A gas sensing device is manufactured with three dimensionally connected metal oxide foam structure of large surface area and elongated channel pores within the three-dimensional porous structure for gas sensing applications, thereby increasing the surface area of the sensing layer and expediting sensitivity and sensor response. A gas sensor device includes the fabricated metal-oxide-foam sensing material attached via silver paste to platinum electrodes and ruthenium heater that are printed on low temperature co-fired ceramic substrate. This device will provide improved gas sensing performance with improved sensitivity and response time. Gas sensors including the metal oxide foam sensing material exhibit higher sensitivity to toxic gases such as ethanol and carbon monoxide due to the large surface area achieved from the porous three-dimensional structure providing increased chemical reaction sites and the larger porous channels allowing gases to easily pass, shortening the gas diffusion reaction path.

A dental implant body includes a ceramics sintered body, and the ceramics sintered body is a porous body having blind/continuous holes formed from a surface of the ceramics sintered body and walls formed by the blind/continuous holes. The porosity of the blind/continuous holes may be 50±10%. Further, the diameter of the blind/continuous hole may be equal to or greater than 50 μm and equal to or smaller than 190 μm.

Provided herein are methods for making a freeze-cast material having a internal structure, the methods comprising steps of: determining the internal structure of the material, the internal structure having a plurality of pores, wherein: each of the plurality of pores has directionality; and the step of determining comprises: selecting a temperature gradient and a freezing front velocity to obtain the determined internal structure based on the selected temperature gradient and the selected freezing front velocity; directionally freezing a liquid formulation to form a frozen solid, the step of directionally freezing comprising: controlling the temperature gradient and the freezing front velocity to match the selected temperature gradient and the selected freezing front velocity during directionally freezing; wherein the liquid formulation comprises at least one solvent and at least one dispersed species; and subliming the at least one solvent out of the frozen solid to form the material.

The invention discloses an artificial nacre material with layered structure and preparation method thereof. The preparation method includes the following steps: uniformly mixing a carbonated cementitious material and water at a water-solid ratio of 0.3 to 1.2 to obtain a carbonated cementitious material suspension; treating the carbonated cementitious material suspension by a freeze-casting process to obtain a carbonated cementitious material coagulation with layered structure; treating the carbonated cementitious material coagulation with the layered structure by a freeze-drying process to obtain a carbonated cementitious material with layered structure; treating the carbonated cementitious material with layered structure by a carbonization process to obtain an artificial nacre material with layered structure. The obtained artificial nacre material with layered structure has higher fracture toughness and durability, and the preparation method has the advantages of low energy consumption, carbon dioxide fixation and environmental friendliness.

This invention provides a de-molding system of ceramic parts manufactured by freeze-casting comprising a mold (9), wherein the mold (9) comprises an upper opening (95) and a lower opening (94), wherein the upper opening (95) is adapted to receive a colloidal suspension (92), and one of the openings is adapted to allow the passage of a manufactured ceramic part (92), characterized by comprising at least one main de-molding element (80) adapted to actuate a ceramic part manufactured (92) through an opening in the mold (9). In addition, the invention provides a mold cooling system for the manufacturing of ceramic parts by freeze-casting comprising: a source (1) of cooling gas; a cooling gas cooling medium (7) fluidically connected to the cooling gas source (1); and a cooling cell (5), fluidly connected to the cooling gas cooling medium (7), comprising a mold (9) in its interior, wherein the cooling cell (5) comprises a refrigerated cooling gas injection opening. Thus, a mold cooling system is provided for the manufacturing of ceramic parts by freeze-casting comprising the stages of: refrigerating a cooling gas coming from a cooling gas source (1); and injecting a cooling gas that is refrigerated in a cooling cell (5) comprising a mold (9) in its interior.

The present disclosure relates to the manufacture of ceramic products by aqueous gelcasting. Exemplary ceramic products include sanitary ware, such as toilets and sinks. The process includes a slurrying step, a mixing step, a molding step involving aqueous gelcasting, a drying step, a glazing step, and a firing step.

A method of making a refractory article is provided. The method includes: a) mixing a binder system, a refractory charge, and a second colloidal binder to form an aqueous slurry; b) casting the aqueous slurry into a mold; c) subjecting the mold containing the aqueous slurry to a temperature that is lower than a slurry casting temperature for a time sufficient to form a green strength article; and d) firing the green strength article at a temperature of at least 450° C. for a time sufficient to achieve thermal homogeneity, thereby forming a refractory article. Refractory articles made in accordance with the method have a unique combination of pore structure and mechanical properties.

A method and apparatus for forming variable density ceramic structures, where the method includes: obtaining a ceramic powder having an ultrafine particle size; mixing the ceramic powder into a suspension fluid thus forming a ceramic suspension; providing a mold configured to retain the ceramic suspension; providing a plurality of electrodes about the mold; applying an alternating voltage to the electrodes thus forming alternating electric currents through the suspension thus causing accumulation of ceramic particles on at least one of the electrodes; reducing the temperature of the suspension thus inducing the formation of ice crystals therein necessary for ice-templating; freeze drying the frozen suspension into a porous state; and sintering the ceramic particles into a solid architecture retaining a common final structure with the ceramic particles in the porous state.

The present disclosure relates to the manufacture of ceramic products by aqueous gelcasting. Exemplary ceramic products include sanitary ware, such as toilets and sinks. The process includes a slurrying step, a mixing step, a molding step involving aqueous gelcasting, a drying step, a glazing step, and a firing step.

A method of making a refractory article is provided. The method includes: a) mixing a binder system, a refractory charge, and a second colloidal binder to form an aqueous slurry; b) casting the aqueous slurry into a mold; c) subjecting the mold containing the aqueous slurry to a temperature that is lower than a slurry casting temperature for a time sufficient to form a green strength article; and d) firing the green strength article at a temperature of at least 450° C. for a time sufficient to achieve thermal homogeneity, thereby forming a refractory article. Refractory articles made in accordance with the method have a unique combination of pore structure and mechanical properties.