The present invention provides a resin composition for stereolithography that is easily shapable with good shape precision while reducing sedimentation of inorganic particles during storage, and a obtained three-dimensional shaped article thereby excels in mechanical characteristics such as flexural strength and flexural modulus, in addition to having a desirable shade and good shade stability. The present invention relates to a resin composition for stereolithography comprising a polymerizable monomer (a), a photopolymerization initiator (b), an inorganic particle (c) having an average particle diameter of 5 to 500 nm, and a hindered phenolic compound (d), wherein the content of the photopolymerization initiator (b) is 0.1 to 10 parts by mass relative to 100 parts by mass of the polymerizable monomer (a), the content of the inorganic particle (c) is 50 to 400 parts by mass relative to 100 parts by mass of the polymerizable monomer (a), and the content of the hindered phenolic compound (d) is 0.1 to 500 parts by mass relative to 100 parts by mass of the photopolymerization initiator (b).

This invention provides resin formulations which may be used for 3D printing and pyrolyzing to produce a ceramic matrix composite. The resin formulations contain a solid-phase filler, to provide high thermal stability and mechanical strength (e.g., fracture toughness) in the final ceramic material. The invention provides direct, free-form 3D printing of a preceramic polymer loaded with a solid-phase filler, followed by converting the preceramic polymer to a 3D-printed ceramic matrix composite with potentially complex 3D shapes or in the form of large parts. Other variations provide active solid-phase functional additives as solid-phase fillers, to perform or enhance at least one chemical, physical, mechanical, or electrical function within the ceramic structure as it is being formed as well as in the final structure. Solid-phase functional additives actively improve the final ceramic structure through one or more changes actively induced by the additives during pyrolysis or other thermal treatment.

A polyimide precursor solution includes a polyimide precursor having a glass transition temperature Tg of equal to or higher than 300° C. after imidization, an aqueous solvent containing water, an organic amine compound, and resin particles having a volume average particle size of equal to or less than 100 nm.

A curable composition contains a polymerizable compound (A), a hydrogen abstracting polymerization initiator (B) represented by the following Chemical Formula 1, a photodegradable polymerization initiator (C), and a hydrogen donor (D), wherein the proportion of the hydrogen abstracting polymerization initiator (B) to the entire of the curable composition is from 0.1 to 10 percent by mass and the proportion of the hydrogen donor (D) to the entire of the hydrogen abstracting polymerization initiator (B) is from 30 to 100 percent by mass,

##STR00001## where A represents a phenylene group, a naphthylene group, or a biphenylene group, R.sup.1 and R.sup.2 each, independently represent linear or branched alkyl groups having 1 to 10 carbon atoms, R.sup.3 represents a linear or branched alkyl group having 1 to 10 carbon atoms or a linear or branched alkoxy group having 2 to 9 carbon atoms.

A composition comprises a cyanoacrylate polymer and a protected amine. A method comprises: providing a shaped model comprising a cyanoacrylate polymer; preparing an investment having a cavity that corresponds to the shaped model; and heating the shaped model to sufficient temperature that the cyanoacrylate polymer depolymerizes and volatilizes. A hardenable material may be cast in the investment to provide a replica of the shaped model. A curable composition comprises: a cyanoacrylate monomer; a free-radical photoinitiator; and a protected amine, wherein the curable composition is free of compounds that initiate anionic polymerization of the cyanoacrylate monomer at ambient temperature. A method of curing the curable composition is also disclosed.

Various embodiments provide a method of additively manufacturing a part including depositing a layer of a powder on a working surface, depositing a binder solution on the layer of the powder at first locations, and depositing a sintering aid solution on the layer of the powder at second locations. The sintering aid solution comprises a sintering aid in a solvent. In various embodiments, the sintering aid enables an increased brown strength as compared to parts containing unbound powder. The method enables binders that provide high green strength to be used at the edges of the part, while also balancing a shortened debind time with an increased brown strength. Embodiments in which binder solution is deposited according to a predetermined pattern at second locations are also described.

This invention relates to a high molecular weight nylon powder composition for 3D printing, its preparation method and use. The composition comprises: 100 parts by weight of high-viscosity nylon powder, 1-5 parts by weight of a flow agent, and 0.1-1 parts by weight of an antioxidant; the high-viscosity nylon powder is one or more selected from nylon 6, nylon 66, nylon 11, nylon 12, nylon 612 and nylon 610; or the powder composition is obtained via polymerization reaction of the raw materials comprising the following components, based on the weight parts of lactam monomers or amide monomers: 100 parts by weight of lactam monomers or amide monomers, 0.005-1 parts by weight of a catalyst, and 0.1-1 parts by weight of an antioxidant. The high molecular weight nylon powder composition prepared in the present invention has a particle diameter in the range of 20-100 micrometers, good powder spreading performance, and is suitable for the 3D printing process, and the product of the high molecular weight nylon powder composition has good mechanical properties, good dimensional stability and low manufacturing cost.

A functional polymeric cutting edge structure and methods for manufacturing cutting edge structures using polymeric materials are provided. A razor blade for use in a razor cartridge or a blade box for assembly in a razor cartridge frame may be formed using the present invention.

A printable composition for the manufacture of cell-receiving scaffolds comprising about 0.3 wt % to about 3.0 wt % of one or more collagens; about 5.0 wt % to about 40.0 wt % of one or more monomers; about 0.5 wt % to about 2.0 wt % of a photo initiator; and 0 wt % to about 75 wt % of a vehicle comprising a protic solvent, by weight of the printable composition; wherein the printable composition has a resolution of about 100 microns or less when printed, a photo speed (Dp/Ec) of about 0.1-5 mm (Dp) and about 10-100 mJ/cm.sup.2 (Ec) when printed, and a green strength of at least about 5 kPa after drying. The present technology further includes methods of manufacturing a three-dimensional cell-receiving scaffold using the printable composition.

Methods for additive manufacturing are provided. In embodiments, such a method comprises illuminating a photothermal base with light, the photothermal base comprising a photothermal material and mounted in an additive manufacturing system to form a first interface between a surface of the photothermal base and a curable composition comprising thermally curable components, wherein the light induces light-to-energy conversion in the photothermal base to generate heat at the first interface, thereby inducing curing of the thermally curable components to form a first cured region. Additive manufacturing systems and photothermal bases are also provided.