Provided is a method for preparing nylon having triple shape memory effects, comprising the steps of generating amino acid, containing a biomass-derived pyrrolidone group, by using itaconic acid and a diamine; and generating a nylon copolymer by reacting the amino acid containing the pyrrolidone group and an α, ω-aliphatic amino acid. Therefore, provided is a bionylon having triple shape memory effects, capable of shape deformation, fixing and recovery through two steps and adjusting shape recovery temperature to a desired level by controlling the content of a reactant.

The objective of the present invention is to provide a stretched polyamide film which is excellent in laminatability, lamination strength, mechanical properties and shock resistance property and which has effects to prevent goods being broken and protect a content from vibration and shock at the time of transportation when used a various packaging materials. The present invention relates to a stretched polyamide film, wherein a main constituent is nylon 6; at least one surface layer meets the following conditions (1) and (2); and the stretched polyamide film meets the following condition (3): (1) a relaxation degree of a surface layer orientation measured by IR spectroscopy is within a range of not less than 0.3 and not more than 0.5; (2) a crystallization degree of a surface layer measured by IR spectroscopy is within a range of not less than 1.0 and not more than 1.4; (3) a heat shrinkage rate (%) in TD direction at 160° C. for 10 minutes is within a range of not less than 0.6 and not more than 4.

[PROBLEMS] It is an object of the present invention to provide a heat-shrinkable polyester-based film roll which can reduce defects caused during a heat shrinking step due to the variation of a heat shrinkage rate in the heat-shrinkable polyester-based film roll having the longitudinal direction as the main shrinkage direction, specifically, defects of the film when covering an object by a wrap-around method and heat-shrunk. [SOLUTIONS] A heat-shrinkable polyester-based film roll, comprising a core; and a heat-shrinkable polyester-based film having a longitudinal direction as a main shrinkage direction that is wound around the core; wherein the film (roll) satisfy predetermined polyester composition, and all samples cutout every about 100 m have a heat shrinkage rate measured by immersion in hot water of 90° C. for 10 seconds of 30% or more and 80% or less and ±3% or less of an average in the longitudinal direction.

Provided are a polypropylene film that has excellent structural stability relative to heat, is suitable for use in high-voltage capacitors or the like, and, when used in a high-voltage capacitor, has excellent long-term reliability in high-temperature environments; a metal layer laminated film that uses the polypropylene film; and a film capacitor. The polypropylene film has the sum of F5 values for the longitudinal direction and the width direction at 130° C. of at least 15 MPa and, for dielectric breakdown testing at 130° C., a dielectric breakdown voltage (B150) (V/μm) after heat treating for 1 minute at 150° C. and a dielectric breakdown voltage (B0) (V/μm) without heat treating satisfy the following relationship.

(B150)/(B0)≥0.80

A housing structure manufacturing method and an electronic device are provided. The housing structure manufacturing method includes providing a plurality of memory polymeric materials, heating the plurality of memory polymeric materials, and forming the housing structure having a first morphology by printing the plurality of memory polymeric materials that are heated.

A housing structure manufacturing method and an electronic device are provided. The housing structure manufacturing method includes providing a plurality of memory polymeric materials, heating the plurality of memory polymeric materials, and forming the housing structure having a first morphology by printing the plurality of memory polymeric materials that are heated.

The invention provides a heat-shrinkable polyester film with high heat shrinkage ratio in a main shrinkage direction and is also satisfactorily recyclable with used beverage PET bottles to produce a recycled PET resin. The heat-shrinkable polyester film comprises 95-100 mol % of dicarboxylic acid and 0-5 mol % of isophthalic acid in 100 mol % of whole dicarboxylic acid component, 85-98 mol % of ethylene terephthalate unit in 100 mol % of whole ester unit, and 2-15 mol % of diethylene glycol in 100 mol % of whole polyol component, wherein the film has the predetermined hot-water heat shrinkage ratio, as well as the melting peak temperature, the amount of exothermic heat in crystallizing, and the amount of endothermic heat in melting within the predetermined range which are determined through differential scanning calorimetry (DSC) in heating the film to be melted, quenching the film, and re-heating the film.

Embodiments provide an apparel product. The apparel product includes a major component forming a base portion of the apparel product and is configured to be supported and worn at least partially over a portion of a wearer. The apparel product includes a minor component forming a secondary portion configured to be coupled to the major component. An adhesive is disposed at least partially between a portion of the major component and a portion of the minor component. The adhesive includes a shape memory material.

Embodiments provide an apparel product. The apparel product includes a major component forming a base portion of the apparel product and is configured to be supported and worn at least partially over a portion of a wearer. The apparel product includes a minor component forming a secondary portion configured to be coupled to the major component. An adhesive is disposed at least partially between a portion of the major component and a portion of the minor component. The adhesive includes a shape memory material.

A heat-shrinkable polyester film that effectively suppresses a breakage phenomenon is provided. Disclosed is a heat-shrinkable polyester film derived from a polyester resin, the heat-shrinkable polyester film satisfying the following configurations (a) to (c): (a) a thermal shrinkage ratio in the TD direction obtainable under the conditions of 10 seconds in hot water at 80° C. as designated A1 is a value of 25% or greater; (b) when a thermal shrinkage ratio in the TD direction obtainable under the conditions of 10 seconds in hot water at 90° C. as designated A2 is a value of 40% or greater; and (c) when the upper yield point stress is E1 and the lower yield point stress is E2, a numerical value represented by E1−E2 is a value of 5 MPa or less.