The method of metal-thermoplastic resin direct bonding is characterized by comprising a first step for irradiating a surface of the metal material with a pulse laser under an oxidizing atmosphere to form a surface modification region, a second step for causing the thermoplastic resin material to abut against the surface modification region to form a bonding interface, and a third step for heating up the bonding interface by laser irradiation to achieve bonding, the first step including forming metal oxide particle clusters obtained when metal oxide particles having a particle diameter of 5-500 nm to be continuously bonded at the surface modification region, so that the maximum height (Sz) of a surface of the metal oxide particle clusters is 50 nm-3 .Math.m.

The method of metal-thermoplastic resin direct bonding is characterized by comprising a first step for irradiating a surface of the metal material with a pulse laser under an oxidizing atmosphere to form a surface modification region, a second step for causing the thermoplastic resin material to abut against the surface modification region to form a bonding interface, and a third step for heating up the bonding interface by laser irradiation to achieve bonding, the first step including forming metal oxide particle clusters obtained when metal oxide particles having a particle diameter of 5-500 nm to be continuously bonded at the surface modification region, so that the maximum height (Sz) of a surface of the metal oxide particle clusters is 50 nm-3 .Math.m.

The present invention aims to provide an ETFE film having excellent transparency and heat resistance and cost efficiency. The present invention relates to a film including a copolymer containing an ethylene unit, a tetrafluoroethylene unit, and a (fluoroalkyl)ethylene unit represented by Formula (1):
CH.sub.2═CX—Rf  (1)
wherein X represents H or F, and Rf represents a fluoroalkyl group having 2 or more carbon atoms, the copolymer containing the (fluoroalkyl)ethylene unit in an amount of 0.8 to 2.5 mol % relative to the amount of all the monomer units and containing the ethylene unit and the tetrafluoroethylene unit at a molar ratio of 30.0/70.0 to 50.0/50.0, the film having a crystallinity of 68% or less, the crystallinity being calculated on the basis of a diffraction intensity curve of the film resulting from X-ray diffraction measurement.

An embodiment relates to a sheet comprising an acrylic resin layer and a fluorinated polymer resin layer directly formed on one surface of the acrylic resin layer; a laminated steel plate comprising the sheet; and a manufacturing method therefor.

The invention pertains to a fluoroelastomer composition comprising:—at least one fluoroelastomer [perfluoroelastomer (A)], said fluoroelastomer (A) comprising iodine and/or bromine atoms and having a backbone comprising:—recurring units derived from tetrafluoroethylene (TFE);—recurring units derived from at least one perfluorinated monomer selected from the group consisting of:—perfluoroalkylvinylethers complying with formula CF.sub.2═CFOR.sub.f1 in which Rn is a C.sub.1-C.sub.6 perfluoroalkyl (monomers of this type being referred to, herein after, as PAVE), e.g. —CF.sub.3, —C.sub.2F.sub.5, —C.sub.3F.sub.7;—perfluoro-oxyalkylvinylethers complying with formula CF.sub.2=CFOX.sub.0, in which X.sub.0 can be (i) a C.sub.1-C.sub.12 perfluorooxyalkyl having one or more ether groups, e.g. —C.sub.2F.sub.5—O—CF.sub.3; or (ii) a group of formula —CF.sub.2OR.sub.f2 in which R.sub.f2 is a C.sub.1-C.sub.6 perfluoroalkyl, e.g. —CF.sub.3, —C.sub.2F.sub.5, —C.sub.3F.sub.7 (monomers of this type being referred to, herein after, as MOVE);—recurring units derived from vinylidene fluoride (VDF) in an amount of up to 30% by moles, with respect to the total moles of recurring units; and—optionally, recurring units derived from at least one perfluorinated C.sub.3-C.sub.8 alpha-olefin, in an amount of up to 5% moles;—optionally, recurring units derived from at least one fluorine-free alpha-olefin, in an amount of up to 10% moles;—from 0.5 to 5 weight parts, per 100 parts by weight of said fluoroelastomer (A), of at least one polyunsaturated compound;—from 0.1 to 3 weight parts, per 100 parts by weight of said fluoroelastomer (A), of at least one organic peroxide;—from 0.1 to 3 weight parts, per 100 parts by weight of said fluoroelastomer (A), of at least one organic base [base (B)] selected from the group consisting of: (i) non-aromatic primary amines or amides complying with general formula (B1m) or (B1d): R.sub.bm—[C(0)].sub.t-NH.sub.2 (B1m) H.sub.2N—[C(O)].sub.t′—R.sub.dm—[C(O)].sub.t″—NH.sub.2 (B1d) wherein:—each of t, t′ and t″, equal to or different from each other and at each occurrence is zero or 1;—R.sub.bm is a monovalent hydrocarbon non-aromatic group having 12 to 30 carbon atoms;—R.sub.bm is a divalent hydrocarbon non-aromatic group having 6 to 30 carbon atoms; and (ii) cycloaliphatic secondary or tertiary amines complying with general formula (B2m) or (B2d) wherein:—Cy represents a divalent aliphatic group comprising at least 4 carbon atoms, optionally comprising one or more than one ethylenically unsaturated double bond, and optionally comprising one or more catenary nitrogen atoms, forming a cycle

A cable passage for sealing and for electrically contacting an exhaust-gas sensor includes: a protective sleeve; and at least one connecting cable which is run out of the protective sleeve on at least one front side of the protective sleeve. At least one cross section of the space existing between the protective sleeve and the at least one connecting cable is filled with a thermoplastically workable fluoropolymer-containing material.

A laminate of the present invention includes a first member which contains a thermoplastic polymer and through which laser light is transmitted and a second member which contains a thermoplastic polymer and absorbs laser light, wherein the first member is directly bonded to the second member, and A represented by the formula 1: A=−9×D+Wa−45 is more than zero. D represents a distance between a Hansen solubility parameter of the thermoplastic polymer of the first member and a Hansen solubility parameter of the thermoplastic polymer of the second member, and Wa represents work of adhesion calculated from each surface free energy of the first member and the second member. Such a first member and a second member are firmly bonded to each other without using a bonding sheet.

A laminate of the present invention includes a first member which contains a thermoplastic polymer and through which laser light is transmitted and a second member which contains a thermoplastic polymer and absorbs laser light, wherein the first member is directly bonded to the second member, and A represented by the formula 1: A=−9×D+Wa−45 is more than zero. D represents a distance between a Hansen solubility parameter of the thermoplastic polymer of the first member and a Hansen solubility parameter of the thermoplastic polymer of the second member, and Wa represents work of adhesion calculated from each surface free energy of the first member and the second member. Such a first member and a second member are firmly bonded to each other without using a bonding sheet.

A method of manufacturing a heat exchanger array that includes stacking a plurality of heat exchanger units in an aligned configuration with respective first ports of the plurality of heat exchanger units aligned. The method can further include generating heat in the first coupling elements at the same time and at a temperature sufficient to generate a first plurality of respective couplings between adjacent sheets of adjacent heat exchanger units about adjacent first ports and without a coupling being generated between the first and second sheets of a given heat exchanger unit.

A method of manufacturing a heat exchanger array that includes stacking a plurality of heat exchanger units in an aligned configuration with respective first ports of the plurality of heat exchanger units aligned. The method can further include generating heat in the first coupling elements at the same time and at a temperature sufficient to generate a first plurality of respective couplings between adjacent sheets of adjacent heat exchanger units about adjacent first ports and without a coupling being generated between the first and second sheets of a given heat exchanger unit.