Disclosed are bio-based mono-ethylene glycol (MEG) compositions containing from about 1 ppm to about 5000 ppm of at least one C3-C12 1,2-diol, bio-based polyester compositions made therefrom, and methods of making the same are disclosed. Preforms and blow-molded polyester containers prepared from the bio-based MEG and polyester are described.

Disclosed are bio-based mono-ethylene glycol (MEG) compositions containing from about 1 ppm to about 5000 ppm of at least one C3-C12 1,2-diol, bio-based polyester compositions made therefrom, and methods of making the same are disclosed. Preforms and blow-molded polyester containers prepared from the bio-based MEG and polyester are described.

A resin composition comprises: a modified EVOH (A) that is represented by a following formula (I), has contents (mol %) of a, b, and c based on the total monomer units satisfying following formulae (1) through (3), and has a degree of saponification (DS) defined by a following formula (4) of 90 mol % or more; and inorganic oxide particles (B), wherein a content of the inorganic oxide particles (B) is from 5 to 5000 ppm. Such a resin composition is improved in adhesion to a resin other than EVOH, secondary processability, and flexibility without decreasing the performances originally possessed by EVOH, such as gas barrier properties, transparency, flavor retention, solvent resistance, and oil resistance. Accordingly, the resin is preferably used as a molded article, a film, a sheet, a heat shrinkable film, a thermoformed article, a multilayer structure, a coinjection stretch blow molded container, a fuel container, and the like. ##STR00001##
18≤a≤55  (1)
0.01≤c≤20  (2)
[100−(a+c)]×0.9≤b≤[100−(a+c)]  (3)
DS=[(Total Number of Moles of Hydrogen Atoms in X,Y, and Z)/(Total Number of Moles of X,Y, and Z)]×100  (4).

A resin composition comprises: a modified EVOH (A) that is represented by a following formula (I), has contents (mol %) of a, b, and c based on the total monomer units satisfying following formulae (1) through (3), and has a degree of saponification (DS) defined by a following formula (4) of 90 mol % or more; and inorganic oxide particles (B), wherein a content of the inorganic oxide particles (B) is from 5 to 5000 ppm. Such a resin composition is improved in adhesion to a resin other than EVOH, secondary processability, and flexibility without decreasing the performances originally possessed by EVOH, such as gas barrier properties, transparency, flavor retention, solvent resistance, and oil resistance. Accordingly, the resin is preferably used as a molded article, a film, a sheet, a heat shrinkable film, a thermoformed article, a multilayer structure, a coinjection stretch blow molded container, a fuel container, and the like. ##STR00001##
18≤a≤55  (1)
0.01≤c≤20  (2)
[100−(a+c)]×0.9≤b≤[100−(a+c)]  (3)
DS=[(Total Number of Moles of Hydrogen Atoms in X,Y, and Z)/(Total Number of Moles of X,Y, and Z)]×100  (4).

This disclosure provides new methods, compositions, containers, preforms, and designs for refillable carbonated soft drink bottles having improved caustic stress cracking resistance. The method of this disclosure combine the use of PET-based co-polyester resin that incorporates a cyclic hydrocarbon diacid co-monomer and/or a cyclic hydrocarbon diol comonomer, with a bottle design incorporating a petaloid base, for unexpectedly enhanced performance.

This disclosure provides new methods, compositions, containers, preforms, and designs for refillable carbonated soft drink bottles having improved caustic stress cracking resistance. The method of this disclosure combine the use of PET-based co-polyester resin that incorporates a cyclic hydrocarbon diacid co-monomer and/or a cyclic hydrocarbon diol comonomer, with a bottle design incorporating a petaloid base, for unexpectedly enhanced performance.

The disclosure relates to a device and a method for controlling the throughflow of blow-molding fluid during the blow molding of containers. It is the intention to provide a control device and a control method which permit a controlled or defined growth and a defined propagation of the container bubble formed by the expanding preform in the pre-blowing phase of the blow molding process without the specification of a specific setpoint value profile or of a setpoint value curve. The object is achieved by means of a control device and a control method having a proportional valve with a variable throughflow cross section, having an actuator for the operation of the proportional valve, having a means for detecting the position of the actuator, and having sensor means for detecting the valve inlet and valve outlet pressure, wherein a time for the attainment of the yield point for the preform, a container volume and a time period for the attainment of the container volume are predefinable, and, by means of a digital controller, during the pre-blowing phase, from the attainment of the yield point until the run duration, a calculation of control values for the operation of the actuator in order to attain the predefined container volume within the predefined time period is performed in automated cyclic fashion, and the actuator is operated in accordance with the calculated control values, wherein, in each calculation cycle, the calculation of the respectively next control value is performed taking into consideration the container volume attained prior to the respective calculation cycle and calculated on the basis of the previous actuator positions and the previous pressure profile.

The disclosure relates to a device and a method for controlling the throughflow of blow-molding fluid during the blow molding of containers. It is the intention to provide a control device and a control method which permit a controlled or defined growth and a defined propagation of the container bubble formed by the expanding preform in the pre-blowing phase of the blow molding process without the specification of a specific setpoint value profile or of a setpoint value curve. The object is achieved by means of a control device and a control method having a proportional valve with a variable throughflow cross section, having an actuator for the operation of the proportional valve, having a means for detecting the position of the actuator, and having sensor means for detecting the valve inlet and valve outlet pressure, wherein a time for the attainment of the yield point for the preform, a container volume and a time period for the attainment of the container volume are predefinable, and, by means of a digital controller, during the pre-blowing phase, from the attainment of the yield point until the run duration, a calculation of control values for the operation of the actuator in order to attain the predefined container volume within the predefined time period is performed in automated cyclic fashion, and the actuator is operated in accordance with the calculated control values, wherein, in each calculation cycle, the calculation of the respectively next control value is performed taking into consideration the container volume attained prior to the respective calculation cycle and calculated on the basis of the previous actuator positions and the previous pressure profile.

The method for producing wet spun fibers/a wet formed film using a double-walled pipe type micronozzle apparatus according to the present invention is a production method, wherein, in a step of extruding an internal phase comprising a fiber/film material and a good solvent for the fiber/film material in a linear form from the circular/rectangular end of the internal pipe of the apparatus into an external phase comprising a poor solvent for the fiber/film material, the external phase flowing in the external pipe of the apparatus, the ratio of the external phase flow rate to the internal phase flow rate is set to 1 or more, and further for the wet spun fibers, the external phase line speed at the orifice portion at which the internal phase and the external phase merge is set to 0.1 ms.sup.−1 or more.

A method for producing a sterilized container comprises: providing a preform having a hanger arranged on a bottom of the preform, heating the preform in a heating device, feeding the heated preform into a stretching and blowing apparatus, stretching and blowing the preform in the stretching and blowing apparatus such that the container for the infusion solution is formed from the preform, cleaning the formed container in a rinsing apparatus, and drying the cleaned container in a drying device, filling the cleaned and dried container at least with an infusion solution, via a filling opening present in the container, in a filling plant, closing the container by attaching a closure cap to the filling opening of the container, sterilizing the closed container in an autoclave, wherein the hanger of the preform is oriented and folded over by a bending apparatus prior to stretching and blowing in the stretching and blowing apparatus.