A composition for the additive manufacture of three-dimensional objects is provided. The composition includes a sinterable frit, a protein binder, and an aqueous-based solvent.

An R-T-B based permanent magnet includes main phase grains composed of R.sub.2T.sub.14B type compound. R is a rare earth element. T is iron group element(s) essentially including Fe or Fe and Co. B is boron. An average grain size of the main phase grains is 0.8 μm to 2.8 μm. The R-T-B based permanent magnet contains at least C and Ga in addition to R, T, and B. B is contained at 0.71 mass % to 0.86 mass %. C is contained at 0.13 mass % to 0.34 mass %. Ga is contained at 0.40 mass % to 1.80 mass %. A formula (1) of 0.14≦[C]/([B]+[C])≦0.30 is satisfied, where [B] is a B content represented by atom %, and [C] is a C content represented by atom %.

An R-T-B based permanent magnet includes main phase grains composed of R.sub.2T.sub.14B type compound. R is a rare earth element. T is iron group element(s) essentially including Fe or Fe and Co. B is boron. An average grain size of the main phase grains is 0.8 μm to 2.8 μm. The R-T-B based permanent magnet contains at least C and Ga in addition to R, T, and B. B is contained at 0.71 mass % to 0.86 mass %. C is contained at 0.13 mass % to 0.34 mass %. Ga is contained at 0.40 mass % to 1.80 mass %. A formula (1) of 0.14≦[C]/([B]+[C])≦0.30 is satisfied, where [B] is a B content represented by atom %, and [C] is a C content represented by atom %.

An iron-based sintered sliding member is provided in which solid lubricating agent is dispersed uniformly inside of powder particles in addition to inside of pores and particle interfaces of the powder, the agent is strongly fixed, and sliding properties and mechanical strength are superior. The iron-based sintered sliding member contains S: 3.24 to 8.10 mass %, remainder: Fe and inevitable impurities, as an overall composition; the metallic structure includes a ferrite base in which sulfide particles are dispersed, and pores; and the sulfide particles are dispersed at a ratio of 15 to 30 vol % versus the base.

An iron-based sintered sliding member is provided in which solid lubricating agent is dispersed uniformly inside of powder particles in addition to inside of pores and particle interfaces of the powder, the agent is strongly fixed, and sliding properties and mechanical strength are superior. The iron-based sintered sliding member contains S: 3.24 to 8.10 mass %, remainder: Fe and inevitable impurities, as an overall composition; the metallic structure includes a ferrite base in which sulfide particles are dispersed, and pores; and the sulfide particles are dispersed at a ratio of 15 to 30 vol % versus the base.

A process of fabricating a shield, a process of preparing a component, and an erosion shield are disclosed. The process of fabricating the shield includes forming a near-net shape shield. The near-net shape shield includes a nickel-based layer and an erosion-resistant alloy layer. The nickel-based layer is configured to facilitate secure attachment of the near-net shaped to a component. The process of preparing the component includes securing a near-net shape shield to a substrate of a component.

A method of manufacturing a three-dimensional target object may include forming a shell from loose machining powder using an additive manufacturing process and subjecting the shell to a densification process to form a target object. The shell may define an enclosure that contains additional machining powder. The densification process may include causing metallurgical bonding between the shell and additional machining powder contained in the enclosure defined by the shell and shrinking and/or distorting the shape of the shell to conform the target object to a three-dimensional model for the target object. The shell may include a plurality of layers and/or parts that differ at least in respect of density. The plurality of layers and/or parts may be configured based at least in part on the shrinking and/or distorting to the shape of the shell needed to conform the target object to the three-dimensional model for the target object.

A method of manufacturing a three-dimensional target object may include forming a shell from loose machining powder using an additive manufacturing process and subjecting the shell to a densification process to form a target object. The shell may define an enclosure that contains additional machining powder. The densification process may include causing metallurgical bonding between the shell and additional machining powder contained in the enclosure defined by the shell and shrinking and/or distorting the shape of the shell to conform the target object to a three-dimensional model for the target object. The shell may include a plurality of layers and/or parts that differ at least in respect of density. The plurality of layers and/or parts may be configured based at least in part on the shrinking and/or distorting to the shape of the shell needed to conform the target object to the three-dimensional model for the target object.

Novel nanoparticle-coated multilayer shell microstructures are disclosed herein. Some variations of the invention provide a material comprising a plurality of hollow microstructures characterized by an average shortest diameter from about 5 microns to about 1 millimeter, wherein each of the microstructures comprises multiple shells, including at least an inner shell and an outmost shell, with a combined thickness that is less than one-tenth of the average shortest diameter. The inner shell and the outmost shell have different composition. The outmost shell comprises nanoparticles sized between about 10 nanometers to about 500 nanometers, and the nanoparticles each contain an oxide and/or are surrounded by an oxide layer having a layer thickness of at least 1 nanometer. Several microstructure configurations are illustrated in the drawings.

Novel nanoparticle-coated multilayer shell microstructures are disclosed herein. Some variations of the invention provide a material comprising a plurality of hollow microstructures characterized by an average shortest diameter from about 5 microns to about 1 millimeter, wherein each of the microstructures comprises multiple shells, including at least an inner shell and an outmost shell, with a combined thickness that is less than one-tenth of the average shortest diameter. The inner shell and the outmost shell have different composition. The outmost shell comprises nanoparticles sized between about 10 nanometers to about 500 nanometers, and the nanoparticles each contain an oxide and/or are surrounded by an oxide layer having a layer thickness of at least 1 nanometer. Several microstructure configurations are illustrated in the drawings.