The present invention relates to multi-layered composite structures and to methods for the preparation thereof. The present multi-layered composite structures are light weight and capable of high load bearing making the present multi-layered composite structures especially suitable to be used as load bearing structures in, for example, automotive. Specifically, the present invention relates to methods comprising the steps of a) providing a mould for said multi-layered composite structure; b) layering said mould with two or more layers forming the outer surface of said multi-layered composite; c) filling said layered mould with a mixture comprised of non-expanded heat-expandable microspheres and closing said mould; and d) subjecting said closed mould to a temperature of 80 C. to 140 C. during 1 to 230 minutes thereby providing a relative pressure in said closed mould of 0.1 to 20 bar through expansion of said heat-expandable microspheres thereby forming a multi-layered composite structure in said mould with a foam enforced inner core and a multi-layered outer surface; and e) separating the multi-layered composite structure from said mould.

A device (e.g., an article of athletic gear) comprising a post-molded expandable component, which is a part of the device that is configured to be expanded or has been expanded after being molded. This may allow the post-molded expandable component to have enhanced characteristics (e.g., be more shock-absorbent, lighter, etc.), to be cost-effectively manufactured (e.g., by using less material and/or making it in various sizes), and/or to be customized for a user (e.g., by custom-fitting it to the user).

An insulating structure for an appliance includes an outer layer and an inner layer, wherein an insulating cavity is defined therebetween. A plurality of hollow nano-spheres are disposed within the insulating cavity, wherein each of the hollow nano-spheres includes a diameter in the range of from approximately 50 nanometers to approximately 1000 nanometers and has a wall that defines the internal space, and wherein the wall of each hollow nano-sphere has a thickness that is in a range of from approximately 0.5 nanometers to approximately 100 nanometers. A fill material is disposed in the insulating cavity and wherein the fill material is disposed in the space defined between the plurality of hollow nano-spheres, and wherein the fill material includes at least one of powdered silica, granulated silica, other silica material, aerogel and insulating gas.

A system for forming a structure on a print medium 1 includes: a print unit (print device) 10 for printing an electromagnetic wave-heat conversion layer for converting electromagnetic waves into heat, on a medium including an expansion layer that expands by heating; an expansion unit (expansion device) 20 aligned laterally with the print unit 10, for expanding the expansion layer by irradiating the medium with electromagnetic waves; and a top plate 30 covering the print unit 10 and the expansion unit 20 from above.

Polystyrene-phenolic foam composites and processes for their preparation are provided. The composites have very low density yet retain advantageous mechanical properties. The composites have excellent fire resistance properties and find application in the production of insulation panels.

Feedstocks for additive manufacturing are provided. The feedstock may include a matrix material, and one or more capsules disposed in the matrix material, wherein the one or more capsules are configured to be removable from a surface portion when the matrix material is solidified to form one or more cavities in the surface portion. Methods of depositing the feedstocks and objects formed from the feedstocks are also provided.

An insulating structure for an appliance includes an outer layer and an inner layer, wherein an insulating cavity is defined therebetween. A plurality of hollow nano-spheres are disposed within the insulating cavity, wherein each of the hollow nano-spheres includes a diameter in the range of from approximately 50 nanometers to approximately 1000 nanometers and has a wall that defines the internal space, and wherein the wall of each hollow nano-sphere has a thickness that is in a range of from approximately 0.5 nanometers to approximately 100 nanometers. A fill material is disposed in the insulating cavity and wherein the fill material is disposed in the space defined between the plurality of hollow nano-spheres, and wherein the fill material includes at least one of powdered silica, granulated silica, other silica material, aerogel and insulating gas.

An expansion device, including: an installation unit in which a thermally expandable sheet is disposed; an irradiation unit configured to irradiate the thermally expandable sheet placed on the installation unit with light; and a control unit configured to perform processes described below, wherein after an expansion process to expand the thermally expandable sheet by irradiating the thermally expandable sheet placed on the installation unit with light by the irradiation unit, a cooling process to cool the thermally expandable sheet by a predetermined cooling unit while maintaining the state in which the thermally expandable sheet is placed on the installation unit.

An expansion device, including: an irradiation unit configured to irradiate the thermally expandable sheet placed on a placing unit with light; a conveyance unit configured to reciprocably convey the irradiation unit between a first position and a second position; an exhaust fan fixed to a housing and configured to discharge air from the housing; and an air supply fan which is movable with the irradiation unit and configured to supply outside air into the housing, wherein the exhaust fan is provided at a position where air can be discharged from the second position side when the irradiation unit is returned from the first position to the second position after being moved from the second position toward the first position.

A production method of a modeled object includes a fixing step of fixing a thermally expandable sheet onto a tray by entirely or partially fixing a periphery of the thermally expandable sheet placed on the tray by a fixing member; a thermally expanding step of thermally expanding partially the thermally expandable sheet, which is in a state of being fixed onto the tray by the fixing step, by being heated by irradiating the thermally expandable sheet with light by an irradiation unit, while moving the irradiation unit from a first position toward a second position unit; and cooling the thermally expandable sheet, which has been thermally expanded partially by the thermally expanding step, while maintaining the state in which the thermally expandable sheet is fixed onto the tray, while returning the irradiation unit from the second position to the first position.