A physically crosslinked, closed cell continuous multilayer foam structure comprising at least one polypropylene/polyethylene coextruded foam layer is obtained. The multilayer foam structure is obtained by coextruding a multilayer structure comprising at least one foam composition layer, irradiating the coextruded structure with ionizing radiation, and continuously foaming the irradiated structure.

The present invention provides methods, processes, and systems for the manufacture of three-dimensional articles made of polymers using 3D printing. A layer of prepolymer is deposited on a build plate to form a powder bed. The deposited powder bed is heated to about 50° C. to about 170° C. Then, a solution of activating agent is printed on the powder bed in a predetermined pattern, and a stimulus is applied converting the prepolymer to the final polymer. After a predetermined period of time, sequential layers are printed to provide the three-dimensional article. The three-dimensional object can be cured to produce the three-dimensional article composed of the final polymers.

Objects produced by conventional three-dimensional printing methods are often incompletely consolidated and are not easily repaired. Printing compositions to address this issue can include a solidifiable matrix and a microwave absorber dispersed in the solidifiable matrix. The microwave absorber can be a plurality of carbon nanostructures containing a plurality of carbon nanotubes that are branched, crosslinked, and share common walls with one another. Methods for processing a three-dimensional printed object can include: providing a three-dimensional printed object formed from a printing composition containing a solidifiable matrix and a microwave absorber dispersed in the solidifiable matrix, and applying a focused input of microwave radiation to the printed object at one or more locations. Applying the microwave radiation heats the microwave absorber at the one or more locations and promotes consolidation of the printing composition within the printed object.

Objects produced by conventional three-dimensional printing methods are often incompletely consolidated and are not easily repaired. Printing compositions to address this issue can include a solidifiable matrix and a microwave absorber dispersed in the solidifiable matrix. The microwave absorber can be a plurality of carbon nanostructures containing a plurality of carbon nanotubes that are branched, crosslinked, and share common walls with one another. Methods for processing a three-dimensional printed object can include: providing a three-dimensional printed object formed from a printing composition containing a solidifiable matrix and a microwave absorber dispersed in the solidifiable matrix, and applying a focused input of microwave radiation to the printed object at one or more locations. Applying the microwave radiation heats the microwave absorber at the one or more locations and promotes consolidation of the printing composition within the printed object.

A method of making a flexible magnetized sheet is provided. The method may comprise the steps of (1) using cold extrusion to produce a highly viscous fluid magnetizable sheet, (2) passing the sheet through a magnetic field to create an uncured magnetized sheet, and (3) curing the sheet with electron beam curing. The fluid mixture may comprise magnetizable particles with a random charge orientation and an acrylic resin. The components of the mixture are cool when passed through an extrusion die. The extruded fluid sheet allows for the sheet to be magnetized and then, instead of curing by cooling, cured by the bombardment of electrons via an electron beam (EB) generator. The method can eliminate the heat of extrusion and can allow for more freedom of orientation because the sheet does not cure until it reaches the electron beam curing station.

A method of making a flexible magnetized sheet is provided. The method may comprise the steps of (1) using cold extrusion to produce a highly viscous fluid magnetizable sheet, (2) passing the sheet through a magnetic field to create an uncured magnetized sheet, and (3) curing the sheet with electron beam curing. The fluid mixture may comprise magnetizable particles with a random charge orientation and an acrylic resin. The components of the mixture are cool when passed through an extrusion die. The extruded fluid sheet allows for the sheet to be magnetized and then, instead of curing by cooling, cured by the bombardment of electrons via an electron beam (EB) generator. The method can eliminate the heat of extrusion and can allow for more freedom of orientation because the sheet does not cure until it reaches the electron beam curing station.

This disclosure relates in general to three dimensional (“3D”) printers having a configuration that prepares a three-dimensional object by using a feedstock comprising a metal or a polymer compound and a carbon coating formed on a surface of the compound. This disclosure also relates to such feedstocks and their preparation methods. This disclosure further relates to 3D composite objects prepared by using such printers and feedstocks. This disclosure also relates to carbon containing photocurable formulations and methods for their preparation. This disclosure further relates to electrically conducting 3D polymer composites prepared by using such carbon containing photocurable formulations.

This disclosure relates in general to three dimensional (“3D”) printers having a configuration that prepares a three-dimensional object by using a feedstock comprising a metal or a polymer compound and a carbon coating formed on a surface of the compound. This disclosure also relates to such feedstocks and their preparation methods. This disclosure further relates to 3D composite objects prepared by using such printers and feedstocks. This disclosure also relates to carbon containing photocurable formulations and methods for their preparation. This disclosure further relates to electrically conducting 3D polymer composites prepared by using such carbon containing photocurable formulations.

An object of the present invention is to provide a process for producing a surface-modified molded article, whereby surface layer strength of a molded article can be enhanced, and a molded article containing an organic polymer compound with low adhesive property, such as a fluororesin, can be bonded to an adherend without the use of an adhesive, and whereby a treatment step or an apparatus in an atmospheric-pressure plasma treatment are not complicated, and to provide a process for producing a composite of the surface-modified molded article and an adherend. The present invention is a process for producing a surface-modified molded article wherein a surface of the molded article containing an organic polymer compound is subjected to an atmospheric pressure plasma treatment to introduce a peroxide radical with adjusting the surface temperature of the molded article to (melting point of the organic polymer compound −120° C. or higher.

An object of the present invention is to provide a process for producing a surface-modified molded article, whereby surface layer strength of a molded article can be enhanced, and a molded article containing an organic polymer compound with low adhesive property, such as a fluororesin, can be bonded to an adherend without the use of an adhesive, and whereby a treatment step or an apparatus in an atmospheric-pressure plasma treatment are not complicated, and to provide a process for producing a composite of the surface-modified molded article and an adherend. The present invention is a process for producing a surface-modified molded article wherein a surface of the molded article containing an organic polymer compound is subjected to an atmospheric pressure plasma treatment to introduce a peroxide radical with adjusting the surface temperature of the molded article to (melting point of the organic polymer compound −120° C. or higher.