength of secondary eutectic carbides can be increased by reducing a B amount in the secondary eutectic carbides and surface roughening resistance can be improved, and a composite roll for rolling in which this outer layer material is used in an outer layer. The outer layer material for a composite roll for rolling of the present invention is an outer layer material for a composite roll for rolling containing C in an amount of 1.8 mass % or more and 2.5 mass % or less, Si in an amount of more than 0 mass % and 1.0 mass % or less, Mn in an amount of more than 0 mass % and 1.0 mass % or less, Ni in an amount of more than 0 mass % and 0.5 mass % or less, Cr in an amount of more than 3.0 mass % and 8.0 mass % or less, Mo in an amount of more than 2.0 mass % and 10.0 mass % or less, W in an amount of more than 0 mass % and 10.0 mass % or less, V in an amount of more than 0 mass % and 10.0 mass % or less, and B in an amount of more than 0 mass % and less than 0.01 mass %, and a remaining portion including Fe and inevitable impurities.

A centrifugally cast composite roll comprising an outer layer formed by a centrifugal casting method, and an inner layer made of ductile cast iron and integrally fused to the outer layer, the outer layer being made of an Fe-based alloy comprising by mass 1.3-3.7% of C, 0.3-3% of Si, 0.1-3% of Mn, 1-7% of Cr, 1-8% of Mo, at least one of 2.5-7% of V, 0.1-3% of Nb and 0.1-5% of W (V is indispensable), and 0.01-0.2% of B and/or 0.05-0.3% of S, the balance being substantially Fe and inevitable impurities, the outer layer having a structure containing no graphite; the inner layer comprising a core portion fused to the outer layer, and a drive-side shaft portion and a free-side shaft portion integrally extending from both ends of the core portion; the total amount of Cr, Mo, V, Nb and W being 0.35-2% by mass in an end portion of the drive-side shaft portion and 0.15-1.8% by mass in an end portion of the free-side shaft portion, the former being larger than the latter by 0.2% or more by mass.

A centrifugally cast composite roll comprising an outer layer formed by a centrifugal casting method, and an inner layer made of ductile cast iron and integrally fused to the outer layer, the outer layer being made of an Fe-based alloy comprising by mass 1.3-3.7% of C, 0.3-3% of Si, 0.1-3% of Mn, 1-7% of Cr, 1-8% of Mo, at least one of 2.5-7% of V, 0.1-3% of Nb and 0.1-5% of W (V is indispensable), and 0.01-0.2% of B and/or 0.05-0.3% of S, the balance being substantially Fe and inevitable impurities, the outer layer having a structure containing no graphite; the inner layer comprising a core portion fused to the outer layer, and a drive-side shaft portion and a free-side shaft portion integrally extending from both ends of the core portion; the total amount of Cr, Mo, V, Nb and W being 0.35-2% by mass in an end portion of the drive-side shaft portion and 0.15-1.8% by mass in an end portion of the free-side shaft portion, the former being larger than the latter by 0.2% or more by mass.

A centrifugally cast, hot-rolling composite roll comprising an outer layer formed by a centrifugal casting method, and an inner layer made of ductile cast iron and integrally fused to the outer layer; the outer layer having a chemical composition comprising by mass 1-3% of C, 0.4-3% of Si, 0.3-3% of Mn, 1-5% of Ni, 2-7% of Cr, 3-8% of Mo, 3-7% of V, and 0.01-0.12% of B, the balance being Fe and inevitable impurities, and meeting the relation expressed by Cr/(Mo+0.5W)<−2/3[C−0.2(V+1.19Nb)]+11/6, wherein W=0, and Nb=0, when W and Nb are not contained; and containing by area 1-15% of MC carbide, 0.5-20% of carboboride, and 0.5-20% of Mo-based carbide.

A centrifugally cast, hot-rolling composite roll comprising an outer layer formed by a centrifugal casting method, and an inner layer made of ductile cast iron and integrally fused to the outer layer; the outer layer having a chemical composition comprising by mass 1-3% of C, 0.4-3% of Si, 0.3-3% of Mn, 1-5% of Ni, 2-7% of Cr, 3-8% of Mo, 3-7% of V, and 0.01-0.12% of B, the balance being Fe and inevitable impurities, and meeting the relation expressed by Cr/(Mo+0.5W)<−2/3[C−0.2(V+1.19Nb)]+11/6, wherein W=0, and Nb=0, when W and Nb are not contained; and containing by area 1-15% of MC carbide, 0.5-20% of carboboride, and 0.5-20% of Mo-based carbide.

A centrifugally cast, hot-rolling composite roll comprising an outer layer formed by a centrifugal casting method, and an inner layer made of ductile cast iron and integrally fused to the outer layer; the outer layer having a chemical composition comprising by mass 1.6-3% of C, 0.3-2.5% of Si, 0.3-2.5% of Mn, 0.1-5% of Ni, 2.8-7% of Cr, 1.8-6% of Mo, 3.3-6.5% of V, and 0.02-0.12% of B (or 0.01-0.12% of B, and 0.05-02% of S), the balance being Fe and inevitable impurities, and meeting the relation expressed by Cr/(Mo+0.5W)≥−2/3[C−0.2(V+1.19Nb)]+11/6, wherein W=0, and Nb=0, when W and Nb are not contained, and containing by area 1-15% of MC carbide, 0.5-20% of carboboride, and 1-25% of Cr-based carbide.

A centrifugally cast, hot-rolling composite roll comprising an outer layer formed by a centrifugal casting method, and an inner layer made of ductile cast iron and integrally fused to the outer layer; the outer layer having a chemical composition comprising by mass 1.6-3% of C, 0.3-2.5% of Si, 0.3-2.5% of Mn, 0.1-5% of Ni, 2.8-7% of Cr, 1.8-6% of Mo, 3.3-6.5% of V, and 0.02-0.12% of B (or 0.01-0.12% of B, and 0.05-02% of S), the balance being Fe and inevitable impurities, and meeting the relation expressed by Cr/(Mo+0.5W)≥−2/3[C−0.2(V+1.19Nb)]+11/6, wherein W=0, and Nb=0, when W and Nb are not contained, and containing by area 1-15% of MC carbide, 0.5-20% of carboboride, and 1-25% of Cr-based carbide.

A centrifugally cast composite roll for hot rolling comprising an outer layer having a composition comprising by mass 0.8-3.5% of C, 0.1-2.5% of Si, 0.1-2.5% of Mn, 1.2-15% of Cr, 1-5% of Ni, and 1-10% of Mo+0.5×W, the balance being substantially Fe and inevitable impurities, and an inner layer made of an iron-based alloy and integrally fused to the outer layer; the outer layer having Shore hardness of 67-82 at the initial diameter of the composite roll; and the maximum Shore hardness of the outer layer in a range 30 mm or more deep from the initial diameter being higher by 1 or more than the Shore hardness of the outer layer at the initial diameter.

A centrifugally cast composite roll for hot rolling comprising an outer layer having a composition comprising by mass 0.8-3.5% of C, 0.1-2.5% of Si, 0.1-2.5% of Mn, 1.2-15% of Cr, 1-5% of Ni, and 1-10% of Mo+0.5×W, the balance being substantially Fe and inevitable impurities, and an inner layer made of an iron-based alloy and integrally fused to the outer layer; the outer layer having Shore hardness of 67-82 at the initial diameter of the composite roll; and the maximum Shore hardness of the outer layer in a range 30 mm or more deep from the initial diameter being higher by 1 or more than the Shore hardness of the outer layer at the initial diameter.

A coating liquid for preparing a needle-shaped cylinder liner, comprising the following components: 0.05-0.4 parts of an anionic surfactant; 0.05-0.5 parts of tannic acid; 0.15-0.7 parts of caustic soda; 22-38 parts of diatomite; 3-10 parts of montmorillonite; and 62-75 parts of water. A method for preparing a needle-shaped cylinder liner comprises spraying a coating liquid for preparing the needle-shaped cylinder liner onto the inner wall of a hollow cylindrical mould, and drying the coating liquid to obtain a mould with a coating attached to the surface of the inner wall; adding an inoculated iron liquid into the rotary mould, and cooling and demoulding to obtain a cylinder liner blank; and subjecting the blank to outer surface cleaning and forming machining to obtain the needle-shaped cylinder liner.