The present disclosure is directed to actinic radiation curable polymeric mixtures, cured polymeric mixtures, tires and tire components made from the foregoing, and related processes.

A lens comprises an internal cavity structure formed by dissolution of a soluble insert material. The internal soluble material may dissolve through a body of a lens such as a contact lens in order to form the cavity within the contact lens. The cavity within the lens can be shaped in many ways, and corresponds to the shape of the dissolved material, such that many internal cavity shapes can be readily fabricated within the contact lens. The insert can be placed in a mold with a pre-polymer material, and the pre-polymer material cured with the insert placed in the mold to form the lens body. The polymerized polymer may comprise a low expansion polymer in order to inhibit expansion of the lens when hydrated. The polymer may comprise a hydrogel when hydrated. The soft contact lens material comprises a sufficient amount of cross-linking to provide structure to the lens and shape the cavity.

Provided herein according to some embodiments is a method of forming a three-dimensional intermediate object with a polymerizable liquid, said polymerizable liquid comprising a mixture of (i) a microwave absorbing material, (ii) a light polymerizable liquid first component, and (iii) a second solidifiable component that is different from said first component. Optionally, but in some embodiments preferably, the method includes supporting the three-dimensional intermediate with a separate support media prior to solidifying and/or curing the second solidifiable component in the three-dimensional intermediate to form the three-dimensional object; and then optionally separating said support media when present from said three-dimensional object.

The disclosure provides a method for preparing a structured hydrogel and a method for preparing a hydrogel heart valve. In the disclosure, the method includes: providing a photocurable hydrogel ink; establishing a three-dimensional digital model, and conducting photocuring 3D printing on the photocurable hydrogel ink to obtain a printed hydrogel; and immersing the printed hydrogel in water to obtain the structured functional hydrogel, wherein the photocurable hydrogel ink comprises: a high-density hydrogen-bonded unsaturated monomer, a photoinitiator, a dye, and a solvent; and the solvent comprises water and dimethyl sulfoxide.

A method of printing a cellular solid (120) by direct bubble writing comprises introducing an ink formulation (102) comprising a polymerizable monomer and a gas (104) into a nozzle (106), which includes a core flow channel (108) radially surrounded by an outer flow channel (110). The ink formulation is directed into the outer flow channel (110) and the gas is directed into the core flow channel (108). The ink formulation (102) and the gas (104) are ejected out of the nozzle (106) as a stream of bubbles (112), where each bubble includes a core (114) comprising the gas and a liquid shell (116) overlying the core that comprises the ink formulation. After ejection, the polymerizable monomer is polymerized to form a solid polymeric shell (118) from the liquid shell (116), and the bubbles are deposited on a substrate (122) moving relative to the nozzle (106). Thus, a polymeric cellular solid (120) having a predetermined geometry is printed.

An upper for a sports shoe may include a component such as a vamp or a rear portion. The shoe component may include a UV curable microlattice structure with a plurality of regions such that each region has a different density. In some cases, the microlattice structure may include a high density microlattice structure, a mid-level density microlattice structure, and a non-structural region with a low density microlattice structure.

An ophthalmic lens operable to protect the eye from harmful ultraviolet and high energy visible wavelengths of light and methods for producing the same.

A molding system for applying moldable material to a pipe. An elongate mold has at least one elongate mold member movable relative another elongate mold member between open and closed positions. The mold includes a pipe support that extends generally radially into a mold cavity along a support axis. An inner end of the support is configured to support the pipe in a molding position in which an annular portion of the mold cavity extends circumferentially around the pipe. After moldable material in the annular portion of the mold cavity can support the pipe, the support is withdrawn from the mold cavity by moving outwardly along the support axis. An injector selectively dispenses additional moldable material into a space formed by the support in the existing moldable material.

Liquid radiation curable compositions are disclosed which are suitable for hybrid (i.e. cationic and free-radical) polymerization when processed via additive fabrication equipment utilizing sources of actinic radiation with peak spectral intensities in the UV/vis region. Also disclosed are methods of creating three-dimensional parts via additive fabrication processes utilizing sources of actinic radiation with peak spectral intensities in the UV/vis region employing liquid radiation curable compositions suitable for hybrid polymerization, and the parts cured therefrom.

The invention relates to a device (1) for supplying at least one molding device (2) with a polymerizable mixture of at least two reactants.

According to the invention, said supply device comprises: a buffer tank (10) suitable for receiving said polymerizable mixture via an inlet (101) of said buffer tank, a supply circuit (11), looped with said buffer tank, to convey the polymerizable mixture to an inlet (110) of said at least one molding device and including, beyond said inlet of the molding device, a return pipe (115) connected to the inlet of the buffer tank for sending a portion of the polymerizable mixture from said return pipe, and a filling pipe (42) of said buffer tank, connected to said inlet of said buffer tank, separate from the return pipe, wherein said buffer tank is also suitable for receiving said polymerizable mixture or at least one of said reactants from said filling pipe.