Methods and ceramic matrix composite articles formed thereby, as well as systems for making such ceramic matrix composite articles and carrying out such methods are disclosed herein. The methods include preparing a ceramic matrix composite by steps including (a) providing reinforcing fiber, such as carbon fiber, for impregnation; (b) heat treating the reinforcing fiber; (c) impregnating the heat treated reinforcing fiber with a composition comprising a ceramic forming polymer to form a fiber reinforced, ceramic forming polymer pre-preg; and (d) heat molding the fiber reinforced, ceramic forming polymer pre-preg to form a molded ceramic matrix composite article.

Methods and ceramic matrix composite articles formed thereby, as well as systems for making such ceramic matrix composite articles and carrying out such methods are disclosed herein. The methods include preparing a ceramic matrix composite by steps including (a) providing reinforcing fiber, such as carbon fiber, for impregnation; (b) heat treating the reinforcing fiber; (c) impregnating the heat treated reinforcing fiber with a composition comprising a ceramic forming polymer to form a fiber reinforced, ceramic forming polymer pre-preg; and (d) heat molding the fiber reinforced, ceramic forming polymer pre-preg to form a molded ceramic matrix composite article.

A method for making a carbonated precast concrete product includes: obtaining a mixture including at least one binder material, an aggregate, and water; molding the mixture into a molded intermediate; demolding the molded intermediate to obtain a demolded intermediate, the demolded intermediate having a first water-to-binder ratio; conditioning the demolded intermediate to provide a conditioned article having a second water-to-binder ratio less than the first water-to-binder ratio of the demolded intermediate; moisturizing at least one surface of the conditioned article with an aqueous medium, thereby causing a weight gain of the conditioned article and providing a moisturized product, a first portion of the moisturized product having a third water-to-binder ratio greater than a fourth water-to-binder ratio of a remainder of the moisturized product; and curing the moisturized product with carbon dioxide to obtain the carbonated precast concrete product.

The disclosed subject matter concerns earth based mixtures, methods of preparing mixtures, and a process of forming articles of manufacture, as well as a process of manufacturing articles in molds configured for compression molding of earth based mixtures in accordance with the disclosed subject matter, including mixtures containing one or more of, e.g., sand, silt, clay, minerals, or any combination thereof.

A disclosed method of forming a ceramic article includes forming a pre-ceramic polymer article within a mold tool, and performing a first pyrolizing step on the initial pre-ceramic polymer article to form a ceramic article. The method further includes performing at least one pre-heat treatment polymer infiltration and pyrolizing (PIP) cycle on the ceramic article and an initial heat treatment cycle of the ceramic article after the at least one pre-heat treatment PIP cycle. Subsequent PIP cycles and heat treatment cycles are performed in combination to form a ceramic article including a desired density.

A disclosed method of forming a ceramic article includes forming a pre-ceramic polymer article within a mold tool, and performing a first pyrolizing step on the initial pre-ceramic polymer article to form a ceramic article. The method further includes performing at least one pre-heat treatment polymer infiltration and pyrolizing (PIP) cycle on the ceramic article and an initial heat treatment cycle of the ceramic article after the at least one pre-heat treatment PIP cycle. Subsequent PIP cycles and heat treatment cycles are performed in combination to form a ceramic article including a desired density.

A method for producing a consolidated fiber preform intended for the manufacture of a part made of composite material, includes shaping a fiber texture in a heated metal mold, the texture being pre-impregnated with a transient or fugitive material, or shaping a fiber texture in a metal mold and injecting a transient or fugitive material into the fiber texture held in shape in the metal mold, cooling the mold, removing the set fiber preform from the mold, coating the fiber preform with a slurry containing a powder of ceramic or carbon particles, heat-treating the coated fiber preform so as to form a porous shell around the fiber preform by consolidation of the slurry and so as to remove the transient or fugitive material present in the fiber preform, consolidating the fiber preform by gas-phase chemical infiltration.

A method for producing a consolidated fiber preform intended for the manufacture of a part made of composite material, includes shaping a fiber texture in a heated metal mold, the texture being pre-impregnated with a transient or fugitive material, or shaping a fiber texture in a metal mold and injecting a transient or fugitive material into the fiber texture held in shape in the metal mold, cooling the mold, removing the set fiber preform from the mold, coating the fiber preform with a slurry containing a powder of ceramic or carbon particles, heat-treating the coated fiber preform so as to form a porous shell around the fiber preform by consolidation of the slurry and so as to remove the transient or fugitive material present in the fiber preform, consolidating the fiber preform by gas-phase chemical infiltration.

An object of the present invention is to provide an inorganic board suitable for achieving high specific strength and high freeze-thaw resistance as well as weight reduction and a method for producing the inorganic board. An inorganic board X1 according to the present invention includes a cured layer 11 that includes an inorganic cured matrix, an organic reinforcement material dispersed therein, and a hollow body that is attached to the organic reinforcement material and is smaller than the maximum length of the organic reinforcement material. A method for producing an inorganic board according to the present invention includes a first step of preparing a first mixture through mixing of an organic reinforcement material and a hollow body smaller than the maximum length of the organic reinforcement material, a second step of preparing a second mixture through mixing of the first mixture, a hydraulic material, and a siliceous material, and a third step of forming a second mixture mat by depositing the second mixture.

An automated robotic printing device for additive manufacturing or three-dimensional printing of an engineered cementitious composite (ECC) structure is provided. The device has a feeding system and an automated extrusion system configured to receive the ECC composition from the feeding system and deposit the ECC composition onto a target. The automated extrusion system comprising at least one robotic device comprising a tiltable and steerable deposition head that comprises an extrusion nozzle having a substantially rectangular opening and at least one shaping blade at a terminal end to shape and deposit the cementitious composition onto a target. Methods of additive manufacturing of a structure from the ECC compositions are also provided.