A method for nanoimprinting a pattern on an organic polymer substrate, comprising: (a) preparing a soft operational mold, the operational mold comprising a pattern to be replicated to the substrate; (b) soaking the operational mold in a solvent to produce diffusion of solvent to the mold; (c) removing the operational mold from the solvent, and placing it on a surface of the organic polymer substrate to form a structure, and simultaneously (i) heating the structure to a temperature T<Tg, where Tg is the glass transition temperature of the organic polymer; and (ii) applying controlled pressure in a range of 20-300 psi on the mold to effect a penetration into the surface of the organic polymer substrate, thereby to replicate the pattern of the mold to the surface of the substrate; and (d) separating the operational mold from the patterned substrate.

There are disclosed methods and devices for build temperature control. In some examples, a method comprises applying a temperature controllable top cover over a top of the build volume. The method may further comprise controlling the temperature controllable top cover to maintain a temperature substantially equal to a build temperature for a predetermined period of time. The method may further comprise applying a thermally conductive bottom cover to a bottom of the build volume.

There are disclosed methods and devices for build temperature control. In some examples, a method comprises applying a temperature controllable top cover over a top of the build volume. The method may further comprise controlling the temperature controllable top cover to maintain a temperature substantially equal to a build temperature for a predetermined period of time. The method may further comprise applying a thermally conductive bottom cover to a bottom of the build volume.

The present invention aims to provide a heat-shrinkable polyester film roll having decreased generation of wrinkles or longitudinal shrink mark. The present invention provides a film roll of a heat shrinkable polyester film, wherein a polyester of the polyester film contains recycled raw material from a PET bottle and an acid component of the polyester comprises isophthalic acid, and the film roll satisfies a specific average value of a shrinkage, specific isophthalic acid ratio, and specific thickness unevenness.

The present invention aims to provide a heat-shrinkable polyester film roll having decreased generation of wrinkles or longitudinal shrink mark. The present invention provides a film roll of a heat shrinkable polyester film, wherein a polyester of the polyester film contains recycled raw material from a PET bottle and an acid component of the polyester comprises isophthalic acid, and the film roll satisfies a specific average value of a shrinkage, specific isophthalic acid ratio, and specific thickness unevenness.

This invention relates to chemical polymer compositions, methods of synthesis, and fabrication methods for devices regarding polymers capable of displaying shape memory behavior (SMPs) and which can first be polymerized to a linear or branched polymeric structure, having thermoplastic properties, subsequently processed into a device through processes typical of polymer melts, solutions, and dispersions and then crossed linked to a shape memory thermoset polymer retaining the processed shape.

This invention relates to chemical polymer compositions, methods of synthesis, and fabrication methods for devices regarding polymers capable of displaying shape memory behavior (SMPs) and which can first be polymerized to a linear or branched polymeric structure, having thermoplastic properties, subsequently processed into a device through processes typical of polymer melts, solutions, and dispersions and then crossed linked to a shape memory thermoset polymer retaining the processed shape.

A method of manufacturing a modified liquid crystal polymer includes: providing a liquid crystal polymer having a first melting point; heating the liquid crystal polymer to a first temperature and maintaining at the first temperature for a first time period, in which the first temperature is lower than or equal to the first melting point; and cooling the liquid crystal polymer to a second temperature to form a first modified liquid crystal polymer, the second temperature being lower than the first temperature, the first modified liquid crystal polymer having a second melting point, in which the second melting point is higher than the first melting point.

A method of manufacturing a modified liquid crystal polymer includes: providing a liquid crystal polymer having a first melting point; heating the liquid crystal polymer to a first temperature and maintaining at the first temperature for a first time period, in which the first temperature is lower than or equal to the first melting point; and cooling the liquid crystal polymer to a second temperature to form a first modified liquid crystal polymer, the second temperature being lower than the first temperature, the first modified liquid crystal polymer having a second melting point, in which the second melting point is higher than the first melting point.

The invention relates to a method of manufacturing a sandwich panel comprises the steps of: a) providing a plate-shaped assembly of a first cover part and a second cover part and between these cover parts a core part of a thermoplastic material containing a physical blowing agent, b) heating the assembly resulting from step a) under pressure between press tools in a press to a foaming temperature below the glass transition temperature of the thermoplastic material in the core part, thereby effecting adhesion of the foamed core part to the first and second cover parts c) foaming the thermoplastic material in the core part under pressure and at the foaming temperature wherein the spacing between the press tools is increased; d) a cooling step of cooling the foamed sandwich panel resulting from step c), while the sandwich panel is maintained under pressure between the press tools; e) removing the thus cooled sandwich panel from the press; and f) drying the sandwich panel thus obtained; wherein the cooling step d) comprises.a first substep d1) of cooling the foamed assembly from the foaming temperature to an intermediate temperature in the range of 70-100° C. at a first cooling rate and a second substep d2) of cooling the foamed assembly from the intermediate temperature to ambient temperature at a second cooling rate, the second cooling rate is less than the first cooling rate.