A manufacturing method for a p-type semiconductor formed by sintering a compound represented by the general chemical formula: Mg.sub.2Si.sub.XSn.sub.YGe.sub.Z (where X+Y+Z=1, X>0, and Y>0, Z>0). The p-type semiconductor has a composition in which X is in the range of 0.00<X0.25, and Z satisfies the relationship: 1.00X+0.40Z2.00X+0.10, where Z>0.00, and Y is in the range of 0.60Y0.95, and Z satisfies either of the relationships: 1.00Y+1.00Z1.00Y+0.75, where 0.60Y0.90 and Z>0.00, and 2.00Y+1.90Z1.00Y+0.75, where 0.90Y0.95 and Z>0.00.

A novel class of reagents, useful for synthesis of elemental nanoparticles, includes at least one element, formally in oxidation state zero in complex with a hydride molecule. The reagents can optionally include an additional ligand incorporated into the complex. Elemental nanoparticles are synthesized by adding solvent to the reagent, optionally with a free ligand and/or a monoatomic cation.

Some variations provide a system for producing a functionalized powder, comprising: an agitated pressure vessel; first particles and second particles contained within the agitated pressure vessel; a fluid contained within the agitated pressure vessel; an exhaust line for releasing the fluid from the agitated pressure vessel; and a means for recovering a functionalized powder containing the second particles disposed onto surfaces of the first particles. A preferred fluid is carbon dioxide in liquefied or supercritical form. The carbon dioxide may be initially loaded into the pressure vessel as solid carbon dioxide. The pressure vessel may be batch or continuous and is operated under reaction conditions to functionalize the first particles with the second particles, thereby producing a functionalized powder, such as nanofunctionalized metal particles in which nanoparticles act as grain refiners for a component ultimately produced from the nanofunctionalized metal particles. Methods for making the functionalized powder are also disclosed.

Nanoparticles, nanoparticle conjugates, devices for making nanoparticles and nanoparticle conjugates, and related methods of use and synthesis are described.

A method for additively manufacturing a part of a nacelle of an aircraft propulsion unit such as an exhaust conduit portion a step of depositing a compound including a TiAl-based powdery intermetallic alloy and consolidating the compound by sintering, without melting the compound.

Included is a method of preparing a compound for bonded magnets, the method including: coating a magnetic material having an average particle size of 10 m or less with a thermosetting resin and a curing agent at a ratio of the equivalent weight of the curing agent to the equivalent weight of the thermosetting resin of 2 or higher and 10 or lower to obtain a coated material; granulating the coated material by compression to obtain a granulated product; milling the granulated product to obtain a milled product; and surface treating the milled product with a silane coupling agent to obtain a compound for bonded magnets, the method either including, between the granulation and the milling, heat curing the granulated product to obtain a cured product, or including, between the milling and the surface treatment, heat curing the milled product to obtain a cured product.

Included is a method of preparing a compound for bonded magnets, the method including: coating a magnetic material having an average particle size of 10 m or less with a thermosetting resin and a curing agent at a ratio of the equivalent weight of the curing agent to the equivalent weight of the thermosetting resin of 2 or higher and 10 or lower to obtain a coated material; granulating the coated material by compression to obtain a granulated product; milling the granulated product to obtain a milled product; and surface treating the milled product with a silane coupling agent to obtain a compound for bonded magnets, the method either including, between the granulation and the milling, heat curing the granulated product to obtain a cured product, or including, between the milling and the surface treatment, heat curing the milled product to obtain a cured product.