A cannula assembly having a retention member and a method of manufacture of the cannula assembly is provided. The cannula assembly includes a cannula and a sleeve disposed around the cannula from a proximal end to a distal end. The sleeve can be pre-formed by a stretch blow molding process then advanced over the cannula. The sleeve includes an inflatable balloon and an annular ring distal the inflatable balloon. The cannula includes an annular recess. The annular ring is sized to have an interference fit with the annular recess.

The invention provides a heat-shrinkable polyester-based film comprising ethylene terephthalate units, constituent units derived from at least one monomer which forms an amorphous component, and constituent units derived from butanediol. The amount of the constituent units derived from at least one monomer which forms an amorphous component is 18 mol % or more, and the amount of the constituent units derived from butanediol is 1 to 25 mol % based on 100 mol % of all polyester resin components. The heat-shrinkable polyester-based film is characterized by particular values for the secondary shrinkage ratio of the film, the hot-water heat shrinkage ratio of the film, and the reversing heat capacity difference before and after the glass transition temperature of the film.

A non-crosslinked polymeric heat shrink tubing including poly(ether-block-amide) (PEBA) and methods for making such non-crosslinked polymeric heat shrink tubing is provided. The non-crosslinked PEBA heat shrink tubing disclosed herein finds application, e.g., as a processing aid and final component in the manufacture of catheters and other medical devices.

A cannula assembly having a retention member and a method of manufacture of the cannula assembly is provided. The cannula assembly includes a cannula and a sleeve disposed around the cannula from a proximal end to a distal end. The sleeve can be pre-formed by a stretch blow molding process then advanced over the cannula. The sleeve includes an inflatable balloon and an annular ring distal the inflatable balloon. The cannula includes an annular recess. The annular ring is sized to have an interference fit with the annular recess.

Curved heat shrink tubing and methods of making the same are described herein. An example method includes inserting heat shrink tubing into a tube, curving the tube, and deforming the heat shrink tubing, inside of the tube, to have a curved shape along a length of the heat shrink tubing where a first length of the heat shrink tubing along an outer radius of the curved shape is longer than a second length of the heat shrink tubing along an inner radius of the curved shape.

The present disclosure provides for a heat-shrinkable, biaxially stretched, multilayer thermoplastic film that includes at least a puncture resistant layer. The puncture resistant layer is formed with a polyethylene based plastomer having a density of 0.890 g/cm.sup.3 to 0.910 g/cm.sup.3 as measured in accordance with ASTM D-792, and a melt index (MI) as measured by ASTM D-1238 at 190? C./2.16 kg from 0.20 g/10 minutes to 1.5 g/10 minutes. The polyethylene based plastomer has a logM.sub.25% of an upper 25% of a GPC quadrant having a value of 5.1 to 5.7, an intermediate molecular weight distribution (Mw/Mn) of 2.5 to 3, a Mz/Mw value of 2 to 2.5, a Comonomer Distribution Constant value from 60 to 400 and a single SCBD peak between 40-85? C. with a mass fraction of less than 3% above 85? C. as determined by CEF, and a ZSVR value from 1.0 to 5.5. The multilayer thermoplastic film is biaxially stretched at a temperature of 60? C. to 120? C. with a blow-up ratio from 2:1 to 10:1.

A heat-shrinkable polyester-based film is provided, which is heat-shrinkable in the longitudinal direction and which is freed from various problems, particularly curling-up or peeling in a bonded area. The heat-shrinkable polyester-based film is characterized by an A1/A2 (absorbance) ratio in the longitudinal direction, which is the main shrinking direction of the film, of 0.55 to 1, with an A1/A2 ratio in the width direction perpendicular to the main shrinking direction of 0.5 to 0.9, wherein A1 is the absorbance of the film at 1340 cm.sup.1 and A2 is the absorbance of the film at 1410 cm.sup.1 as determined by polarized ATR-FTIR spectroscopy, and a hot-water shrinkage of 35 to 60% in the longitudinal direction of the film and 3 to 12% in the width direction of the film, wherein the hot-water shrinkage is determined by dipping the film in hot water at 90 C. for 10 seconds.

This ball joint is provided with: a ball stud, one end being fastened to a suspension device/stabilizer, and the other end having a ball part; a housing that rotatably supports the ball part of the ball stud; and a ball seat provided so as to be interposed between the housing and the ball part, the ball seat having an inner spherical part for accommodating the ball part. The ball seat is provided to the housing by insert injection molding. The inside diameter dimension of the inner spherical part formed by separate injection molding is set to a dimension corresponding to the anticipated amount of molding shrinkage of the resin during the insert injection molding.

Multi-layered blocked shrink bundling films include at least one layer that contains a blocking polymer. Materials and methods for forming multi-layered blocked shrink bundling films via a blown film extrusion process are described.

The invention provides a heat-shrinkable polyester film which has a high heat shrinkage rate in the width direction, exhibits a low heat shrinkage rate in the longitudinal direction, and has a great mechanical strength in the longitudinal direction, good openability along perforations, and excellent shrink finish. The film has a hot-water heat shrinkage rate of 40% to 85% in the main shrinking direction and 5% to 15% in the perpendicular direction when the film is immersed in hot water at 98 C. for 10 seconds, and a maximum shrinkage stress of 2-7 MPa in the main shrinking direction when measured in hot air of 90 C. and the shrinkage stress 30 seconds after measurement of the shrinkage stress has started is of 60-100% of the maximum shrinkage stress. The film contains 6 mol % or more of diethylene glycol-derived constituent units with respect to 100 mol % of all polyester resin components.