The present invention provides polyurethanes including a reaction product of components including: (1) a reaction product of (a) an isocyanate functional urethane prepolymer including a reaction product of components including: (i) about 1 equivalent of at least one polyisocyanate; and (ii) about 0.005 to about 0.35 equivalent of at least one polycaprolactone polyol; and (b) about 0.01 to about 0.5 equivalent of at least one polyol having 2 hydroxyl groups, based upon the about 1 equivalent of the at least one polyisocyanate; and (2) about 0.3 to about 1.0 equivalent of at least one polyol having at least 2 hydroxyl groups, based upon the about 1 equivalent of the at least one polyisocyanate, wherein the at least one polyol (b) can be the same or different from the at least one polyol (2); compositions, coatings and articles made therefrom and methods of making the same.

Methods and apparatus comprising a dewetting phase and a polymerization liquid that are immiscible, and can be used for the formation of three-dimensional objects, wherein the method does not require a dead zone. Additionally, methods and apparatus that employ an optically transparent cooling apparatus to mitigate heat generated during the fabrication process, and the use of a mobile phase to provide a shearing interface to reduce interfacial adhesive forces.

Methods and apparatus comprising a dewetting phase and a polymerization liquid that are immiscible, and can be used for the formation of three-dimensional objects, wherein the method does not require a dead zone. Additionally, methods and apparatus that employ an optically transparent cooling apparatus to mitigate heat generated during the fabrication process, and the use of a mobile phase to provide a shearing interface to reduce interfacial adhesive forces.

An additive production assembly and method is provided by the present disclosure. The assembly includes a tank containing radiation-curable liquid and has at least one radiation-penetrable sidewall, a projector that projects at least one beam to the sidewall, and a transportation assembly to transport an object. The beam acts through the sidewall and an area of the liquid close to the sidewall is hardened to form the object. The object is transported along a transporting direction (T) in a sideward direction away from the sidewall, as a result of which liquid flows into a gap between the object and the sidewall.

A composite body includes a bound mixture, a resin and a coating. The bound mixture includes a binder and a plurality of particles. The resin fully infiltrates the bound mixture such that the resin fully infiltrates an entire thickness of the bound mixture. The composite body is formed by combining a plurality of particles with a binder to form a bound mixture and infiltrating the bound mixture with a resin to a depth such that substantially an entire thickness of the bound mixture contains the resin. The coating defines an outer layer of the composite body.

A process forms an implantable product including poly(glycerol sebacate) urethane (PGSU) loaded with an active pharmaceutical ingredient (API). The process includes homogeneously mixing a flowable poly(glycerol sebacate) (PGS) resin with the API and a catalyst to form a resin blend. The process also includes homogeneously combining the resin blend with an isocyanate to form a reaction mixture and injecting the reaction mixture to form the PGSU loaded with the API. An implantable product includes a PGSU loaded with an API. In some embodiments, the implantable product includes at least 40% w/w of the API, and the implantable product releases the API by surface degradation of the PGSU at a predetermined release rate for at least three months under physiological conditions. In some embodiments, the PGSU is formed from a PGS reacted with an isocyanate at an isocyanate-to-hydroxyl stoichiometric (crosslinking) ratio in the range of 1:0.25 to 1:1.25.

A method for manufacturing an engineered stone, the method including: providing a mixture comprising at least a stone or stone like material and a binder; compacting the mixture; curing the binder; and further comprising printing a printed pattern on at least a top surface of the engineered stone.

The present invention provides an apparatus for manufacturing artificial marble, which includes a granite soil storage unit configured to supply a granite soil by storing, drying, and heating it, a granite soil heating unit configured to heat the granite soil supplied from the granite soil storage unit, a resin storage unit configured to store a thermoplastic polyurethane (TPU) resin maintained in a solid phase at room temperature, a mixing-transporting unit configured to accommodate the TPU resin and the heated granite soil therein and then melting and mixing them to produce and simultaneously transport an artificial marble slurry, a material guide unit configured to guide the granite soil and the TPU resin into the mixing-transporting unit, a discharge unit configured to discharge the artificial marble slurry mixed in the mixing-transporting unit by a certain amount, a mold supply unit configured to continuously supply a mold for accommodating and molding the artificial marble slurry therein, a mold guide unit configured to guide the mold supplied from the mold supply unit downward of the discharge unit to accommodate the artificial marble slurry in the mold, a forming unit configured to form an artificial marble by applying vibration and pressure to the artificial marble slurry accommodated in the mold, an extraction unit configured to extract the mold accommodating the artificial marble, and a lamination unit configured to laminate and store the mold extracted by the extraction unit.

Methods of forming solid carbon products include disposing a plurality of nanotubes in a press, and applying heat to the plurality of carbon nanotubes to form the solid carbon product. Further processing may include sintering the solid carbon product to form a plurality of covalently bonded carbon nanotubes. The solid carbon product includes a plurality of voids between the carbon nanotubes having a median minimum dimension of less than about 100 nm. Some methods include compressing a material comprising carbon nanotubes, heating the compressed material in a non-reactive environment to form covalent bonds between adjacent carbon nanotubes to form a sintered solid carbon product, and cooling the sintered solid carbon product to a temperature at which carbon of the carbon nanotubes do not oxidize prior to removing the resulting solid carbon product for further processing, shipping, or use.

Methods of forming solid carbon products include disposing a plurality of nanotubes in a press, and applying heat to the plurality of carbon nanotubes to form the solid carbon product. Further processing may include sintering the solid carbon product to form a plurality of covalently bonded carbon nanotubes. The solid carbon product includes a plurality of voids between the carbon nanotubes having a median minimum dimension of less than about 100 nm. Some methods include compressing a material comprising carbon nanotubes, heating the compressed material in a non-reactive environment to form covalent bonds between adjacent carbon nanotubes to form a sintered solid carbon product, and cooling the sintered solid carbon product to a temperature at which carbon of the carbon nanotubes do not oxidize prior to removing the resulting solid carbon product for further processing, shipping, or use.