B29C55/005

Bioriented polyethylene film

The present invention discloses a process for forming a biaxially oriented film. The process includes first selecting a polyolefin resin wherein said polyolefin resin comprises a linear low density polyethylene resin characterized by having from 9 to 35 weight percent of the total weight of linear low density polyethylene resin eluting from a CEF at a temperature greater than 97.0° C.; and further characterized by having a CDR of from 33 to 80 and a Mw Ratio of from 0.15 to 0.45. Next a film is formed from the polyolefin resin selected in the first step. Finally the film formed in the second step is oriented in a sequential manner. The films produced by this process are characterized by having an ultimate elongation at least 1.5 times greater in the MD as compared to the CD and the 2% secant modulus is a least 1.25 times greater in the CD as compared to the MD. The films are further characterized by having free residual shrinkage of less than 10% in the MD and less than 10% in the CD when exposed to a temperature of 90° C. for 10 minutes.

BALLISTIC-RESISTANT ARTICLE BASED ON FILMS PROVIDED WITH MATRIX
20220090881 · 2022-03-24 · ·

A process for manufacturing a ballistic resistant article including steps: a) stacking a stretchable lamina of ultra-high molecular weight polyethylene (UHMWPE) and a stretchable continuous film of a polymer as organic matrix material to form a lamina-film stack, the continuous film not being an UHMWPE film; b) elongating the stack at a temperature below the melting point of the lamina, to an elongation ratio of at least 2, thereby providing a UHMWPE film with an organic matrix material in which the UHMWPE film is co-stretched with the film of polymer as organic matrix material; c) aligning a plurality of films to form a layer of films; d) stacking at least two layers of films to form a sheet; e) stacking a plurality of sheets to form a stack of sheets, and consolidating the sheets prior to and/or after step e) by applying pressure and optionally heat. Also, a ballistic-resistant article.

Method of making relaxor ferroelectric fluoropolymers

This disclosure relates to a method of making a fluoropolymer object. The method may include providing a substrate including fluoropolymer comprising units derived from monomers M.sub.1, M.sub.2 and M.sub.3, wherein: M.sub.1 is a vinylidene fluoride; M.sub.2 is a monomer of formula (I): CX.sub.1X.sub.2═CX.sub.3X.sub.4, wherein each of X.sub.1, X.sub.2, X.sub.3 and X.sub.4 is independently selected from H, Cl and F, and wherein at least one of X.sub.1, X.sub.2, X.sub.3 and X.sub.4 is F; M.sub.3 is a monomer of formula (II): CY.sub.1Y.sub.2═CY.sub.3CF.sub.3, wherein each of Y.sub.1, Y.sub.2 and Y.sub.3 is independently selected from H, Cl, F, Br, I and alkyl groups comprising from 1 to 3 carbon atoms which are optionally partly or fully halogenated; and stretching the substrate.

BIAXIALLY ORIENTED POLYPROPYLENE FILM

The invention provides a biaxially oriented polypropylene film, wherein a relationship between a loop stiffness stress (S [mN]) in a longitudinal direction and a thickness (t [μm]) satisfies the formula S≥0.00020×t.sup.3, a relationship between a loop stiffness stress (S [mN]) in a width direction and the thickness (t [μm]) satisfies the formula S≥0.0010×t.sup.3, and a heat shrinkage rate of the biaxially oriented polypropylene film at 150° C. is not higher than 10% in the longitudinal direction and not higher than 30% in the width direction, a heat shrinkage rate of the biaxially oriented polypropylene film at 120° C. is not higher than 2.0% in the longitudinal direction and not higher than 5.0% in the width direction, and the heat shrinkage rate at 120° C. in the longitudinal direction is lower than the heat shrinkage rate at 120° C. in the width direction.

BIAXIALLY ORIENTED POLYPROPYLENE FILM

Provided is a biaxially oriented polypropylene film that has high stiffness, has excellent heat resistance at a high temperature of 150° C., easily maintains a bag shape when being made into a packaging bag, and has less pitch shift during printing or fewer wrinkles in a sealed portion when being heat-sealed. A biaxially oriented polypropylene film, wherein a half width of a peak derived from an oriented crystal in a width direction in azimuth dependence of a (110) plane of polypropylene α-type crystal obtained by wide-angle X-ray diffraction measurement is not larger than 27°, and a tan δ area in the width direction obtained from a ratio (E′E″) of a storage elastic modulus (E′) to a loss elastic modulus (E″) obtained by dynamic viscoelasticity measurement is not smaller than 0.2 and not larger than 0.4.

Nanovoided polymers having shaped voids

An example device includes a nanovoided polymer element, a first electrode, and a second electrode. The nanovoided polymer element may be located at least in part between the first electrode and the second electrode. In some examples, the nanovoided polymer element may include anisotropic voids. In some examples, anisotropic voids may be elongated along one or more directions. In some examples, the anisotropic voids are configured so that a polymer wall thickness between neighboring voids is generally uniform. Example devices may include a spatially addressable electroactive device, such as an actuator or a sensor, and/or may include an optical element. A nanovoided polymer layer may include one or more polymer components, such as an electroactive polymer.

Separators, batteries, systems, vehicles, and related methods

Improved battery separators, base films or membranes, batteries, cells, devices, systems, vehicles, and/or methods of making and/or using such separators, films or membranes, batteries, cells, devices, systems, vehicles, and/or methods of enhancing battery or cell charge rates, charge capacity, and/or discharge rates, and/or methods of improving batteries, systems including such batteries, vehicles including such batteries and/or systems, and/or the like; biaxially oriented porous membranes, composites including biaxially oriented porous membranes, biaxially oriented microporous membranes, biaxially oriented macroporous membranes, battery separators with improved charge capacities and the related methods and methods of manufacture, methods of use, and the like; flat sheet membranes, liquid retention media; dry process separators; biaxially stretched separators; dry process biaxially stretched separators having a thickness range between about 5 μm and 50 μm, preferably between about 10 μm and 25 μm, having improved strength, high porosity, and unexpectedly and/or surprisingly high charge capacity, such as, for example, high 10 C rate charge capacity; separators or membranes with high charge capacity and high porosity, excellent charge rate and/or charge capacity performance in a rechargeable and/or secondary lithium battery, such as a lithium ion battery, for high power and/or high energy applications, cells, devices, systems, and/or vehicles, and/or the like; single or multiple ply or layer separators, monolayer separators, trilayer separators, composite separators, laminated separators, co-extruded separators, coated separators, 1 C or higher separators, at least 1 C separators, batteries, cells, systems, devices, vehicles, and/or the like; improved microporous battery separators for secondary lithium batteries, improved microporous battery separators with enhanced or high charge (C) rates, discharge (C) rates, and/or enhanced or high charge capacities in or for secondary lithium batteries, and/or related methods of manufacture, use, and/or the like, and/or combinations thereof are disclosed or provided.

Antifog polyester lidding film for CPET trays

The present disclosure is directed to peelable, heat-sealable lidding films for containers of diverse polymer compositions storing various products such as foodstuffs and pharmaceuticals. The lidding films disclosed herein can be heat-sealed to crystalline polyester trays (CPET), easily peeled, and contain improved antifogging performance by incorporating a non-migratory antifogging additive into the heat sealable layer of the film without deteriorating seal strengths.

Decorative film, method for producing decorative film, and method for producing three-dimensional molded product provided with decorative film

To provide a decorative film in which swelling of a layer containing a fluorinated polymer is suppressed and adhesion of the layer containing the fluorinated polymer is excellent; and a method for producing a three-dimensional molded product provided with a decorative film. The decorative film is characterized by comprising a base film containing a plasticizer; a first layer containing at least one member selected from the group consisting of a polyvinylidene fluoride, a polymethyl methacrylate and a polyurethane; and a second layer containing a fluorinated polymer comprising units based on a fluoroolefin and units based on at least one type of non-fluorinated monomer selected from the group consisting of a vinyl ether, a vinyl ester, an allyl ether and an allyl ester, in this order; wherein the water contact angle of the surface on the first layer side of the second layer is larger than the water contact angle on the second layer side of the first layer, and the difference between the water contact angle of the surface on the first layer side of the second layer and the water contact angle of the surface on the second layer side of the first layer is more than 0° and at most 50°.

BIAXIALLY ORIENTED POLYPROPYLENE FILM

Provided is a biaxially oriented polypropylene film that has high stiffness, has excellent heat resistance at a high temperature of 150° C., easily maintains a bag shape when being made into a packaging bag, and has less pitch shift during printing or fewer wrinkles in a sealed portion when being heat-sealed. A biaxially oriented polypropylene film, wherein a stress at 5% elongation (F5) of the biaxially oriented polypropylene film at 23° C. is not lower than 40 MPa in a longitudinal direction and not lower than 160 MPa in a width direction, and a heat shrinkage rate of the biaxially oriented polypropylene film at 150° C. is not higher than 10% in the longitudinal direction and not higher than 30% in the width direction.