The present invention has solved the problems of conventional molding materials, and provides a hydraulic composition for additive manufacturing devices having high strength development, particularly high early strength development, and less generation of gas defect and graphite spheroidization defect. Specifically, the hydraulic composition for additive manufacturing devices of the present invention at least contains calcium aluminate. It is preferable that the hydraulic composition contain 0.5-10 parts by mass of gypsum with respect to 100 parts by mass of the calcium aluminate.

Embodiments of disclosure may provide a method for forming an aluminum-containing nitride ceramic matrix composite, comprising heating a green body, an aluminum-containing composition, ammonia and a mineralizer composition in a sealable container to a temperature between about 400 degrees Celsius and about 800 degrees Celsius and a pressure between about 10 MPa and about 1000 MPa, to form an aluminum-containing nitride ceramic matrix composite characterized by a phosphor-to-aluminum nitride (AlN) ratio, by volume, between about 1% and about 99%, by a porosity between about 1% and about 50%, and by a thermal conductivity between about 1 watt per meter-Kelvin and about 320 watts per meter-Kelvin. The green body comprises a phosphor powder comprising at least one phosphor composition, wherein the phosphor powder particles are characterized by a D50 diameter between about 100 nanometers and about 500 micrometers, and the green body has a porosity between about 10% and about 80%. The aluminum-containing composition has a purity, on a metals basis, between about 90% and about 99.9999%. The fraction of free volume within the sealable container contains between about 10% and about 95% of liquid ammonia prior to heating the green body, the aluminum-containing composition, ammonia and the mineralizer composition in the sealable container.

A method of producing a cylindrical insulator for a spark plug includes a molding step of forming ceramic powder filled in a cavity defined by a mold and a molding pin into a compact. In a first removal step of removing the compact from the mold, the compact has at least one protrusion formed in at least one recess of the molding pin formed in an outer cylindrical surface of the molding pin, and the at least one protrusion is locked in the at least one recess, thereby allowing the compact to be removed with the molding pin from the mold. In a second removal step of removing the molding pin from the compact, the molding pin is turned or rotated in the circumferential direction about the compact, causing the at least one recess to cut the at least one protrusion from the compact, and thereafter the molding pin is removed from the compact.

A three-dimensional shaped article producing composition is provided and contains a plurality of particles, a solvent for dispersing the particles, and a binder having a function to temporarily bind the particles to one another in a state where the solvent is removed, wherein a volume-based average particle diameter of the particles is 0.1 μm or more and less than 50 μm, and a content ratio of the binder is 1.5 vol % or more and 10 vol % or less.

An airfoil for a gas turbine engine is provided that includes a first portion formed from a first plurality of plies of a ceramic matrix composite material and defining an inner surface of the airfoil, as well as a second portion formed from a second plurality of plies of a ceramic matrix composite material and defining an outer surface of the airfoil. The first portion and the second portion define a non-line of sight cooling aperture extending from the inner surface to the outer surface of the airfoil. In one embodiment, a surface angle that is less than 45° is defined between a second aperture and the outer surface. A method for forming an airfoil for a gas turbine engine also is provided.

An airfoil for a gas turbine engine is provided that includes a first portion formed from a first plurality of plies of a ceramic matrix composite material and defining an inner surface of the airfoil, as well as a second portion formed from a second plurality of plies of a ceramic matrix composite material and defining an outer surface of the airfoil. The first portion and the second portion define a non-line of sight cooling aperture extending from the inner surface to the outer surface of the airfoil. In one embodiment, a surface angle that is less than 45° is defined between a second aperture and the outer surface. A method for forming an airfoil for a gas turbine engine also is provided.

A method of fabricating three-dimensional (3D) structures comprises forming a patterned area in a handle wafer, and bonding a mold wafer over the patterned area to produce one or more sealed cavities having a first pressure in the handle wafer. The mold wafer is heated past its softening point at a second pressure different from the first pressure to create a differential pressure across the mold wafer over the sealed cavities. The mold wafer is then cooled to harden the mold wafer into one or more 3D shapes over the sealed cavities. One or more materials are deposited on an outer surface of the mold wafer over the 3D shapes to form a structure layer having 3D structures that conform to the hardened 3D shapes of the mold wafer. The 3D structures are then bonded to a device wafer, and the handle wafer is removed to expose the 3D structures.

A method of fabricating three-dimensional (3D) structures comprises forming a patterned area in a handle wafer, and bonding a mold wafer over the patterned area to produce one or more sealed cavities having a first pressure in the handle wafer. The mold wafer is heated past its softening point at a second pressure different from the first pressure to create a differential pressure across the mold wafer over the sealed cavities. The mold wafer is then cooled to harden the mold wafer into one or more 3D shapes over the sealed cavities. One or more materials are deposited on an outer surface of the mold wafer over the 3D shapes to form a structure layer having 3D structures that conform to the hardened 3D shapes of the mold wafer. The 3D structures are then bonded to a device wafer, and the handle wafer is removed to expose the 3D structures.

Provided in one embodiment is a method of making, comprising: applying a hydrodynamic cavitation process to a raw material comprising particles comprising a metal-containing material or a carbon containing material of a first size to produce a slurry having particles comprising the metal-containing material or the carbon-containing material of a second size, smaller than the first size; and tape casting the slurry to form a green tape. Apparatuses employed to apply the method and the exemplary compositions made in accordance with the method are also provided.

Provided in one embodiment is a method of making, comprising: applying a hydrodynamic cavitation process to a raw material comprising particles comprising a metal-containing material or a carbon containing material of a first size to produce a slurry having particles comprising the metal-containing material or the carbon-containing material of a second size, smaller than the first size; and tape casting the slurry to form a green tape. Apparatuses employed to apply the method and the exemplary compositions made in accordance with the method are also provided.