The present disclosure provides embodiments of improved area-selective deposition (ASD) processes and methods for selectively depositing polymer films on a variety of different target material. More specifically, the present disclosure provides improved ASD processes and related methods that use a cyclic vapor deposition process, which sequentially exposes a surface of a substrate to a polymer precursor followed by an initiator to selectively deposit a polymer thin film on a target material exposed on the substrate surface. The process of sequentially exposing the substrate surface to the precursor and the initiator can be repeated for one or more cycles of the cyclic vapor deposition process until a predetermined thickness of the polymer thin film is selectively deposited on the target material. In one embodiment, sequentially pulsed initiated chemical vapor deposition (spiCVD) is used to selectively deposit the polymer thin film on the target material.

A production method for a waterproof and wear-resistant composite floor, comprising: first manufacturing a PVC composite layer preform (3); then performing a corona treatment and a punching treatment on a soft cushion layer (2); and finally, compounding, at one time, the PVC composite layer preform (3), the soft cushion layer (2) and a waterproof substrate layer (1) into one. Said process is simple and easy to implement, shortening the production cycle, reducing the manpower and material resources required by the production process and reducing the production cost; moreover, the waterproof and wear-resistant composite floor produced has a simple structure, and also has very good waterproof and wear-resistant performance; in addition, the waterproof and wear-resistant composite floor will not swell, and will also not split into layers or deform easily.

A production method for a waterproof and wear-resistant composite floor, comprising: first manufacturing a PVC composite layer preform (3); then performing a corona treatment and a punching treatment on a soft cushion layer (2); and finally, compounding, at one time, the PVC composite layer preform (3), the soft cushion layer (2) and a waterproof substrate layer (1) into one. Said process is simple and easy to implement, shortening the production cycle, reducing the manpower and material resources required by the production process and reducing the production cost; moreover, the waterproof and wear-resistant composite floor produced has a simple structure, and also has very good waterproof and wear-resistant performance; in addition, the waterproof and wear-resistant composite floor will not swell, and will also not split into layers or deform easily.

Textiles are re-cycled by grinding and scatter-laying onto a needle-punched web optionally containing low-melting material, followed by laying a second needle-punched web over the scattered layer and re-needling the three layers before applying heat or heat and pressure to activate the low-melting ground material present within the layers. Additional low-melt ground material is optionally blended into the ground textile if low melt components are absent or insufficient to bond the composite. The ground material is driven and dispersed into the surrounding web layers with at least part of the material being adjacent the two outer surfaces. The physical properties of the composite can be adjusted by selecting suitable combinations including but not limited to needling stroke depth, needling density, needle gage, low-melt content, heat finishing conditions, and relative layer weights. The final composites can optionally be reintroduced into the original end use and include significant percentages of recycled material.

Textiles are re-cycled by grinding and scatter-laying onto a needle-punched web optionally containing low-melting material, followed by laying a second needle-punched web over the scattered layer and re-needling the three layers before applying heat or heat and pressure to activate the low-melting ground material present within the layers. Additional low-melt ground material is optionally blended into the ground textile if low melt components are absent or insufficient to bond the composite. The ground material is driven and dispersed into the surrounding web layers with at least part of the material being adjacent the two outer surfaces. The physical properties of the composite can be adjusted by selecting suitable combinations including but not limited to needling stroke depth, needling density, needle gage, low-melt content, heat finishing conditions, and relative layer weights. The final composites can optionally be reintroduced into the original end use and include significant percentages of recycled material.

The present disclosure provides copolymers useful in medical devices. For example, the disclosure provides copolymers comprising the polymerization product ester block, ether blocks and diisocyanates. In certain embodiments, the disclosure provides a medical copolymer for implantation comprising ester blocks and ether blocks, wherein: the ester blocks comprise a negative free energy transfer and the ether blocks comprise a positive free energy transfer, the ether and ester blocks are less than 1/10 the length of said copolymer, and, the blocks are distributed such that no domain of contiguous blocks possessing the same polarity of free energy transfer are less than ⅓ of the molecular weight of the copolymer. The disclosure further provides methods of making the aforementioned polymers, and medical devices comprising the polymers.

The present disclosure provides copolymers useful in medical devices. For example, the disclosure provides copolymers comprising the polymerization product ester block, ether blocks and diisocyanates. In certain embodiments, the disclosure provides a medical copolymer for implantation comprising ester blocks and ether blocks, wherein: the ester blocks comprise a negative free energy transfer and the ether blocks comprise a positive free energy transfer, the ether and ester blocks are less than 1/10 the length of said copolymer, and, the blocks are distributed such that no domain of contiguous blocks possessing the same polarity of free energy transfer are less than ⅓ of the molecular weight of the copolymer. The disclosure further provides methods of making the aforementioned polymers, and medical devices comprising the polymers.

A new protective polymeric sheet is described wherein said polymeric sheet includes perforations and attached spacers that allow air and water circulation when the sheet is in use. The sheet protects underlying structures from damage while ensuring moisture migration between the protective polymeric sheet and the underlying structure. The protective polymeric sheet comprises a plurality of perforations extending through the sheet and a plurality of spacers, each spacer extending from a lower surface of the sheet adjacent to one side of each perforation. The spacers are created during perforation of the polymeric sheet. The protective polymeric sheet is useful in a number of applications, including without limitation: to protect pipelines; to replace geotextiles in heap leach processes; to line sandboxes and paving stones; to cover greenhouse floors; to make industrial or residential gutter caps; and as a filter.

In a method for producing a lamination stack for rotors and/or stators of electric motors or generators, laminations are punched from electrical steel, a light-activated adhesive is applied to at least one side of the laminations, respectively, and the adhesive is irradiated and activated with a light of a required wavelength immediately before the adhesive exits from an application unit. The laminations are then stacked to a lamination stack. An adhesive application device for carrying out the method has at least one application unit with at least one valve for discharging an adhesive. At least one radiation source is arranged in a region of the valve and emits a radiation and directs the radiation to the adhesive provided in the region of the at least one valve.

In a method for producing a lamination stack for rotors and/or stators of electric motors or generators, laminations are punched from electrical steel, a light-activated adhesive is applied to at least one side of the laminations, respectively, and the adhesive is irradiated and activated with a light of a required wavelength immediately before the adhesive exits from an application unit. The laminations are then stacked to a lamination stack. An adhesive application device for carrying out the method has at least one application unit with at least one valve for discharging an adhesive. At least one radiation source is arranged in a region of the valve and emits a radiation and directs the radiation to the adhesive provided in the region of the at least one valve.