A multi-material three-dimensional printing apparatus is provided. The provided apparatus includes two or more print stations. Each of the print stations includes a substrate, a transportation device, a dispersion device, a compaction device, a printing device, a fixing device, and a fluidized materials removal device. The apparatus also includes an assembly apparatus in communication with the two or more print stations via the transportation device. The apparatus also includes one or more transfer devices in communication with the assembly apparatus. The apparatus also includes a computing and controlling device configured to control the operations of the two or more print stations, the assembly apparatus and the one or more transfer devices.

Described herein are compositions, methods, and systems for printing metal three-dimensional objects. In an example, described is a method of printing a three-dimensional object comprising: (i) depositing a metal powder build material, wherein the metal powder build material has an average particle size of from about 10 μm to about 250 μm; (ii) selectively applying a binder fluid on at least a portion of the metal powder build material, wherein the binder fluid comprises an aqueous liquid vehicle and latex polymer particles dispersed in the aqueous liquid vehicle; (iii) heating the selectively applied binder fluid on the metal powder build material to a temperature of from about 40° C. to about 180° C.; and (iv) repeating (i), (ii), and (iii) at least one time to form the three-dimensional object.

Described herein are compositions, methods, and systems for printing metal three-dimensional objects. In an example, described is a method of printing a three-dimensional object comprising: (i) depositing a metal powder build material, wherein the metal powder build material has an average particle size of from about 10 μm to about 250 μm; (ii) selectively applying a binder fluid on at least a portion of the metal powder build material, wherein the binder fluid comprises an aqueous liquid vehicle and latex polymer particles dispersed in the aqueous liquid vehicle; (iii) heating the selectively applied binder fluid on the metal powder build material to a temperature of from about 40° C. to about 180° C.; and (iv) repeating (i), (ii), and (iii) at least one time to form the three-dimensional object.

The present invention relates to an additive manufacturing powder material including Fe alloy particles each having an oxide film on a surface thereof, in which the Fe alloy particles satisfy d≤15 and I/d≤0.025, where d [nm] represents a thickness of the oxide film, and a peak intensity ratio I represents an intensity ratio IB/IA of a peak B in a region B of a Raman shift of 1,309 to 1,329 cm.sup.−1 to a peak A in a region A of a Raman shift of 657.5 to 677.5 cm.sup.−1 in a Raman spectrum.

The present invention relates to an additive manufacturing powder material including Fe alloy particles each having an oxide film on a surface thereof, in which the Fe alloy particles satisfy d≤15 and I/d≤0.025, where d [nm] represents a thickness of the oxide film, and a peak intensity ratio I represents an intensity ratio IB/IA of a peak B in a region B of a Raman shift of 1,309 to 1,329 cm.sup.−1 to a peak A in a region A of a Raman shift of 657.5 to 677.5 cm.sup.−1 in a Raman spectrum.

This invention provides a method for manufacturing parts with a built-in channel. Two kinds of materials with different melting points are used, the material with the lower melting point is a molding element with an arbitrary shape, the material with the higher melting point is powdered, and the material with the low melting point is wrapped and positioned in the powder with the high melting point. When the preparation is completed, the low-temperature material is melted down, and the channel with the random shape is formed after sintering. In the application that the metal parts need supply water, air, or oil, instead of the channel acquired by mechanical splicing or the channel molded by 3D printing technology, this method in the invention is with a wide application range, the lower cost, and the simple and controllable technology, and is suitable for mass production and with very broad market prospects.

This invention provides a method for manufacturing parts with a built-in channel. Two kinds of materials with different melting points are used, the material with the lower melting point is a molding element with an arbitrary shape, the material with the higher melting point is powdered, and the material with the low melting point is wrapped and positioned in the powder with the high melting point. When the preparation is completed, the low-temperature material is melted down, and the channel with the random shape is formed after sintering. In the application that the metal parts need supply water, air, or oil, instead of the channel acquired by mechanical splicing or the channel molded by 3D printing technology, this method in the invention is with a wide application range, the lower cost, and the simple and controllable technology, and is suitable for mass production and with very broad market prospects.

The present invention relates to an additive manufacturing system for powdery starting material which comprises electron beam guns as irradiation units. The system comprises an improved shielding against ionizing radiation, in particular x-rays. By use of the additive manufacturing system according to the invention a compact an lightweight shielding of the construction area is achieved.

Provided is a hard sintered body which exhibits excellent high temperature oxidation resistance and has a high hardness at a high temperature. In the hard sintered body, a binder phase is contained at from 8.8 to 34.4 mol % and the balance is composed of a hard phase and inevitable impurities. The binder phase contains iron aluminide containing FeAl as a main component and alumina that is dispersed in iron aluminide and has a particle size of 1 μm or less. The hard phase is composed of at least one kind selected from carbides, nitrides, carbonitrides and borides of Group 4 metals, Group 5 metals and Group 6 metals in the periodic table, and solid solutions of these. This hard sintered body is obtained by mixing and pulverizing a binding particle powder containing an iron aluminide powder composed of at least one kind selected from FeAl.sub.2, Fe.sub.2Al.sub.5 and FeAl.sub.3 and a hard particle powder composed of at least one kind selected from carbides, nitrides, carbonitrides and borides of Group 4 metals, Group 5 metals and Group 6 metals in the periodic table and then sintering a mixed powder thus obtained.

The disclosure provides a porous metal substrate structure with high gas permeability and redox stability for a SOFC and the fabrication process thereof, the porous metal substrate structure comprising: a porous metal plate composed of first metal particles; and a porous metal film composed of second metal particles and formed on the porous metal plate; wherein the porous metal plate has a thickness more than the porous metal film, and the first metal particle has a size more than the second metal particle. Further, a porous shell containing Fe is formed on the surface of each metal particle by impregnating a solution containing Fe in a high temperature sintering process of reducing or vacuum atmosphere, and the oxidation and reduction processes. The substrate uses the porous shells containing Fe particles to absorb the leakage oxygen.