A method of printing a 3D printing a photopolymer composite material includes providing a resin premix material including an acrylate monomer or an acrylate oligomer, an inorganic hydrate, a reinforcing filler, a co-initiator, and an ultraviolet (UV) initiator. A thermal initiator is mixed with the resin premix to form a photopolymer composite resin. The photopolymer composite resin is repeatedly extruded and dual-cured by a 3D printing system to create a photopolymer composite material. The 3D printing system includes a control system, a mixing system, a feeding system in fluid communication with the mixing system, a light curing module controlled by the control system, and a printing head controlled by the control system.

Disclosed is a curable composition for the manufacture, by stereolithography, of a green part made of a ceramic or metallic material, the curable composition including at least one ceramic and/or metallic powder; at least one polymerizable monomer and/or oligomer; at least one initiator for the polymerization of the polymerizable monomer(s) and/or oligomer(s). The initiator(s) are selected from iodonium, sulphonium and diazonium salts and onium salts in combination with at least one amine and/or at least one phosphine to form a charge transfer complex. The initiator(s) may generate the initiation of a thermal polymerization under the exposure to at least one source of UV, visible or IR irradiation.

An object of the present invention is to provide a technique capable of reducing the hydrolysis of a biodegradable resin at the time of molding with respect to a biodegradable resin-containing resin composition having a high water content. Provided is a resin composition comprising: a biodegradable resin and heavy calcium carbonate particles in a mass ratio of 50:50 to 10:90, in which 0.5% by mass or more and 3.5% by mass or less of calcium oxide is comprised relative to the resin composition, and 0.2% by mass or more of water is comprised relative to the resin composition.

A biaxially stretched polyester film and a method for producing the same are provided. The biaxially stretched polyester film includes a polyester resin base layer and a matte layer. The polyester resin base layer includes: (1) 50 to 95 wt % of a polyester resin base material, and an intrinsic viscosity of the polyester resin base material being between 0.5 and 0.8 dL/g; and (2) 0.01 to 5 wt % of a high viscosity polyester resin material, and an intrinsic viscosity of the high viscosity polyester resin material being between 0.9 and 1.1 dL/g. The matte layer includes: (1) 50 to 95 wt % of a polyester resin matrix material, and an intrinsic viscosity of the polyester resin matrix material being between 0.5 and 0.8 dL/g; and (2) 0.3 to 40 wt % of a plurality of filler particles, and the filler particles having an average particle size of between 0.15 μm and 10 μm.

A preform for a container comprises a polymer composition which includes tungsten oxide particles, for example WO.sub.2.72 or WO.sub.2.92.

A 3D printing method for an impact-resistant gradient complex part containing a hollow ceramic sphere complex, wherein the method includes the following steps: 1) designing the size and shape of the part as well as an internal layered structure; 2) providing a raw material, wherein the raw material contains a high polymer, a curing agent and hollow ceramic spheres; and 3) providing the raw material with a certain thickness according to a design, then, curing the raw material by using a heat source to form a high polymer layer containing the hollow ceramic spheres, and repeatedly printing the high polymer layer according to the design until the high polymer layer reaches the designed thickness to form the impact-resistant gradient complex part.

A tableted epoxy resin composition for encapsulation of semiconductor devices and a semiconductor device encapsulated using the tableted epoxy resin composition, the tableted epoxy resin composition satisfying the following conditions (i) a proportion of tablets of the tableted epoxy resin composition having a diameter of greater than or equal to 0.1 mm and less than 2.8 mm and a height of greater than or equal to 0.1 mm and less than 2.8 mm is about 97 wt % or more, as measured by sieve analysis using ASTM standard sieves; (ii) the tablets have a packed density of greater than about 1.7 g/mL; and (iii) a ratio of packed density to cured density of the tablets is about 0.6 to about 0.87.

Disclosed herein are compositions for three-dimensional printing. In an example, disclosed herein is a composition for three-dimensional printing comprising: (A) a powder build material; (B) a first fusing agent; (C) a second fusing agent different from the first fusing agent; (D) a detailing agent; (E) a cyan ink composition; (F) a yellow ink composition; (G) a magenta ink composition; and (H) a black ink composition.

A method of fabricating a fiber preform filled with refractory ceramic particles, includes placing a fiber texture including refractory ceramic fibers in a mold cavity; injecting a slip including a powder of refractory ceramic particles present in a liquid medium, the slip being injected into the pores of the fiber texture present in the mold cavity, injection being performed through at least a first face or a first edge of the fiber texture; and draining the liquid medium of the slip that has penetrated into the fiber texture through the porous material part, the draining being performed at least through a second face or a second edge of the fiber texture different from the first face or the first edge, the porous material part also serving to retain the refractory particle powder in the pores of the fiber texture to obtain a fiber preform filled with refractory particles.

A method for preparing a sacrificial support material for use in printing a three-dimensional (3D) article includes providing a water-soluble thermoplastic polymer composite including a water-soluble thermoplastic polyethylene oxide graft polymer having a polyethylene oxide polymer backbone, and from about 0.05% to about 10% by weight of the polyethylene oxide polymer backbone of at least one polar vinyl monomer grafted to the polyethylene oxide polymer backbone. One or more nanoscopic particulate processing aids may be uniformly dispersed in the graft polymer in an amount of from about 0.05% to about 10% by weight of the water-soluble thermoplastic polymer composite. The water-soluble thermoplastic polymer composite may have a viscosity in the range of about 100 to about 10,000 Pa-sec. The method may also include forming the water-soluble thermoplastic polymer composite into the 3D printable sacrificial support material.