A method of forming a three-dimensional object, which method includes a cleaning or washing step, is carried out by: (a) providing a carrier and a fill level, and optionally an optically transparent member having a build surface defining the fill level, the carrier and the fill level having a build region therebetween; (b) filling the build region with a polymerizable liquid, the polymerizable liquid comprising a mixture of (i) a light polymerizable liquid first component, and (ii) a second solidifiable component that is different from the first component; (c) irradiating the build region with light, to form a solid polymer scaffold from the first component and also advancing the carrier away from the build surface to form a three-dimensional intermediate having the same shape as, or a shape to be imparted to, the three-dimensional object and containing the second solidifiable component carried in the scaffold in unsolidified and/or uncured form; (d) washing the three-dimensional intermediate; and (e) concurrently with or subsequent to the irradiating step, and/or the washing step, solidifying and/or curing the second solidifiable component in the three-dimensional intermediate to form the three-dimensional object.

Disclosed herein are methods of forming a three-dimensional object having a biodegradable or bioerodible polymer or copolymer. In some embodiments, the methods include providing a dual cure resin with a photoinitiator, monomers and/or prepolymers that are polymerizable by exposure to actinic radiation or light, at least one cyclic ester, a ring-opening polymerization initiator, and a ring-opening polymerization catalyst. Resins useful for carrying out such methods, and products produced from such methods, are also described.

In a golf ball having a core and a cover of one or more layer encasing the core, an outermost layer of the cover is molded of a thermoplastic material selected from the group consisting of polyurethane, polyurea and mixtures thereof, and the surface of the cover is treated with a polyisocyanate compound that is free of organic solvent. A method of manufacturing the golf ball is also described. Such golf balls are endowed with an excellent spin performance and scuff resistance, in addition to which productivity of the golf balls is high.

A method of forming a three-dimensional object is carried out by: (a) providing a carrier and an optically transparent member having a build surface, the carrier and the build surface defining a build region therebetween; (b) filling the build region with a polymerizable liquid, the polymerizable liquid including a mixture of (i) a light polymerizable liquid first component, and (ii) a second solidifiable component that is different from the first component; (c) irradiating the build region with light through the optically transparent member to form a solid polymer scaffold from the first component and also advancing the carrier away from the build surface to form a three-dimensional intermediate having the same shape as, or a shape to be imparted to, the three-dimensional object, and containing the second solidifiable component carried in the scaffold in unsolidified and/or uncured form; and (d) concurrently with or subsequent to the irradiating step, solidifying and/or curing the second solidifiable component in the three-dimensional intermediate to form the three-dimensional object.

A part adapted for in vivo endosseous implantation made up of a material comprising a thermoplastic organic binder and a fiber charge. The fibers located in a surface layer of the part are mostly delaminated from the binder over all or part of their length. Also, a method for manufacturing such a part.

A method of 4D printing a hydrogel composite structure comprises depositing a first layer of filaments on a substrate in a first predetermined arrangement, where each filament comprises a hydrogel matrix and a plurality of anisotropic filler particles embedded therein. A second layer of the filaments is deposited in a second predetermined arrangement on the first layer. The filaments from the second layer contact the filaments from the first layer at a number of contact regions. The first layer and the second layer are hydrated, and the filaments of the first and second layers swell in size while remaining in contact at the contact regions. Thus, a curved three-dimensional hydrogel composite structure is formed.

An apparatus and a method for treating an object manufactured from a material having a defined melting temperature, by subjecting the object to hot isostatic pressing to reduce porosity and increase a density thereof. The method comprises arranging the object in a pressure chamber interior cavity, submerged in a liquid partially filling the cavity, heating the liquid to a below melting temperature, pressurizing the liquid by pressurizing gas above a liquid surface in the cavity, then moving the object out of the liquid, but still within the cavity, subsequently heating the liquid to an above melting temperature, and resubmerging the object in the liquid. Subsequently, the object is withdrawn from the liquid and moved above the liquid. The apparatus comprises the pressure chamber, a movable object support in the cavity, a liquid heater, and a gas inlet and outlet selectively introducing gas into and venting gas from the cavity.

A method of forming a three-dimensional object of polyurethane, polyurea, or copolymer thereof is carried out by: (a) providing a carrier and an optically transparent member having a build surface, the carrier and the build surface defining a build region therebetween; (b) filling the build region with a polymerizable liquid, the polymerizable liquid including at least one of: (i) a blocked or reactive blocked prepolymer, (ii) a blocked or reactive blocked diisocyante, or (iii) a blocked or reactive blocked diisocyanate chain extender; (c) irradiating the build region with light through the optically transparent member to form a solid blocked polymer scaffold and advancing the carrier away from the build surface to form a three-dimensional intermediate having the same shape as, or a shape to be imparted to, the three-dimensional object, with the intermediate containing the chain extender; and then (d) heating or microwave irradiating the three-dimensional intermediate sufficiently to form from the three-dimensional intermediate the three-dimensional object of polyurethane, polyurea, or copolymer thereof.

Porous and microporous parts prepared by additive manufacturing as disclosed herein are useful in medical and non-medical applications. The parts are prepared from a composition containing both a solvent soluble component and a solvent insoluble component. After a part is printed by an additive manufacturing process it is exposed to solvent to extract solvent soluble component away from the printed part, resulting in a part having surface cavities.

A method for preparing a fiber composite material toughened by nano-particles, comprising: first dispersing agglomerated nano-particles uniformly in a low-viscosity, volatile dispersant by ultrasonic and micro-jet treatment (two-stage dispersion), and spraying the dispersant containing nano-particles uniformly on the fiber fabric through a high-pressure spray gun; after the liquid is removed from the fiber fabric, subjecting the nano-modified fiber fabric and resin to composite molding. The method provided by the present application is simple to operate, can be scaled up, and does not change the original manufacturing process of the fiber composite material. Moreover, the method provided by the present application requires only a very small amount of toughening components to achieve a significant increase in the interlaminar fracture toughness of the composite, which has great application prospects.