Creping adhesives and processes for making and using same. In some embodiments, the creping adhesive can include a solvent, a modified polyvinyl alcohol, and a crosslinked resin. The crosslinked resin can include polyamidoamine backbones crosslinked by primary crosslinking moieties and propanediyl moieties, where the primary crosslinking moieties can be derived from a functionally symmetric crosslinker. In other embodiments, the crosslinked resin can include polyamidoamine backbones crosslinked by primary crosslinking moieties and secondary crosslinking moieties, where the primary crosslinking moieties can be derived from a first functionally symmetric crosslinker and the secondary crosslinking moieties can be derived from a second functionally symmetric crosslinker. In other embodiments, the crosslinked resin can include polyamidoamine backbones crosslinked by primary crosslinking moieties, where the primary crosslinking moieties can be derived from a functionally symmetric crosslinker. The modified polyvinyl alcohol can include a carboxylated, a sulfonated, a sulfated, and/or a sulfonated-carboxylated polyvinyl alcohol.

Creping adhesives and processes for making and using same. In some embodiments, the creping adhesive can include a solvent, a modified polyvinyl alcohol, and a crosslinked resin. The crosslinked resin can include polyamidoamine backbones crosslinked by primary crosslinking moieties and propanediyl moieties, where the primary crosslinking moieties can be derived from a functionally symmetric crosslinker. In other embodiments, the crosslinked resin can include polyamidoamine backbones crosslinked by primary crosslinking moieties and secondary crosslinking moieties, where the primary crosslinking moieties can be derived from a first functionally symmetric crosslinker and the secondary crosslinking moieties can be derived from a second functionally symmetric crosslinker. In other embodiments, the crosslinked resin can include polyamidoamine backbones crosslinked by primary crosslinking moieties, where the primary crosslinking moieties can be derived from a functionally symmetric crosslinker. The modified polyvinyl alcohol can include a carboxylated, a sulfonated, a sulfated, and/or a sulfonated-carboxylated polyvinyl alcohol.

A grafted polyvinyl alcohol polymer includes a polyvinyl alcohol main chain and a plurality of side chains grafted to the polyvinyl alcohol main chain. One or more of the side chains from the plurality of side chains include one or more units selected from: an aliphatic carboxylic acid, an aliphatic amide, an amino alkyl (meth)acrylate, a hydroxylated alkyl (meth)acrylate, or any combinations thereof. The grafted polyvinyl alcohol polymer can be included in a formulation that also includes water, and the formulation can be used as an adhesive in a creping process.

A belt for creping a web in a papermaking process. The belt includes a surface onto which the web is transferred during the papermaking process. A plurality of openings extend through the surface, with the openings being arranged in lines that are offset from lines in the machine direction (MD) and cross-machine direction (CD) of the belt. Paper products, such as absorbent sheets, made from the belt have hollow dome regions and connecting regions between the domes, with the domes being arranged in lines that are offset from lines in the MD and CD of the paper products.

A modified creping adhesive formulation is described that includes at least one creping adhesive, and modifier, wherein the modifier is or includes an emulsion of polypropylene glycol, at least one quaternary ammonium compound, and at least one non-ionic surfactant. The present invention is directed to the modifier itself as well. Methods of creping using the formulation are also described.

A modified creping adhesive formulation is described that includes at least one creping adhesive, and modifier, wherein the modifier is or includes an emulsion of polypropylene glycol, at least one quaternary ammonium compound, and at least one non-ionic surfactant. The present invention is directed to the modifier itself as well. Methods of creping using the formulation are also described.

Toilet paper includes at least two sheets on which embossments are formed and that are joined together in a nested manner. The area of a top part of an embossed protrusion of each of the embossments is between 0.8 mm.sup.2 and 1.5 mm.sup.2, and the area percentage of top parts of embossed protrusions of the embossments is between 5% and 10%.

A process having the steps of producing the web material with the papermaking machine; measuring a molar amount of a monovalent inorganic ionizable cation species (MIICS) in the web material; measuring a molar amount of a divalent inorganic ionizable cation species (DIICS) in the web material; calculating a molar ratio of the measured molar amount of the MIICS to the measured molar amount of the DIICS in the web material; determining if the molar ratio of MIICS to DIICS is about less than or equal to 10; and, if the molar ratio of MIICS to DIICS is greater than about 10, adding an amount of DIICS to the papermaking machine to adjust the molar ratio of MIICS to DIICS so the web material adhering to the Yankee drum drying system has a molar ratio of MIICS to DIICS of about less than or equal to 10, is disclosed.

A process for manufacturing a web material is disclosed. The process generally comprises the steps of providing a papermaking machine with a monovalent inorganic ionizable cation species (MIICS) and a divalent inorganic ionizable cation species (DIICS) measuring devices, measuring molar concentrations of MIICS and DIICS in the web material with the MIICS and DIICS measuring devices and calculating a molar ratio of the measured molar concentration of the MIICS to the measured molar concentration of the DIICS, and subsequently determining if the calculated molar ratio is about less than or equal to 10. If the molar ratio is greater than 10, adding an amount of DIICS to the papermaking machine and manufacturing the web material with the papermaking machine with the added amount of DIICS.

The present invention relates to a release aid that includes at least one succinic anhydride derivative for use in a papermaking process. For example, the release aid of the present invention is particularly useful for use in a paperweb creping process. The present invention also relates to a paperweb creping method that includes a release aid comprising at least one succinic anhydride.