A thermoplastic elastomer composition including an acrylic block copolymer (I) and a hydrogenated block copolymer (II). The content of the acrylic block copolymer (I) is 70 to 300 parts by mass with respect to 100 parts by mass of the hydrogenated block copolymer (II); the hydrogenated block copolymer (II) is a hydrogenated product of a block copolymer (P) including a polymer block (A1) containing structural units derived from an aromatic vinyl compound, and a polymer block (B1) containing 1 to 100 mass % of structural units (b1) derived from farnesene and 99 to 0 mass % of structural units (b2) derived from a conjugated diene other than farnesene, the mass ratio [(A1)/(B1)] of the polymer block (A1) to the polymer block (B1) being 1/99 to 70/30; and the hydrogenation ratio of carbon-carbon double bonds in the polymer block (B1) is 50 to 100 mol %.

A thermo-adhesive multilayer film based on thermoplastic polyurethane includes a barrier layer having a material with anti-dye migration properties selected from: ethylene vinyl alcohol copolymer, polyvinyl alcohol, polyvinyl acetate, polyamides, cellulose derivatives, polyvinylidene chloride and combinations. The barrier layer is interposed between two layers, each having a mixture of a thermoplastic polyurethane with a compatibilizing agent selected from: co-polymers modified with maleic anhydride, co-polymers modified with epoxy groups, co-polymers containing hydroxyl groups and combinations thereof. A decorative multilayer film includes the thermo-adhesive multilayer film and a further decorative layer, which provides an aesthetic effect. A process of co-extruding the layers obtains the thermo-adhesive multilayer film and the subsequent bonding thereof with the decorative layer obtains the decorative multilayer film. The decorative multilayer film decorates substrates in the field of textiles, clothing, footwear and accessories. A finished decorated article includes a substrate on which the decorative multilayer film is applied.

A thermo-adhesive multilayer film based on thermoplastic polyurethane includes a barrier layer having a material with anti-dye migration properties selected from: ethylene vinyl alcohol copolymer, polyvinyl alcohol, polyvinyl acetate, polyamides, cellulose derivatives, polyvinylidene chloride and combinations. The barrier layer is interposed between two layers, each having a mixture of a thermoplastic polyurethane with a compatibilizing agent selected from: co-polymers modified with maleic anhydride, co-polymers modified with epoxy groups, co-polymers containing hydroxyl groups and combinations thereof. A decorative multilayer film includes the thermo-adhesive multilayer film and a further decorative layer, which provides an aesthetic effect. A process of co-extruding the layers obtains the thermo-adhesive multilayer film and the subsequent bonding thereof with the decorative layer obtains the decorative multilayer film. The decorative multilayer film decorates substrates in the field of textiles, clothing, footwear and accessories. A finished decorated article includes a substrate on which the decorative multilayer film is applied.

Provided is a heat-resistant shrinkable adhesive film capable of reducing or preventing defects such as shrinkage when exposed to a high temperature even when bonded in a highly stretched state. A heat-resistant shrinkable adhesive film according to one embodiment of the present disclosure includes (A) an acid functional group-containing (meth)acrylic polymer having a glass transition temperature of about 25° C. or lower, and (B) an acid or base functional group-containing (meth)acrylic polymer having a glass transition temperature of about 50° C. or higher, the mixing ratio of the component (A) being larger than the mixing ratio of the component (B), and the adhesive film including an adhesive layer with a crosslinked structure derived from a metal coordination bond crosslinking agent and can be stretched to an area magnification of 4 times or more

Problem to be Solved

A thermoplastic polyurethane film that is capable of achieving a stress relaxation property regardless of the type of polyol, while having good pasting workability, as well as a multilayer film using the same, is provided.

Solution

The thermoplastic polyurethane film is constituted by a reaction product obtained by using dicyclohexylmethane diisocyanate (H.sub.12MDI). This enables the thermoplastic polyurethane film and the multilayer film to have a good stress relaxation property regardless of the type of polyol, and to have excellent pasting workability.

Problem to be Solved

A thermoplastic polyurethane film that is capable of achieving a stress relaxation property regardless of the type of polyol, while having good pasting workability, as well as a multilayer film using the same, is provided.

Solution

The thermoplastic polyurethane film is constituted by a reaction product obtained by using dicyclohexylmethane diisocyanate (H.sub.12MDI). This enables the thermoplastic polyurethane film and the multilayer film to have a good stress relaxation property regardless of the type of polyol, and to have excellent pasting workability.

The interlayer film for laminated glass of the present invention comprises a thermoplastic resin and has a shear storage elastic modulus at 30° C. of 1.5 MPa or less. According to the present invention, an interlayer film for laminated glass can be provided which can allow for sufficient suppression of warpage in a case where laminated glass is obtained by allowing inorganic glass and organic glass to adhere.

The interlayer film for laminated glass of the present invention comprises a thermoplastic resin and has a shear storage elastic modulus at 30° C. of 1.5 MPa or less. According to the present invention, an interlayer film for laminated glass can be provided which can allow for sufficient suppression of warpage in a case where laminated glass is obtained by allowing inorganic glass and organic glass to adhere.

To provide laminated glass that can significantly reduce air bubbles remaining inside.

Laminated glass having a first glass substrate and a second glass substrate laminated to each other, which has a first interlayer disposed between the first glass substrate and the second glass substrate and being in contact with the first glass substrate, a second interlayer disposed between the first glass substrate and the second glass substrate and being in contact with the second glass substrate, first and second functional members disposed between the first interlayer and the second interlayer and being in contact with the first interlayer and the second interlayer, wherein the first and second functional members have a higher rigidity than the first and second interlayers, and the first and second functional members are spaced apart from each other by a distance d when the laminated glass is viewed in plan view, and said distance d is at least 15 mm.

To provide laminated glass that can significantly reduce air bubbles remaining inside.

Laminated glass having a first glass substrate and a second glass substrate laminated to each other, which has a first interlayer disposed between the first glass substrate and the second glass substrate and being in contact with the first glass substrate, a second interlayer disposed between the first glass substrate and the second glass substrate and being in contact with the second glass substrate, first and second functional members disposed between the first interlayer and the second interlayer and being in contact with the first interlayer and the second interlayer, wherein the first and second functional members have a higher rigidity than the first and second interlayers, and the first and second functional members are spaced apart from each other by a distance d when the laminated glass is viewed in plan view, and said distance d is at least 15 mm.