In one aspect, composite articles are described herein employing cobalt-based alloy claddings exhibiting high hardness and wear resistance while maintaining desirable integrity and adhesion to surfaces of metallic substrates. A composite article, in some embodiments, comprises a metallic substrate and a composite cladding metallurgically bonded to one or more surfaces of the metallic substrate, the composite cladding including cobalt-based alloy having a chromium gradient, wherein chromium content increases in a direction from the composite cladding surface to an interface of the composite cladding with the metallic substrate.

The present invention relates to a method of making a cemented carbide comprising mixing in a slurry a first powder fraction and a second powder fraction, subjecting the slurry to milling, drying, pressing and sintering. The first powder fraction is made from cemented carbide scrap recycled using the Zn recovery process, comprising the elements W, C, Co, and at least one or more of Ta, Ti, Nb, Cr, Zr, Hf and Mo, and the second powder fraction comprising virgin raw materials of WC and possibly carbides and/or carbonitrides of one or more of Cr, Zr, W, Ta, Ti, Hf and Nb. The first powder fraction is subjected to a pre-milling step, prior to the step of forming the slurry, to obtain an average grain size of between 0.2 to 1.5 μm.

The present invention relates to a method of making a cemented carbide comprising mixing in a slurry a first powder fraction and a second powder fraction, subjecting the slurry to milling, drying, pressing and sintering. The first powder fraction is made from cemented carbide scrap recycled using the Zn recovery process, comprising the elements W, C, Co, and at least one or more of Ta, Ti, Nb, Cr, Zr, Hf and Mo, and the second powder fraction comprising virgin raw materials of WC and possibly carbides and/or carbonitrides of one or more of Cr, Zr, W, Ta, Ti, Hf and Nb. The first powder fraction is subjected to a pre-milling step, prior to the step of forming the slurry, to obtain an average grain size of between 0.2 to 1.5 μm.

A method of 3D printing a metal or alloy product includes providing a layer of a powder bed which comprises a compound of a first metal, and optionally also said first metal in elemental form and/or optionally other elemental metal(s) which are suitable for alloying with said first metal; jetting a functional binder onto selected parts of said layer, wherein said functional binder infiltrates into pores in the powder bed, reacts with said compound of a first metal to form said first metal in elemental form, and locally fuses elemental metal particles of the powder bed in situ, sequentially repeating said steps of applying a layer of powder on top and selectively jetting functional binder, multiple times, to provide a powder bed bonded at selected locations by printed functional binder and; taking the resultant bound 3D structure out of the powder bed.

A cutting tool made of a cemented carbide substrate of WC, a metallic binder phase and gamma phase is provided. The cemented carbide has a well distributed gamma phase and a reduced amount of abnormal WC grains. The cutting tool has a more predicted tool life and an increased resistance against plastic deformation.

A component can include a degradable portion that is degradable in an aqueous environment; and a non-degradable portion that is not degradable in the aqueous environment where the non-degradable portion can include polycrystalline diamond.

Provided is a hard sintered body which exhibits excellent high temperature oxidation resistance and has a high hardness at a high temperature. In the hard sintered body, a binder phase is contained at from 8.8 to 34.4 mol % and the balance is composed of a hard phase and inevitable impurities. The binder phase contains iron aluminide containing FeAl as a main component and alumina that is dispersed in iron aluminide and has a particle size of 1 μm or less. The hard phase is composed of at least one kind selected from carbides, nitrides, carbonitrides and borides of Group 4 metals, Group 5 metals and Group 6 metals in the periodic table, and solid solutions of these. This hard sintered body is obtained by mixing and pulverizing a binding particle powder containing an iron aluminide powder composed of at least one kind selected from FeAl.sub.2, Fe.sub.2Al.sub.5 and FeAl.sub.3 and a hard particle powder composed of at least one kind selected from carbides, nitrides, carbonitrides and borides of Group 4 metals, Group 5 metals and Group 6 metals in the periodic table and then sintering a mixed powder thus obtained.

Superabrasive compacts and methods of making superabrasive compacts are disclosed. A superabrasive compact includes a polycrystalline diamond table and a substrate attached to the polycrystalline diamond table. The substrate includes a hard metal carbide and a binder having a compound with a composition of A.sub.xB.sub.yC.sub.z, where A and B are transition metals, where C is carbon, and where 0≦x≦7, 0≦y≦7, x+y=7, and 0≦z≦3.

Methods of forming larger sintered compacts of PCD and other sintered ultrahard materials are disclosed. Improved solvent metal compositions and layering of the un-sintered construct allow for sintering of thicker and larger high quality sintered compacts. Jewelry may also be made from sintered ultrahard materials including diamond, carbides, and boron nitrides. Increased biocompatibility is achieved through use of a sintering metal containing tin. Methods of sintering perform shapes are provided.

A shaped charge liner may include an apex portion and a skirt portion extending from the apex portion. The skirt portion may include a body connected to the apex portion, a perimeter spaced apart from the apex portion, and a carbide layer extending between and spaced apart from the perimeter and the apex portion. A shaped charge for creating a perforation hole in a wellbore casing may include a shaped charge liner having at least one material having hardness that is greater than a corresponding hardness of the wellbore casing. The at least one material is configured to bond to at least one of an outer surface and an inner surface of the perforation hole upon detonation of the shaped charge and penetration of the casing by a perforation jet.